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Thermoplastic polyurethane and multi-walled carbon nanotubes nanocomposites for electrostatic dissipation; Nanocompositos de poliuretana termoplastica e nanotubos de carbono de paredes multiplas para dissipacao eletrostatica

Abstract

Polyurethane/multi-walled carbon nanotube (MWCNT) nanocomposites have been prepared with nanotube concentrations between 0.01 wt% and 1 wt%. MWCNT as-synthesized samples with {approx}74 nm diameter and {approx}7 mm length were introduced by solution processing in the polyurethane matrix. Scanning electron microscopy (SEM) images demonstrated good dispersion and adhesion of the CNTs to the polymeric matrix. The C=O stretching band showed evidence of perturbation of the hydrogen interaction between urethanic moieties in the nanocomposites as compared to pure TPU. Differential scanning calorimetry and positron annihilation lifetime spectroscopy measurements allowed the detection of glass transition displacement with carbon nanotube addition. Furthermore, the electrical conductivity of the nanocomposites was significantly increased with the addition of CNT. (author)
Authors:
Lavall, Rodrigo L; Sales, Juliana A. de; Borges, Raquel S; Calado, Hallen D. R.; Machado, Jose C; Windmoeller, Dario; Silva, Glaura G; [1]  Lacerda, Rodrigo G; Ladeira, Luiz O [2] 
  1. Universidade Federal de Minas Gerais (UFMG), Belo Horizonte, MG (Brazil). Inst. de Ciencias Exatas. Dept. de Quimica
  2. Universidade Federal de Minas Gerais (UFMG), Belo Horizonte, MG (Brazil). Inst. de Ciencias Exatas. Dept. de Fisica
Publication Date:
Jul 01, 2010
Product Type:
Journal Article
Resource Relation:
Journal Name: Quimica Nova On-Line; Journal Volume: 33; Journal Issue: 1
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ABSORPTION SPECTROSCOPY; BENZHYDROL; CARBON 13; CASTING; FORMAMIDE; GLYCOLS; HYDROGEN 1; INFRARED SPECTRA; ISOCYANATES; METHYLENE RADICALS; NMR SPECTRA; POLYURETHANES; SCANNING ELECTRON MICROSCOPY; ULTRASONIC WAVES
OSTI ID:
21310045
Country of Origin:
Brazil
Language:
Portuguese
Other Identifying Numbers:
Journal ID: ISSN 1678-7064; TRN: BR10V1342053162
Availability:
Available from http://www.scielo.br/pdf/qn/v33n1/25.pdf;INIS
Submitting Site:
BRN
Size:
page(s) 133-140
Announcement Date:
Jul 15, 2010

Citation Formats

Lavall, Rodrigo L, Sales, Juliana A. de, Borges, Raquel S, Calado, Hallen D. R., Machado, Jose C, Windmoeller, Dario, Silva, Glaura G, Lacerda, Rodrigo G, and Ladeira, Luiz O. Thermoplastic polyurethane and multi-walled carbon nanotubes nanocomposites for electrostatic dissipation; Nanocompositos de poliuretana termoplastica e nanotubos de carbono de paredes multiplas para dissipacao eletrostatica. Brazil: N. p., 2010. Web.
Lavall, Rodrigo L, Sales, Juliana A. de, Borges, Raquel S, Calado, Hallen D. R., Machado, Jose C, Windmoeller, Dario, Silva, Glaura G, Lacerda, Rodrigo G, & Ladeira, Luiz O. Thermoplastic polyurethane and multi-walled carbon nanotubes nanocomposites for electrostatic dissipation; Nanocompositos de poliuretana termoplastica e nanotubos de carbono de paredes multiplas para dissipacao eletrostatica. Brazil.
Lavall, Rodrigo L, Sales, Juliana A. de, Borges, Raquel S, Calado, Hallen D. R., Machado, Jose C, Windmoeller, Dario, Silva, Glaura G, Lacerda, Rodrigo G, and Ladeira, Luiz O. 2010. "Thermoplastic polyurethane and multi-walled carbon nanotubes nanocomposites for electrostatic dissipation; Nanocompositos de poliuretana termoplastica e nanotubos de carbono de paredes multiplas para dissipacao eletrostatica." Brazil.
@misc{etde_21310045,
title = {Thermoplastic polyurethane and multi-walled carbon nanotubes nanocomposites for electrostatic dissipation; Nanocompositos de poliuretana termoplastica e nanotubos de carbono de paredes multiplas para dissipacao eletrostatica}
author = {Lavall, Rodrigo L, Sales, Juliana A. de, Borges, Raquel S, Calado, Hallen D. R., Machado, Jose C, Windmoeller, Dario, Silva, Glaura G, Lacerda, Rodrigo G, and Ladeira, Luiz O}
abstractNote = {Polyurethane/multi-walled carbon nanotube (MWCNT) nanocomposites have been prepared with nanotube concentrations between 0.01 wt% and 1 wt%. MWCNT as-synthesized samples with {approx}74 nm diameter and {approx}7 mm length were introduced by solution processing in the polyurethane matrix. Scanning electron microscopy (SEM) images demonstrated good dispersion and adhesion of the CNTs to the polymeric matrix. The C=O stretching band showed evidence of perturbation of the hydrogen interaction between urethanic moieties in the nanocomposites as compared to pure TPU. Differential scanning calorimetry and positron annihilation lifetime spectroscopy measurements allowed the detection of glass transition displacement with carbon nanotube addition. Furthermore, the electrical conductivity of the nanocomposites was significantly increased with the addition of CNT. (author)}
journal = []
issue = {1}
volume = {33}
place = {Brazil}
year = {2010}
month = {Jul}
}