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Highly organized crystalline monolayer of a semi-fluorinated alkane on a solid substrate obtained by spin-coating

Abstract

We have obtained a 40 nm parameter crystalline monolayer of a semifluorinated alkane on a silicon wafer using the spin-coating technique. Its structure, analyzed by atomic force microscopy (AFM), is identical to that recently observed at the air-water interface, showing the existence of hexagonal nanodomains, organized on a long range order hexagonal lattice of a few tens of nanometers lateral parameter. Considering AFM images published on films transferred by the usual Langmuir-Blodgett method, one can note that the monolayers form locally ordered rounded domains. With our procedure, the original highly organized large crystalline structure is recovered.
Authors:
Bardin, Lisa; [1]  Synchrotron SOLEIL, L'Orme des Merisiers Saint-Aubin, BP 48 91192 Gif/Yvette (France)]; Faure, Marie-Claude; [1]  UFR Biomedicale, Universite Paris Descartes, 45 rue des Saints Peres, 75006 Paris (France)]; Filipe, Eduardo J.M.; [2]  Fontaine, Philippe; [3]  Goldmann, Michel; [1]  UFR Biomedicale, Universite Paris Descartes, 45 rue des Saints Peres, 75006 Paris (France)]
  1. Institut des Nano Sciences de Paris (INSP), UMR 7588 CNRS, Universite Pierre et Marie Curie, 140 rue de Lourmel, 75015 Paris (France)
  2. Instituto Superior Tecnico, Av. Rovisco Pais, 1049-001 Lisboa (Portugal)
  3. Synchrotron SOLEIL, L'Orme des Merisiers Saint-Aubin, BP 48 91192 Gif/Yvette (France)
Publication Date:
Oct 29, 2010
Product Type:
Journal Article
Resource Relation:
Journal Name: Thin Solid Films; Journal Volume: 519; Journal Issue: 1; Other Information: DOI: 10.1016/j.tsf.2010.07.065; PII: S0040-6090(10)01015-1; Copyright (c) 2010 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.
Subject:
36 MATERIALS SCIENCE; ALKANES; ATOMIC FORCE MICROSCOPY; CRYSTALS; HEXAGONAL LATTICES; INTERFACES; SILICON; SPIN-ON COATING; THIN FILMS; WATER; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DEPOSITION; ELEMENTS; FILMS; HYDROCARBONS; HYDROGEN COMPOUNDS; MICROSCOPY; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; SEMIMETALS; SURFACE COATING
OSTI ID:
21474232
Country of Origin:
Netherlands
Language:
English
Other Identifying Numbers:
Journal ID: ISSN 0040-6090; THSFAP; TRN: NL10S8081067230
Availability:
Available from http://dx.doi.org/10.1016/j.tsf.2010.07.065
Submitting Site:
NLN
Size:
page(s) 414-416
Announcement Date:
Sep 12, 2011

Citation Formats

Bardin, Lisa, Synchrotron SOLEIL, L'Orme des Merisiers Saint-Aubin, BP 48 91192 Gif/Yvette (France)], Faure, Marie-Claude, UFR Biomedicale, Universite Paris Descartes, 45 rue des Saints Peres, 75006 Paris (France)], Filipe, Eduardo J.M., Fontaine, Philippe, Goldmann, Michel, and UFR Biomedicale, Universite Paris Descartes, 45 rue des Saints Peres, 75006 Paris (France)]. Highly organized crystalline monolayer of a semi-fluorinated alkane on a solid substrate obtained by spin-coating. Netherlands: N. p., 2010. Web. doi:10.1016/j.tsf.2010.07.065.
Bardin, Lisa, Synchrotron SOLEIL, L'Orme des Merisiers Saint-Aubin, BP 48 91192 Gif/Yvette (France)], Faure, Marie-Claude, UFR Biomedicale, Universite Paris Descartes, 45 rue des Saints Peres, 75006 Paris (France)], Filipe, Eduardo J.M., Fontaine, Philippe, Goldmann, Michel, & UFR Biomedicale, Universite Paris Descartes, 45 rue des Saints Peres, 75006 Paris (France)]. Highly organized crystalline monolayer of a semi-fluorinated alkane on a solid substrate obtained by spin-coating. Netherlands. https://doi.org/10.1016/j.tsf.2010.07.065
Bardin, Lisa, Synchrotron SOLEIL, L'Orme des Merisiers Saint-Aubin, BP 48 91192 Gif/Yvette (France)], Faure, Marie-Claude, UFR Biomedicale, Universite Paris Descartes, 45 rue des Saints Peres, 75006 Paris (France)], Filipe, Eduardo J.M., Fontaine, Philippe, Goldmann, Michel, and UFR Biomedicale, Universite Paris Descartes, 45 rue des Saints Peres, 75006 Paris (France)]. 2010. "Highly organized crystalline monolayer of a semi-fluorinated alkane on a solid substrate obtained by spin-coating." Netherlands. https://doi.org/10.1016/j.tsf.2010.07.065.
@misc{etde_21474232,
title = {Highly organized crystalline monolayer of a semi-fluorinated alkane on a solid substrate obtained by spin-coating}
author = {Bardin, Lisa, Synchrotron SOLEIL, L'Orme des Merisiers Saint-Aubin, BP 48 91192 Gif/Yvette (France)], Faure, Marie-Claude, UFR Biomedicale, Universite Paris Descartes, 45 rue des Saints Peres, 75006 Paris (France)], Filipe, Eduardo J.M., Fontaine, Philippe, Goldmann, Michel, and UFR Biomedicale, Universite Paris Descartes, 45 rue des Saints Peres, 75006 Paris (France)]}
abstractNote = {We have obtained a 40 nm parameter crystalline monolayer of a semifluorinated alkane on a silicon wafer using the spin-coating technique. Its structure, analyzed by atomic force microscopy (AFM), is identical to that recently observed at the air-water interface, showing the existence of hexagonal nanodomains, organized on a long range order hexagonal lattice of a few tens of nanometers lateral parameter. Considering AFM images published on films transferred by the usual Langmuir-Blodgett method, one can note that the monolayers form locally ordered rounded domains. With our procedure, the original highly organized large crystalline structure is recovered.}
doi = {10.1016/j.tsf.2010.07.065}
journal = []
issue = {1}
volume = {519}
place = {Netherlands}
year = {2010}
month = {Oct}
}