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Development and Application of Chlorinated, Fluorinated and Technological Polymer Films Modified by Grafting Process Using Electron Beam and Gamma Radiation

Abstract

The ionizing irradiation (electron beam and gamma irradiation) induced grafting to fluorinated and chlorinated polymeric films were studied. Styrene grafting onto fluorinated and perfluorinated polymers and their ulterior sulfonation constitute a process to produce ionomers for many applications. The modification of polyvinylchloride with dimethylaminethylmethacrylate-heparin grafting attempt for the fact that grafting can be applied in packaging industry as an alternative for decreasing of plasticizer or another chemical species migration, in many cases nocivus contaminant for human health, and, in the specific study of this project, to obtain a less thrombogenic polymer surface to be used in medical applications. The results indicate mutual styrene grafting performed by industrial EB accelerator can be a fast alternative to produce ionomers that can compete in market. The numerical method to simulate diffusion process evolved is simple and fast and applied to fit experimental results. (author)
Authors:
Manzoli, J E; [1]  Universidade Sao Judas Tadeu, Sao Paulo (Brazil)]; Geraldo, A B.C.; Moura, E; Somesari, E S.R.; Silveira, C G; Oikawa, H; Moreira, N S; Forbicini, C; [1]  Tenorio, E; [2]  Augusto, C G; [3]  Universidade Sao Judas Tadeu, Sao Paulo (Brazil)]; Panzarini, L C.G.A. [4] 
  1. Nuclear Energy National Commission, Nuclear and Energetic Research Institute, Sao Paulo (Brazil)
  2. FATEC, Tatui (Brazil)
  3. IFSP, Sao Paulo (Brazil)
  4. FEI, Sao Bernardo do Campo (Brazil)
Publication Date:
Sep 15, 2012
Product Type:
Book
Resource Relation:
Other Information: 10 figs, 3 tabs, 17 refs; Related Information: In: Development of Novel Adsorbents and Membranes by Radiation-induced Grafting for Selective Separation in Environmental and Industrial Applications| 290 p.
Subject:
38 RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY; ELECTRON BEAMS; FILMS; GAMMA RADIATION; HEPARIN; INDUSTRY; IRRADIATION; POLYMERS; PUBLIC HEALTH; STYRENE; SULFONATION; SURFACES
OSTI ID:
22012222
Research Organizations:
International Atomic Energy Agency, Industrial Applications and Chemistry Section, Vienna (Austria)
Country of Origin:
IAEA
Language:
English
Other Identifying Numbers:
Other: ISSN 2225-8833; ISBN 978-92-0-134010-8; TRN: XA12N1782099323
Availability:
Also available on-line: http://www-pub.iaea.org/MTCD/Publications/PDF/P1572_web.pdf; Enquiries should be addressed to IAEA, Marketing and Sales Unit, Publishing Section, E-mail: sales.publications@iaea.org; Web site: http://www.iaea.org/books
Submitting Site:
INIS
Size:
page(s) 35-47
Announcement Date:
Jan 03, 2013

Citation Formats

Manzoli, J E, Universidade Sao Judas Tadeu, Sao Paulo (Brazil)], Geraldo, A B.C., Moura, E, Somesari, E S.R., Silveira, C G, Oikawa, H, Moreira, N S, Forbicini, C, Tenorio, E, Augusto, C G, Universidade Sao Judas Tadeu, Sao Paulo (Brazil)], and Panzarini, L C.G.A. Development and Application of Chlorinated, Fluorinated and Technological Polymer Films Modified by Grafting Process Using Electron Beam and Gamma Radiation. IAEA: N. p., 2012. Web.
Manzoli, J E, Universidade Sao Judas Tadeu, Sao Paulo (Brazil)], Geraldo, A B.C., Moura, E, Somesari, E S.R., Silveira, C G, Oikawa, H, Moreira, N S, Forbicini, C, Tenorio, E, Augusto, C G, Universidade Sao Judas Tadeu, Sao Paulo (Brazil)], & Panzarini, L C.G.A. Development and Application of Chlorinated, Fluorinated and Technological Polymer Films Modified by Grafting Process Using Electron Beam and Gamma Radiation. IAEA.
Manzoli, J E, Universidade Sao Judas Tadeu, Sao Paulo (Brazil)], Geraldo, A B.C., Moura, E, Somesari, E S.R., Silveira, C G, Oikawa, H, Moreira, N S, Forbicini, C, Tenorio, E, Augusto, C G, Universidade Sao Judas Tadeu, Sao Paulo (Brazil)], and Panzarini, L C.G.A. 2012. "Development and Application of Chlorinated, Fluorinated and Technological Polymer Films Modified by Grafting Process Using Electron Beam and Gamma Radiation." IAEA.
@misc{etde_22012222,
title = {Development and Application of Chlorinated, Fluorinated and Technological Polymer Films Modified by Grafting Process Using Electron Beam and Gamma Radiation}
author = {Manzoli, J E, Universidade Sao Judas Tadeu, Sao Paulo (Brazil)], Geraldo, A B.C., Moura, E, Somesari, E S.R., Silveira, C G, Oikawa, H, Moreira, N S, Forbicini, C, Tenorio, E, Augusto, C G, Universidade Sao Judas Tadeu, Sao Paulo (Brazil)], and Panzarini, L C.G.A.}
abstractNote = {The ionizing irradiation (electron beam and gamma irradiation) induced grafting to fluorinated and chlorinated polymeric films were studied. Styrene grafting onto fluorinated and perfluorinated polymers and their ulterior sulfonation constitute a process to produce ionomers for many applications. The modification of polyvinylchloride with dimethylaminethylmethacrylate-heparin grafting attempt for the fact that grafting can be applied in packaging industry as an alternative for decreasing of plasticizer or another chemical species migration, in many cases nocivus contaminant for human health, and, in the specific study of this project, to obtain a less thrombogenic polymer surface to be used in medical applications. The results indicate mutual styrene grafting performed by industrial EB accelerator can be a fast alternative to produce ionomers that can compete in market. The numerical method to simulate diffusion process evolved is simple and fast and applied to fit experimental results. (author)}
place = {IAEA}
year = {2012}
month = {Sep}
}