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N-doped graphene-SnO{sub 2} sandwich paper for high-performance lithium-ion batteries

Abstract

A new facile route to fabricate N-doped graphene-SnO{sub 2} sandwich papers is developed. The 7,7,8,8-tetracyanoquinodimethane anion (TCNQ{sup -}) plays a key role for the formation of such structures as it acts as both the nitrogen source and complexing agent. If used in lithium-ion batteries (LIBs), the material exhibits a large capacity, high rate capability, and excellent cycling stability. The superior electrochemical performance of this novel material is the result from its unique features: excellent electronic conductivity related to the sandwich structure, short transportation length for both lithium ions and electrons, and elastomeric space to accommodate volume changes upon Li insertion/extraction. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)
Authors:
Wang, Xi; Chen, Shimou; Tang, Dai-Ming; Zhai, Tianyou; Li, Liang; Bando, Yoshio; Golberg, Dmitri; [1]  Cao, Xinqiang; Zhong, Yeteng; [2]  Bourgeois, Laure; [3]  Guan, Hasigaowa; [4]  Li, Huiqiao [5] 
  1. International Center for Young Scientists (ICYS) and International Center for Materials, Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), Namiki 1-1, Tsukuba, Ibaraki 305-0044 (Japan)
  2. Beijing National Laboratory for Molecular Science, Key Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190 (China)
  3. Monash Centre for Electron Microscopy and Department of Materials Engineering, Monash University, VIC 3800 (Australia)
  4. Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, Ocean University of China, Qingdao 266100 (China)
  5. Energy Technology Research Institute, National Institute of Advanced Industry and Technology (AIST), Umezono, 1-1-1, Tsukuba (Japan)
Publication Date:
Jul 10, 2012
Product Type:
Journal Article
Resource Relation:
Journal Name: Advanced Functional Materials; Journal Volume: 22; Journal Issue: 13; Other Information: With 10 figs., NA tabs., 53 refs.
Subject:
25 ENERGY STORAGE; CARBON; TIN OXIDES; ELECTRIC BATTERIES; PAPER; DOPED MATERIALS; PERFORMANCE; LITHIUM; CHARGE TRANSPORT; NITROGEN; CAPACITY
OSTI ID:
21581489
Country of Origin:
Germany
Language:
English
Other Identifying Numbers:
Journal ID: ISSN 1616-301X; TRN: DE12G8146
Availability:
Available from: http://dx.doi.org/10.1002/adfm.201103110
Submitting Site:
DE
Size:
page(s) 2682-2690
Announcement Date:
Aug 23, 2012

Citation Formats

Wang, Xi, Chen, Shimou, Tang, Dai-Ming, Zhai, Tianyou, Li, Liang, Bando, Yoshio, Golberg, Dmitri, Cao, Xinqiang, Zhong, Yeteng, Bourgeois, Laure, Guan, Hasigaowa, and Li, Huiqiao. N-doped graphene-SnO{sub 2} sandwich paper for high-performance lithium-ion batteries. Germany: N. p., 2012. Web. doi:10.1002/ADFM.201103110.
Wang, Xi, Chen, Shimou, Tang, Dai-Ming, Zhai, Tianyou, Li, Liang, Bando, Yoshio, Golberg, Dmitri, Cao, Xinqiang, Zhong, Yeteng, Bourgeois, Laure, Guan, Hasigaowa, & Li, Huiqiao. N-doped graphene-SnO{sub 2} sandwich paper for high-performance lithium-ion batteries. Germany. https://doi.org/10.1002/ADFM.201103110
Wang, Xi, Chen, Shimou, Tang, Dai-Ming, Zhai, Tianyou, Li, Liang, Bando, Yoshio, Golberg, Dmitri, Cao, Xinqiang, Zhong, Yeteng, Bourgeois, Laure, Guan, Hasigaowa, and Li, Huiqiao. 2012. "N-doped graphene-SnO{sub 2} sandwich paper for high-performance lithium-ion batteries." Germany. https://doi.org/10.1002/ADFM.201103110.
@misc{etde_21581489,
title = {N-doped graphene-SnO{sub 2} sandwich paper for high-performance lithium-ion batteries}
author = {Wang, Xi, Chen, Shimou, Tang, Dai-Ming, Zhai, Tianyou, Li, Liang, Bando, Yoshio, Golberg, Dmitri, Cao, Xinqiang, Zhong, Yeteng, Bourgeois, Laure, Guan, Hasigaowa, and Li, Huiqiao}
abstractNote = {A new facile route to fabricate N-doped graphene-SnO{sub 2} sandwich papers is developed. The 7,7,8,8-tetracyanoquinodimethane anion (TCNQ{sup -}) plays a key role for the formation of such structures as it acts as both the nitrogen source and complexing agent. If used in lithium-ion batteries (LIBs), the material exhibits a large capacity, high rate capability, and excellent cycling stability. The superior electrochemical performance of this novel material is the result from its unique features: excellent electronic conductivity related to the sandwich structure, short transportation length for both lithium ions and electrons, and elastomeric space to accommodate volume changes upon Li insertion/extraction. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)}
doi = {10.1002/ADFM.201103110}
journal = []
issue = {13}
volume = {22}
place = {Germany}
year = {2012}
month = {Jul}
}