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La{sub 0.7}Sr{sub 0.3}MnO{sub 3} thin films deposited by pulsed laser ablation for spintronic applications

Abstract

Among spintronic materials, mixed-valence manganite La{sub 0.7}Sr{sub 0.3}MnO{sub 3} (LSMO) is widely investigated due to its half-metal nature. LSMO thin films were grown by pulsed laser deposition (PLD) onto amorphous silica substrates heated at nearly 600 C. An ArF excimer laser was chosen to induce ablation due to its more energetic photons compared to the other quoted excimer laser sources. Different oxygen pressures were considered in order to study the influence of oxygen on the LSMO optical and electrical properties. In this respect, the visible transparency percentage of the deposited films is found good enough for spin-OLED applications. The absorption coefficient shows an absorption band tunable as a function of the oxygen content. Its energetic location and evolution with the oxygen content demonstrate it originates from radiative transitions between the spin-majority bands separated by the Jahn-Teller distortion. All of this lets relate the deposition oxygen pressure to the Mn{sup 3+} ion content in each film and interpret electrical data. The 200 and 100 nm thick samples exhibit weak metallic transport behavior at room temperature with a resistivity of 4.8 and 6.9 {omega} cm, respectively. Concerning the resistivity response versus temperature, the measured low metal-insulator transition temperature (150 K) is related  More>>
Authors:
Martino, Maurizio; Cesaria, Maura; Caricato, Anna Paola; [1]  Maruccio, Giuseppe; [1]  NNL CNR-Istituto di Nanoscienze, Via Arnesano, 73100 Lecce (Italy)]; Cola, Adriano; Farella, Isabella [2] 
  1. Physics Department, University of Salento, Via Arnesano, 73100 Lecce (Italy)
  2. Institute for Microelectronics and Microsystems, IMM-CNR, 73100 Lecce (Italy)
Publication Date:
Aug 15, 2011
Product Type:
Journal Article
Resource Relation:
Journal Name: Physica Status Solidi. A, Applications and Materials Science (Print); Journal Volume: 208; Journal Issue: 8; Other Information: With 5 figs., 19 refs.
Subject:
36 MATERIALS SCIENCE; ABLATION; ABSORPTION SPECTRA; ARRHENIUS EQUATION; ELECTRIC CONDUCTIVITY; ENERGY-LEVEL TRANSITIONS; LANTHANUM COMPOUNDS; LASER RADIATION; LIGHT EMITTING DIODES; MANGANATES; POLARONS; STRONTIUM COMPOUNDS; SUBSTRATES; TEMPERATURE DEPENDENCE; TEMPERATURE RANGE 0013-0065 K; TEMPERATURE RANGE 0065-0273 K; TEMPERATURE RANGE 0273-0400 K; TEMPERATURE RANGE 0400-1000 K; THIN FILMS; VAPOR DEPOSITED COATINGS
OSTI ID:
21488574
Country of Origin:
Germany
Language:
English
Other Identifying Numbers:
Journal ID: ISSN 1862-6300; TRN: DE11FD389
Availability:
Available from: http://dx.doi.org/10.1002/pssa.201084037
Submitting Site:
DEN
Size:
page(s) 1817-1820
Announcement Date:
Nov 07, 2011

Citation Formats

Martino, Maurizio, Cesaria, Maura, Caricato, Anna Paola, Maruccio, Giuseppe, NNL CNR-Istituto di Nanoscienze, Via Arnesano, 73100 Lecce (Italy)], Cola, Adriano, and Farella, Isabella. La{sub 0.7}Sr{sub 0.3}MnO{sub 3} thin films deposited by pulsed laser ablation for spintronic applications. Germany: N. p., 2011. Web. doi:10.1002/PSSA.201084037.
Martino, Maurizio, Cesaria, Maura, Caricato, Anna Paola, Maruccio, Giuseppe, NNL CNR-Istituto di Nanoscienze, Via Arnesano, 73100 Lecce (Italy)], Cola, Adriano, & Farella, Isabella. La{sub 0.7}Sr{sub 0.3}MnO{sub 3} thin films deposited by pulsed laser ablation for spintronic applications. Germany. https://doi.org/10.1002/PSSA.201084037
Martino, Maurizio, Cesaria, Maura, Caricato, Anna Paola, Maruccio, Giuseppe, NNL CNR-Istituto di Nanoscienze, Via Arnesano, 73100 Lecce (Italy)], Cola, Adriano, and Farella, Isabella. 2011. "La{sub 0.7}Sr{sub 0.3}MnO{sub 3} thin films deposited by pulsed laser ablation for spintronic applications." Germany. https://doi.org/10.1002/PSSA.201084037.
@misc{etde_21488574,
title = {La{sub 0.7}Sr{sub 0.3}MnO{sub 3} thin films deposited by pulsed laser ablation for spintronic applications}
author = {Martino, Maurizio, Cesaria, Maura, Caricato, Anna Paola, Maruccio, Giuseppe, NNL CNR-Istituto di Nanoscienze, Via Arnesano, 73100 Lecce (Italy)], Cola, Adriano, and Farella, Isabella}
abstractNote = {Among spintronic materials, mixed-valence manganite La{sub 0.7}Sr{sub 0.3}MnO{sub 3} (LSMO) is widely investigated due to its half-metal nature. LSMO thin films were grown by pulsed laser deposition (PLD) onto amorphous silica substrates heated at nearly 600 C. An ArF excimer laser was chosen to induce ablation due to its more energetic photons compared to the other quoted excimer laser sources. Different oxygen pressures were considered in order to study the influence of oxygen on the LSMO optical and electrical properties. In this respect, the visible transparency percentage of the deposited films is found good enough for spin-OLED applications. The absorption coefficient shows an absorption band tunable as a function of the oxygen content. Its energetic location and evolution with the oxygen content demonstrate it originates from radiative transitions between the spin-majority bands separated by the Jahn-Teller distortion. All of this lets relate the deposition oxygen pressure to the Mn{sup 3+} ion content in each film and interpret electrical data. The 200 and 100 nm thick samples exhibit weak metallic transport behavior at room temperature with a resistivity of 4.8 and 6.9 {omega} cm, respectively. Concerning the resistivity response versus temperature, the measured low metal-insulator transition temperature (150 K) is related to the sample structural features as involved by the depositions. Two different transport mechanisms describe the conductivity regime of the deposited samples, namely the small polaron variable range hopping (VRH) and the Arrhenius law. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)}
doi = {10.1002/PSSA.201084037}
journal = []
issue = {8}
volume = {208}
place = {Germany}
year = {2011}
month = {Aug}
}