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Determination of microquantities of methanol and ethanol in toluene by gas chromatography; Determinacion de microcantidades de metanol y de etanol en tolueno por cromatogrfia de gases

Abstract

A study is made of the detection of methanol and ethanol in toluene by means of gas chromatography, using Porapak Q columns, 1 m long at 189 degree centigree, employing a flame ionization detector, with propanol as an internal standard. The variation od the detector absolute and relative response was found to be linear within the range of concentration studied, that is, from 5 to 1000 ppm. The limit of sensitivity for the detection of ethanol in a column of 2% Ucon, over Chromosorob G deactivated with 0,1% Carbowax 400, was 20 ppm, which was four times higher than the limit of sensitivity of the Porapak Q column. Also in this case, the absolute and relative response of the detector was linear. (Author) 3 refs.
Authors:
Publication Date:
Jul 01, 1970
Product Type:
Technical Report
Report Number:
JEN-206
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; METHANOL; TOLUENE; ETHANOL; DETECTION; GAS CHROMATOGRAPHY; PROPANOLS; IONIZATION; SENSITIVITY
OSTI ID:
21125883
Research Organizations:
Junta de Energia Nuclear (JEN), Madrid (Spain)
Country of Origin:
Spain
Language:
Spanish
Other Identifying Numbers:
TRN: ES09B0030
Availability:
Commercial reproduction prohibited; OSTI as DE21125883
Submitting Site:
SPN
Size:
11 pages
Announcement Date:
Feb 26, 2009

Citation Formats

Perez, M M. Determination of microquantities of methanol and ethanol in toluene by gas chromatography; Determinacion de microcantidades de metanol y de etanol en tolueno por cromatogrfia de gases. Spain: N. p., 1970. Web.
Perez, M M. Determination of microquantities of methanol and ethanol in toluene by gas chromatography; Determinacion de microcantidades de metanol y de etanol en tolueno por cromatogrfia de gases. Spain.
Perez, M M. 1970. "Determination of microquantities of methanol and ethanol in toluene by gas chromatography; Determinacion de microcantidades de metanol y de etanol en tolueno por cromatogrfia de gases." Spain.
@misc{etde_21125883,
title = {Determination of microquantities of methanol and ethanol in toluene by gas chromatography; Determinacion de microcantidades de metanol y de etanol en tolueno por cromatogrfia de gases}
author = {Perez, M M}
abstractNote = {A study is made of the detection of methanol and ethanol in toluene by means of gas chromatography, using Porapak Q columns, 1 m long at 189 degree centigree, employing a flame ionization detector, with propanol as an internal standard. The variation od the detector absolute and relative response was found to be linear within the range of concentration studied, that is, from 5 to 1000 ppm. The limit of sensitivity for the detection of ethanol in a column of 2% Ucon, over Chromosorob G deactivated with 0,1% Carbowax 400, was 20 ppm, which was four times higher than the limit of sensitivity of the Porapak Q column. Also in this case, the absolute and relative response of the detector was linear. (Author) 3 refs.}
place = {Spain}
year = {1970}
month = {Jul}
}