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Chemiluminescence determination of tetracyclines using Fenton system in the presence europium(III) ions

Abstract

A new simple chemiluminescent method for the determination of chlortetracycline (Chlor-TC), oxytetracycline (Oxy-TC) and doxycycline (Doxy-TC) is described. This method is based on the europium(III) emission as a result of the energy transfer process from the excited product of the tetracyclines oxidation to the uncomplexed Eu(III). Under the optimum conditions, calibration graphs were obtained for 4 x 10{sup -7} to 2 x 10{sup -5} mol L{sup -1} of Chlor-TC; 2 x 10{sup -7} to 2 x 10{sup -5} mol L{sup -1} of Oxy-TC and 1 x 10{sup -7} to 3 x 10{sup -5} mol L{sup -1} of Doxy-TC. The method was successfully applied to the determination of these drugs in pharmaceutical and veterinary formulation and honey.
Authors:
Kaczmarek, Malgorzata; [1]  Lis, Stefan [1] 
  1. Department of Rare Earths, Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60 - 780 Poznan (Poland)
Publication Date:
Apr 20, 2009
Product Type:
Journal Article
Resource Relation:
Journal Name: Analytica Chimica Acta; Journal Volume: 639; Journal Issue: 1-2; Other Information: DOI: 10.1016/j.aca.2009.02.047; PII: S0003-2670(09)00341-9; Copyright (c) 2009 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CALIBRATION; CHEMILUMINESCENCE; ENERGY TRANSFER; EUROPIUM; HONEY; IONS; OXIDATION; OXYTETRACYCLINE; ANTIBIOTICS; ANTI-INFECTIVE AGENTS; CHARGED PARTICLES; CHEMICAL REACTIONS; DRUGS; ELEMENTS; EMISSION; FOOD; LUMINESCENCE; METALS; ORGANIC COMPOUNDS; PHOTON EMISSION; RARE EARTHS; TETRACYCLINES
OSTI ID:
21556944
Country of Origin:
Netherlands
Language:
English
Other Identifying Numbers:
Journal ID: ISSN 0003-2670; ACACAM; TRN: NL09R7430034762
Availability:
Available from http://dx.doi.org/10.1016/j.aca.2009.02.047
Submitting Site:
NLN
Size:
page(s) 96-100
Announcement Date:
May 31, 2012

Citation Formats

Kaczmarek, Malgorzata, and Lis, Stefan. Chemiluminescence determination of tetracyclines using Fenton system in the presence europium(III) ions. Netherlands: N. p., 2009. Web. doi:10.1016/j.aca.2009.02.047.
Kaczmarek, Malgorzata, & Lis, Stefan. Chemiluminescence determination of tetracyclines using Fenton system in the presence europium(III) ions. Netherlands. doi:10.1016/j.aca.2009.02.047.
Kaczmarek, Malgorzata, and Lis, Stefan. 2009. "Chemiluminescence determination of tetracyclines using Fenton system in the presence europium(III) ions." Netherlands. doi:10.1016/j.aca.2009.02.047. https://www.osti.gov/servlets/purl/10.1016/j.aca.2009.02.047.
@misc{etde_21556944,
title = {Chemiluminescence determination of tetracyclines using Fenton system in the presence europium(III) ions}
author = {Kaczmarek, Malgorzata, and Lis, Stefan}
abstractNote = {A new simple chemiluminescent method for the determination of chlortetracycline (Chlor-TC), oxytetracycline (Oxy-TC) and doxycycline (Doxy-TC) is described. This method is based on the europium(III) emission as a result of the energy transfer process from the excited product of the tetracyclines oxidation to the uncomplexed Eu(III). Under the optimum conditions, calibration graphs were obtained for 4 x 10{sup -7} to 2 x 10{sup -5} mol L{sup -1} of Chlor-TC; 2 x 10{sup -7} to 2 x 10{sup -5} mol L{sup -1} of Oxy-TC and 1 x 10{sup -7} to 3 x 10{sup -5} mol L{sup -1} of Doxy-TC. The method was successfully applied to the determination of these drugs in pharmaceutical and veterinary formulation and honey.}
doi = {10.1016/j.aca.2009.02.047}
journal = {Analytica Chimica Acta}
issue = {1-2}
volume = {639}
place = {Netherlands}
year = {2009}
month = {Apr}
}