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Synthesis and characterization of manganese ferrite nanoparticles by thermal treatment method

Abstract

Cubic structured manganese ferrite nanoparticles were synthesized by a thermal treatment method followed by calcination at various temperatures from 723 to 873 K. In this investigation, we used polyvinyl pyrrolidon (PVP) as a capping agent to control the agglomeration of the nanoparticles. The characterization studies were conducted by X-ray diffraction (XRD) and transmission electron microscopy (TEM). The average particle sizes of manganese ferrite nanoparticles were determined by TEM, which increased with the calcination temperature from 12 to 22 nm and they had good agreement with XRD results. Fourier transform infrared spectroscopy confirmed the presence of metal oxide bands at all temperatures and the absence of organic bands at 873 K. Magnetic properties were demonstrated by a vibrating sample magnetometer, which showed a super-paramagnetic behavior for all samples and also saturation magnetization (M{sub s}) increases from 3.06 to 15.78 emu/g by increasing the calcination temperature. The magnetic properties were also confirmed by the use of electron paramagnetic resonance spectroscopy, which revealed the existence of unpaired electrons and also measured peak-to-peak line width, resonant magnetic field and the g-factor. - Research highlights: Cubic structured manganese ferrite nano particles were synthesized by a thermal treatment method. Polyvinylpyrrolidon (PVP) has been used as a  More>>
Publication Date:
Jul 15, 2011
Product Type:
Journal Article
Resource Relation:
Journal Name: Journal of Magnetism and Magnetic Materials; Journal Volume: 323; Journal Issue: 13; Other Information: DOI: 10.1016/j.jmmm.2011.01.016; PII: S0304-8853(11)00028-X; Copyright (c) 2011 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.
Subject:
77 NANOSCIENCE AND NANOTECHNOLOGY; CALCINATION; ELECTRON SPIN RESONANCE; FERRITES; FOURIER TRANSFORM SPECTROMETERS; HEAT TREATMENTS; LANDE FACTOR; LINE WIDTHS; MAGNETIC PROPERTIES; MAGNETIZATION; MANGANESE COMPOUNDS; NANOSTRUCTURES; OXIDES; PARAMAGNETISM; PARTICLE SIZE; PARTICLES; PVP; TRANSMISSION ELECTRON MICROSCOPY; VIBRATING SAMPLE MAGNETOMETERS; X-RAY DIFFRACTION; AMIDES; AZOLES; BLOOD SUBSTITUTES; CHALCOGENIDES; CHEMICAL REACTIONS; COHERENT SCATTERING; DECOMPOSITION; DIFFRACTION; DIMENSIONLESS NUMBERS; DRUGS; ELECTRON MICROSCOPY; FERRIMAGNETIC MATERIALS; HEMATOLOGIC AGENTS; HETEROCYCLIC COMPOUNDS; IRON COMPOUNDS; LACTAMS; MAGNETIC MATERIALS; MAGNETIC RESONANCE; MAGNETISM; MAGNETOMETERS; MATERIALS; MEASURING INSTRUMENTS; MICROSCOPY; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; ORGANIC POLYMERS; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; POLYMERS; POLYVINYLS; PYROLYSIS; PYRROLES; PYRROLIDONES; RESONANCE; SCATTERING; SIZE; SPECTROMETERS; THERMOCHEMICAL PROCESSES; TRANSITION ELEMENT COMPOUNDS
OSTI ID:
21500871
Country of Origin:
Netherlands
Language:
English
Other Identifying Numbers:
Journal ID: ISSN 0304-8853; JMMMDC; TRN: NL11R2782092479
Availability:
Available from http://dx.doi.org/10.1016/j.jmmm.2011.01.016
Submitting Site:
NLN
Size:
page(s) 1745-1749
Announcement Date:
Nov 14, 2011

Citation Formats

Goodarz Naseri, M., E-mail: mahmoud.naseri55@gmail.co [Department of Physics, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor (Malaysia), Department of Physics, Faculty of Science, Malayer University, Malayer (Iran, Islamic Republic of)], Bin Saion, E, Ahangar, H Abbastabar, Hashim, M, Advance Materials and Nanotechnology Laboratory, Institute of Advanced Technology, University Putra Malaysia, 43400 UPM, Serdang, Selangor (Malaysia)], and Shaari, A H. Synthesis and characterization of manganese ferrite nanoparticles by thermal treatment method. Netherlands: N. p., 2011. Web. doi:10.1016/j.jmmm.2011.01.016.
Goodarz Naseri, M., E-mail: mahmoud.naseri55@gmail.co [Department of Physics, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor (Malaysia), Department of Physics, Faculty of Science, Malayer University, Malayer (Iran, Islamic Republic of)], Bin Saion, E, Ahangar, H Abbastabar, Hashim, M, Advance Materials and Nanotechnology Laboratory, Institute of Advanced Technology, University Putra Malaysia, 43400 UPM, Serdang, Selangor (Malaysia)], & Shaari, A H. Synthesis and characterization of manganese ferrite nanoparticles by thermal treatment method. Netherlands. https://doi.org/10.1016/j.jmmm.2011.01.016
Goodarz Naseri, M., E-mail: mahmoud.naseri55@gmail.co [Department of Physics, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor (Malaysia), Department of Physics, Faculty of Science, Malayer University, Malayer (Iran, Islamic Republic of)], Bin Saion, E, Ahangar, H Abbastabar, Hashim, M, Advance Materials and Nanotechnology Laboratory, Institute of Advanced Technology, University Putra Malaysia, 43400 UPM, Serdang, Selangor (Malaysia)], and Shaari, A H. 2011. "Synthesis and characterization of manganese ferrite nanoparticles by thermal treatment method." Netherlands. https://doi.org/10.1016/j.jmmm.2011.01.016.
@misc{etde_21500871,
title = {Synthesis and characterization of manganese ferrite nanoparticles by thermal treatment method}
author = {Goodarz Naseri, M., E-mail: mahmoud.naseri55@gmail.co [Department of Physics, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor (Malaysia), Department of Physics, Faculty of Science, Malayer University, Malayer (Iran, Islamic Republic of)], Bin Saion, E, Ahangar, H Abbastabar, Hashim, M, Advance Materials and Nanotechnology Laboratory, Institute of Advanced Technology, University Putra Malaysia, 43400 UPM, Serdang, Selangor (Malaysia)], and Shaari, A H}
abstractNote = {Cubic structured manganese ferrite nanoparticles were synthesized by a thermal treatment method followed by calcination at various temperatures from 723 to 873 K. In this investigation, we used polyvinyl pyrrolidon (PVP) as a capping agent to control the agglomeration of the nanoparticles. The characterization studies were conducted by X-ray diffraction (XRD) and transmission electron microscopy (TEM). The average particle sizes of manganese ferrite nanoparticles were determined by TEM, which increased with the calcination temperature from 12 to 22 nm and they had good agreement with XRD results. Fourier transform infrared spectroscopy confirmed the presence of metal oxide bands at all temperatures and the absence of organic bands at 873 K. Magnetic properties were demonstrated by a vibrating sample magnetometer, which showed a super-paramagnetic behavior for all samples and also saturation magnetization (M{sub s}) increases from 3.06 to 15.78 emu/g by increasing the calcination temperature. The magnetic properties were also confirmed by the use of electron paramagnetic resonance spectroscopy, which revealed the existence of unpaired electrons and also measured peak-to-peak line width, resonant magnetic field and the g-factor. - Research highlights: Cubic structured manganese ferrite nano particles were synthesized by a thermal treatment method. Polyvinylpyrrolidon (PVP) has been used as a capping agent to control the agglomeration of the nanoparticles. The average particle sizes of manganese ferrite nano particles were determined by TEM.}
doi = {10.1016/j.jmmm.2011.01.016}
journal = []
issue = {13}
volume = {323}
place = {Netherlands}
year = {2011}
month = {Jul}
}