Abstract
The rate of the proto tropic change of benzylidene-benzylamine has been determined by using azomethine {sup 1}4C-labelled in the methylenic group and measuring the distribution of activity between benzaldehyde and benzylamine obtained by hydrolysis at different reaction times. this rate has been compared with those of tautomerization of benzylidene-{alpha}-alkyl benzylamine and {alpha}-alkyl benzylidene-benzyl amines in the same experimental conditions in order to establish ethe influence of alkyl group on this reaction. (Author) 14 refs.
Citation Formats
Perez Ossorio, R, Gamboa, J M, and Martinez Utrilla, R.
Mechanism of Prototropy. III. Kinetics of the Tautomerization of Benzylidene-Benzylamine. comparison of the influence of hydrogen and alkyl groups on the S{sub E}2' reaction rate; mecanismo de la Prototropia. III. Cinetica de la tautomerizacion de la benciliden-bencilamina. Comparacion de la influencia del hidrogeno y grupos alcohilos sobre la velocidad de la reaccion S{sub E}2'.
Spain: N. p.,
1961.
Web.
Perez Ossorio, R, Gamboa, J M, & Martinez Utrilla, R.
Mechanism of Prototropy. III. Kinetics of the Tautomerization of Benzylidene-Benzylamine. comparison of the influence of hydrogen and alkyl groups on the S{sub E}2' reaction rate; mecanismo de la Prototropia. III. Cinetica de la tautomerizacion de la benciliden-bencilamina. Comparacion de la influencia del hidrogeno y grupos alcohilos sobre la velocidad de la reaccion S{sub E}2'.
Spain.
Perez Ossorio, R, Gamboa, J M, and Martinez Utrilla, R.
1961.
"Mechanism of Prototropy. III. Kinetics of the Tautomerization of Benzylidene-Benzylamine. comparison of the influence of hydrogen and alkyl groups on the S{sub E}2' reaction rate; mecanismo de la Prototropia. III. Cinetica de la tautomerizacion de la benciliden-bencilamina. Comparacion de la influencia del hidrogeno y grupos alcohilos sobre la velocidad de la reaccion S{sub E}2'."
Spain.
@misc{etde_21222109,
title = {Mechanism of Prototropy. III. Kinetics of the Tautomerization of Benzylidene-Benzylamine. comparison of the influence of hydrogen and alkyl groups on the S{sub E}2' reaction rate; mecanismo de la Prototropia. III. Cinetica de la tautomerizacion de la benciliden-bencilamina. Comparacion de la influencia del hidrogeno y grupos alcohilos sobre la velocidad de la reaccion S{sub E}2'}
author = {Perez Ossorio, R, Gamboa, J M, and Martinez Utrilla, R}
abstractNote = {The rate of the proto tropic change of benzylidene-benzylamine has been determined by using azomethine {sup 1}4C-labelled in the methylenic group and measuring the distribution of activity between benzaldehyde and benzylamine obtained by hydrolysis at different reaction times. this rate has been compared with those of tautomerization of benzylidene-{alpha}-alkyl benzylamine and {alpha}-alkyl benzylidene-benzyl amines in the same experimental conditions in order to establish ethe influence of alkyl group on this reaction. (Author) 14 refs.}
place = {Spain}
year = {1961}
month = {Jul}
}
title = {Mechanism of Prototropy. III. Kinetics of the Tautomerization of Benzylidene-Benzylamine. comparison of the influence of hydrogen and alkyl groups on the S{sub E}2' reaction rate; mecanismo de la Prototropia. III. Cinetica de la tautomerizacion de la benciliden-bencilamina. Comparacion de la influencia del hidrogeno y grupos alcohilos sobre la velocidad de la reaccion S{sub E}2'}
author = {Perez Ossorio, R, Gamboa, J M, and Martinez Utrilla, R}
abstractNote = {The rate of the proto tropic change of benzylidene-benzylamine has been determined by using azomethine {sup 1}4C-labelled in the methylenic group and measuring the distribution of activity between benzaldehyde and benzylamine obtained by hydrolysis at different reaction times. this rate has been compared with those of tautomerization of benzylidene-{alpha}-alkyl benzylamine and {alpha}-alkyl benzylidene-benzyl amines in the same experimental conditions in order to establish ethe influence of alkyl group on this reaction. (Author) 14 refs.}
place = {Spain}
year = {1961}
month = {Jul}
}