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Mechanism of Prototropy. V. Arrhenius parameters of the tautomerization of Benzylidene Benzylamine and its {alpha}-{alpha}-alkyl derivatives; Mecanismo de la prototropia V. Parametros de Arrhenius de la toutomerizacion de benciliden-bencilamina y sus {alpha}- y {alpha}-alquilderivados

Abstract

The reactions were conducted in ethyl alcohol-dioxan, in the presence of EtONa, as catalyst. Rates were followed by a radioactive tracer method when R=H and by spectroscopic method when R= alkyl as described in previous papers. The results suggest that polar effects alone cannot account for the relative Arrhenius parameters obtained. (Author) 3 refs.
Publication Date:
Jul 01, 1961
Product Type:
Technical Report
Report Number:
JEN-70
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; REACTION KINETICS; ARRHENIUS EQUATION; ACTIVATION ENERGY; LATTICE PARAMETERS; BENZYL RADICALS; ALPHA DETECTION; BENZYL ALCOHOL
OSTI ID:
21222108
Research Organizations:
Junta de Energia Nuclear (JEN), Madrid (Spain)
Country of Origin:
Spain
Language:
Spanish
Other Identifying Numbers:
TRN: ES09B0519
Availability:
Commercial reproduction prohibited; OSTI as DE21222108
Submitting Site:
SPN
Size:
10 pages
Announcement Date:
Oct 14, 2009

Citation Formats

Perez Ossorio, R, Gomez Herrera, F, Utrilla, R M, Hidalgo, A, and Gamboa, J M. Mechanism of Prototropy. V. Arrhenius parameters of the tautomerization of Benzylidene Benzylamine and its {alpha}-{alpha}-alkyl derivatives; Mecanismo de la prototropia V. Parametros de Arrhenius de la toutomerizacion de benciliden-bencilamina y sus {alpha}- y {alpha}-alquilderivados. Spain: N. p., 1961. Web.
Perez Ossorio, R, Gomez Herrera, F, Utrilla, R M, Hidalgo, A, & Gamboa, J M. Mechanism of Prototropy. V. Arrhenius parameters of the tautomerization of Benzylidene Benzylamine and its {alpha}-{alpha}-alkyl derivatives; Mecanismo de la prototropia V. Parametros de Arrhenius de la toutomerizacion de benciliden-bencilamina y sus {alpha}- y {alpha}-alquilderivados. Spain.
Perez Ossorio, R, Gomez Herrera, F, Utrilla, R M, Hidalgo, A, and Gamboa, J M. 1961. "Mechanism of Prototropy. V. Arrhenius parameters of the tautomerization of Benzylidene Benzylamine and its {alpha}-{alpha}-alkyl derivatives; Mecanismo de la prototropia V. Parametros de Arrhenius de la toutomerizacion de benciliden-bencilamina y sus {alpha}- y {alpha}-alquilderivados." Spain.
@misc{etde_21222108,
title = {Mechanism of Prototropy. V. Arrhenius parameters of the tautomerization of Benzylidene Benzylamine and its {alpha}-{alpha}-alkyl derivatives; Mecanismo de la prototropia V. Parametros de Arrhenius de la toutomerizacion de benciliden-bencilamina y sus {alpha}- y {alpha}-alquilderivados}
author = {Perez Ossorio, R, Gomez Herrera, F, Utrilla, R M, Hidalgo, A, and Gamboa, J M}
abstractNote = {The reactions were conducted in ethyl alcohol-dioxan, in the presence of EtONa, as catalyst. Rates were followed by a radioactive tracer method when R=H and by spectroscopic method when R= alkyl as described in previous papers. The results suggest that polar effects alone cannot account for the relative Arrhenius parameters obtained. (Author) 3 refs.}
place = {Spain}
year = {1961}
month = {Jul}
}