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Uses of complexone III and ion exchange resins in colorimetric determination with o-phenanthroline of Fe traces in uranium compounds; Aplicacion de la complexona III y resinas combadoras a la determinacion colorimetrica con orto-fenantro-lina de trazas de dhierro en compuesto de uranio

Abstract

The determination of small quantities of iron using o-phenanthroline, assumes the elimination of some cations interference by means of pH control before the formation of a coloured complex. We have eluded that difficulty by the connected action of complexones III and ion exchange. the previous forms quelate with the iron (III) with a stability constant high enough to permit the pass of an iron solution through a cation resin column without being fixed which never occurs with the interferer cations. Mercury is the only element with a similar stability, but it has been eliminated previously. (Author) 16 refs.
Publication Date:
Jul 01, 1956
Product Type:
Technical Report
Report Number:
JEN-11
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; MERCURY; CHEMICAL ANALYSIS; ION EXCHANGE; RESINS; COLORIMETRIC DOSEMETERS; URANIUM; URANIUM COMPOUNDS; CATIONS
OSTI ID:
21240022
Research Organizations:
Junta de Energia Nuclear (JEN), Madrid (Spain)
Country of Origin:
Spain
Language:
Spanish
Other Identifying Numbers:
TRN: ES09B0723
Availability:
Commercial reproduction prohibited; OSTI as DE21240022
Submitting Site:
SPN
Size:
14 pages
Announcement Date:
Dec 11, 2009

Citation Formats

Fernandez Cellini, R, and Ruiz Sanchez, F. Uses of complexone III and ion exchange resins in colorimetric determination with o-phenanthroline of Fe traces in uranium compounds; Aplicacion de la complexona III y resinas combadoras a la determinacion colorimetrica con orto-fenantro-lina de trazas de dhierro en compuesto de uranio. Spain: N. p., 1956. Web.
Fernandez Cellini, R, & Ruiz Sanchez, F. Uses of complexone III and ion exchange resins in colorimetric determination with o-phenanthroline of Fe traces in uranium compounds; Aplicacion de la complexona III y resinas combadoras a la determinacion colorimetrica con orto-fenantro-lina de trazas de dhierro en compuesto de uranio. Spain.
Fernandez Cellini, R, and Ruiz Sanchez, F. 1956. "Uses of complexone III and ion exchange resins in colorimetric determination with o-phenanthroline of Fe traces in uranium compounds; Aplicacion de la complexona III y resinas combadoras a la determinacion colorimetrica con orto-fenantro-lina de trazas de dhierro en compuesto de uranio." Spain.
@misc{etde_21240022,
title = {Uses of complexone III and ion exchange resins in colorimetric determination with o-phenanthroline of Fe traces in uranium compounds; Aplicacion de la complexona III y resinas combadoras a la determinacion colorimetrica con orto-fenantro-lina de trazas de dhierro en compuesto de uranio}
author = {Fernandez Cellini, R, and Ruiz Sanchez, F}
abstractNote = {The determination of small quantities of iron using o-phenanthroline, assumes the elimination of some cations interference by means of pH control before the formation of a coloured complex. We have eluded that difficulty by the connected action of complexones III and ion exchange. the previous forms quelate with the iron (III) with a stability constant high enough to permit the pass of an iron solution through a cation resin column without being fixed which never occurs with the interferer cations. Mercury is the only element with a similar stability, but it has been eliminated previously. (Author) 16 refs.}
place = {Spain}
year = {1956}
month = {Jul}
}