Abstract
A cyano-bridged Fe(III)-Fe(III) complex, [Fe(L)]{sub 2}Fe(CN){sub 6}](NEt{sub 4})(MeOH){sub 2} (1) (L=N,N{sup '}-bis(5-chloro salicylidene)-2,2-dimethyl-1,3-diaminopropane) was prepared and characterized. The compound 1 crystallizes in Trigonal space group P3(1)21 with a= 16.3482, b= 16.3482, c= 19.5011 A{sup 0}, {gamma}= 120.00 degree . Single crystal X-ray analysis reveals that the complex assumes a cyano-bridged Fe{sub 3} unit. The four CN in the equatorial plane of the [Fe(CN){sub 6}]{sup -}3 moiety bridge four Mn ions, each in the trans position, which results in a 3D neutral layered structure giving a [-Fe-NC-Fe-CN-Fe-] linkage. The Mn ion assumes an elongated octahedral geometry, in which the equatorial sites are occupied by N{sub 2}O{sub 2} donor atoms of the Schiff base ligand, and the two axial positions are filled by two cyanide ion of [Fe(CN){sub 6}]{sup -}3. The magnetic measurement showed this complex to exhibit ferromagnetic behaviour.
Karaoglu, A;
Kara, H;
Kurtaran, R;
Azizoglu, A;
[1]
Yahsi, Y;
Sorace, L
[2]
- Balikesir University, Balikesir (Turkey)
- Universita di Firenze, Firenze (Italy)
Citation Formats
Karaoglu, A, Kara, H, Kurtaran, R, Azizoglu, A, Yahsi, Y, and Sorace, L.
The cyano-bridged penta nuclear Fe(III){sub 3} cluster structure and magnetic properties.
Turkey: N. p.,
2010.
Web.
Karaoglu, A, Kara, H, Kurtaran, R, Azizoglu, A, Yahsi, Y, & Sorace, L.
The cyano-bridged penta nuclear Fe(III){sub 3} cluster structure and magnetic properties.
Turkey.
Karaoglu, A, Kara, H, Kurtaran, R, Azizoglu, A, Yahsi, Y, and Sorace, L.
2010.
"The cyano-bridged penta nuclear Fe(III){sub 3} cluster structure and magnetic properties."
Turkey.
@misc{etde_21496946,
title = {The cyano-bridged penta nuclear Fe(III){sub 3} cluster structure and magnetic properties}
author = {Karaoglu, A, Kara, H, Kurtaran, R, Azizoglu, A, Yahsi, Y, and Sorace, L}
abstractNote = {A cyano-bridged Fe(III)-Fe(III) complex, [Fe(L)]{sub 2}Fe(CN){sub 6}](NEt{sub 4})(MeOH){sub 2} (1) (L=N,N{sup '}-bis(5-chloro salicylidene)-2,2-dimethyl-1,3-diaminopropane) was prepared and characterized. The compound 1 crystallizes in Trigonal space group P3(1)21 with a= 16.3482, b= 16.3482, c= 19.5011 A{sup 0}, {gamma}= 120.00 degree . Single crystal X-ray analysis reveals that the complex assumes a cyano-bridged Fe{sub 3} unit. The four CN in the equatorial plane of the [Fe(CN){sub 6}]{sup -}3 moiety bridge four Mn ions, each in the trans position, which results in a 3D neutral layered structure giving a [-Fe-NC-Fe-CN-Fe-] linkage. The Mn ion assumes an elongated octahedral geometry, in which the equatorial sites are occupied by N{sub 2}O{sub 2} donor atoms of the Schiff base ligand, and the two axial positions are filled by two cyanide ion of [Fe(CN){sub 6}]{sup -}3. The magnetic measurement showed this complex to exhibit ferromagnetic behaviour.}
place = {Turkey}
year = {2010}
month = {Jul}
}
title = {The cyano-bridged penta nuclear Fe(III){sub 3} cluster structure and magnetic properties}
author = {Karaoglu, A, Kara, H, Kurtaran, R, Azizoglu, A, Yahsi, Y, and Sorace, L}
abstractNote = {A cyano-bridged Fe(III)-Fe(III) complex, [Fe(L)]{sub 2}Fe(CN){sub 6}](NEt{sub 4})(MeOH){sub 2} (1) (L=N,N{sup '}-bis(5-chloro salicylidene)-2,2-dimethyl-1,3-diaminopropane) was prepared and characterized. The compound 1 crystallizes in Trigonal space group P3(1)21 with a= 16.3482, b= 16.3482, c= 19.5011 A{sup 0}, {gamma}= 120.00 degree . Single crystal X-ray analysis reveals that the complex assumes a cyano-bridged Fe{sub 3} unit. The four CN in the equatorial plane of the [Fe(CN){sub 6}]{sup -}3 moiety bridge four Mn ions, each in the trans position, which results in a 3D neutral layered structure giving a [-Fe-NC-Fe-CN-Fe-] linkage. The Mn ion assumes an elongated octahedral geometry, in which the equatorial sites are occupied by N{sub 2}O{sub 2} donor atoms of the Schiff base ligand, and the two axial positions are filled by two cyanide ion of [Fe(CN){sub 6}]{sup -}3. The magnetic measurement showed this complex to exhibit ferromagnetic behaviour.}
place = {Turkey}
year = {2010}
month = {Jul}
}