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Physical-chemistry aspects of water in steam turbines associated with material stress and electrochemical assessment of the AISI 403 to simulate real condition

Abstract

This study described a methodology developed to prevent the occurrence of corrosion failure in steam turbines. The methodology was developed after the failure of a turbine blade at a plant in Brazil. Deposits were collected from various locations along the turbine blade path and analyzed. A turbine deposit collector and simulator was installed to determine the concentrations of steam impurities. Samples were collected from the low pressure turbine at the crossover point and from the polishing station and analyzed using inductive coupled plasma-mass spectrometry (ICP-MS) in order to determine if sodium levels exceeded 3 ppb. Filters were weighed in order to determine the accumulation of impurities. A 3-electrode system was used to determine the influence of chloride ions. The design of the system's condensate polisher beds was modified in order to improve condensate effluent conductivity. The condensate treatment procedure lowered the concentrations of salt impurities and established a monitoring methodology for water and steam used at the plant. It was concluded that the methodology can be used to to reduce inspection intervals and increase system reliability. 10 refs., 1 tab., 7 figs.
Authors:
Pacheco, D S; Franco, C V; Godinho, J F; Frech, W A; Sonai, G G; [1]  Torres, L A.M.; Ellwanger, A R.F. [2] 
  1. Univ. Federal de Santa Catarina, Florianopolis (Brazil)
  2. Tractebel Energia, Capivari de Baixo (Brazil)
Publication Date:
Jul 01, 2009
Product Type:
Conference
Resource Relation:
Conference: The ICF 12. international conference on fracture, Ottawa, ON (Canada), 12-17 Jul 2009; Other Information: Monday July 13. Paper T09.008. Session T09-S2 : corrosion, environmentally assisted cracking and corrosion fatigue; Available on a CD-ROM for viewing with Adobe Reader; Related Information: In: Proceedings of the ICF 12. international conference on fracture, [600] pages.
Subject:
36 MATERIALS SCIENCE; 42 ENGINEERING; MATERIALS; ENGINEERING; STEAM TURBINES; CORROSION; STEAM; IMPURITIES; BENCH-SCALE EXPERIMENTS; MODIFICATIONS; FLUIDIZED BEDS; CONDENSATES
Sponsoring Organizations:
Univ. Federal de Santa Catarina, Florianopolis (Brazil); Tractebel Energia, Capivari de Baixo (Brazil); CNPq, Rio de Janeiro (Brazil)
OSTI ID:
21222039
Research Organizations:
Natural Resources Canada, Ottawa, ON (Canada). CANMET Materials Technology Lab; National Research Council of Canada, Ottawa, ON (Canada)
Country of Origin:
Canada
Language:
English
Other Identifying Numbers:
TRN: CA0904976
Availability:
Available from the ICF12 Conference Management Office, National Research Council Canada, Building M-19, 1200 Montreal Road, Ottawa, Ontario, K1A 0R6
Submitting Site:
CANM
Size:
page(s) 1-12
Announcement Date:
Oct 14, 2009

Citation Formats

Pacheco, D S, Franco, C V, Godinho, J F, Frech, W A, Sonai, G G, Torres, L A.M., and Ellwanger, A R.F. Physical-chemistry aspects of water in steam turbines associated with material stress and electrochemical assessment of the AISI 403 to simulate real condition. Canada: N. p., 2009. Web.
Pacheco, D S, Franco, C V, Godinho, J F, Frech, W A, Sonai, G G, Torres, L A.M., & Ellwanger, A R.F. Physical-chemistry aspects of water in steam turbines associated with material stress and electrochemical assessment of the AISI 403 to simulate real condition. Canada.
Pacheco, D S, Franco, C V, Godinho, J F, Frech, W A, Sonai, G G, Torres, L A.M., and Ellwanger, A R.F. 2009. "Physical-chemistry aspects of water in steam turbines associated with material stress and electrochemical assessment of the AISI 403 to simulate real condition." Canada.
@misc{etde_21222039,
title = {Physical-chemistry aspects of water in steam turbines associated with material stress and electrochemical assessment of the AISI 403 to simulate real condition}
author = {Pacheco, D S, Franco, C V, Godinho, J F, Frech, W A, Sonai, G G, Torres, L A.M., and Ellwanger, A R.F.}
abstractNote = {This study described a methodology developed to prevent the occurrence of corrosion failure in steam turbines. The methodology was developed after the failure of a turbine blade at a plant in Brazil. Deposits were collected from various locations along the turbine blade path and analyzed. A turbine deposit collector and simulator was installed to determine the concentrations of steam impurities. Samples were collected from the low pressure turbine at the crossover point and from the polishing station and analyzed using inductive coupled plasma-mass spectrometry (ICP-MS) in order to determine if sodium levels exceeded 3 ppb. Filters were weighed in order to determine the accumulation of impurities. A 3-electrode system was used to determine the influence of chloride ions. The design of the system's condensate polisher beds was modified in order to improve condensate effluent conductivity. The condensate treatment procedure lowered the concentrations of salt impurities and established a monitoring methodology for water and steam used at the plant. It was concluded that the methodology can be used to to reduce inspection intervals and increase system reliability. 10 refs., 1 tab., 7 figs.}
place = {Canada}
year = {2009}
month = {Jul}
}