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Functionalization of AlGaN/GaN heterostructures with TFAAD

Abstract

AlGaN/GaN high electron mobility transistors (HEMTs) show great promise for the realization of sensors for biomolecular, pharmaceutical and medical purposes. The high sensitivity and the stability in biological solutions are great advantages of this principle. The transduction is based on the AlGaN/GaN heterostructure. Charges on its surface influence the electron density in the 2-dimensional electron gas (2DEG) near the interface of the heterostructure. For a specific sensor, biological recognition methods shall be used. Therefore biomolecules need to be covalently linked to the semiconductor. The surface must be functionalized with a single layer of molecules that form covalent bonds to the surface and present functional groups for the connection with the biomolecule. In this work we investigate the functionalization of AlGaN/GaN heterostructures with 10-Trifluoroacetamiddec-1-ene (TFAAD), a molecule that can bond to GaN in a photochemical reaction and has a protected Amino group for the further procedure. The focus is on the influence of the illumination spectrum and surface pretreatments on the reaction kinetics and the resulting layer morphology with respect to the designated application.
Authors:
Schwarz, Stefan Udo; [1]  Cimalla, Volker; Nebel, Christoph; Ambacher, Oliver [2] 
  1. Institute of Microsystem Technology (IMTEK), University of Freiburg, Georges-Koehler-Allee 106, 79110 Freiburg (Germany)
  2. Fraunhofer Institute for Applied Solid State Physics, Tullastrasse 72, 79108 Freiburg (Germany)
Publication Date:
Jul 01, 2010
Product Type:
Journal Article
Resource Relation:
Journal Name: Verhandlungen der Deutschen Physikalischen Gesellschaft; Journal Issue: Regensburg 2010 issue; Conference: DPG Spring meeting 2010 of the condensed matter section with the divisions biological physics, chemical and polymer physics, crystallography, dielectric solids, dynamics and statistical physics, low temperature physics, magnetism, metal and material physics, physics of socio-economic systems, radiation and medical physics, semiconductor physics, surface science, thin films, vacuum science and technology as well as the working group industry and business, with job market, symposia, teachers' days, tutorials, exhibition of scientific instruments and literature, Regensburg (Germany), 21-26 Mar 2010; Other Information: Session: O 49.2 Mi 10:45; No further information available; Also available as printed version: Verhandlungen der Deutschen Physikalischen Gesellschaft v. 45(3)
Subject:
36 MATERIALS SCIENCE; ACETAMIDE; ALUMINIUM NITRIDES; CHEMICAL BONDS; CHEMICAL REACTION KINETICS; CHEMISORPTION; ENERGY DEPENDENCE; GALLIUM NITRIDES; HETEROJUNCTIONS; LAYERS; MORPHOLOGY; ORGANIC FLUORINE COMPOUNDS; PHOTOCHEMICAL REACTIONS; PHOTON-MOLECULE COLLISIONS; SURFACES
OSTI ID:
21461011
Country of Origin:
Germany
Language:
English
Other Identifying Numbers:
Journal ID: ISSN 0420-0195; VDPEAZ; TRN: DE11G8108
Availability:
http://www.dpg-verhandlungen.de
Submitting Site:
DE
Size:
1 pages
Announcement Date:
Aug 01, 2011

Citation Formats

Schwarz, Stefan Udo, Cimalla, Volker, Nebel, Christoph, and Ambacher, Oliver. Functionalization of AlGaN/GaN heterostructures with TFAAD. Germany: N. p., 2010. Web.
Schwarz, Stefan Udo, Cimalla, Volker, Nebel, Christoph, & Ambacher, Oliver. Functionalization of AlGaN/GaN heterostructures with TFAAD. Germany.
Schwarz, Stefan Udo, Cimalla, Volker, Nebel, Christoph, and Ambacher, Oliver. 2010. "Functionalization of AlGaN/GaN heterostructures with TFAAD." Germany.
@misc{etde_21461011,
title = {Functionalization of AlGaN/GaN heterostructures with TFAAD}
author = {Schwarz, Stefan Udo, Cimalla, Volker, Nebel, Christoph, and Ambacher, Oliver}
abstractNote = {AlGaN/GaN high electron mobility transistors (HEMTs) show great promise for the realization of sensors for biomolecular, pharmaceutical and medical purposes. The high sensitivity and the stability in biological solutions are great advantages of this principle. The transduction is based on the AlGaN/GaN heterostructure. Charges on its surface influence the electron density in the 2-dimensional electron gas (2DEG) near the interface of the heterostructure. For a specific sensor, biological recognition methods shall be used. Therefore biomolecules need to be covalently linked to the semiconductor. The surface must be functionalized with a single layer of molecules that form covalent bonds to the surface and present functional groups for the connection with the biomolecule. In this work we investigate the functionalization of AlGaN/GaN heterostructures with 10-Trifluoroacetamiddec-1-ene (TFAAD), a molecule that can bond to GaN in a photochemical reaction and has a protected Amino group for the further procedure. The focus is on the influence of the illumination spectrum and surface pretreatments on the reaction kinetics and the resulting layer morphology with respect to the designated application.}
journal = []
issue = {Regensburg 2010 issue}
place = {Germany}
year = {2010}
month = {Jul}
}