Abstract
Raman spectroscopy was used to reveal the formation of novel complexes involving [Zr{sub 2}Cl{sub 9}]{sup -} and [Hf{sub 2}Cl{sub 9}]{sup -} anions in molten mixtures of ZrCl{sub 4} and HfCl{sub 4} with CsCl, RbCl, and KCl. A prediction is made about the presence of the above-mentioned complex anions in poorly investigated melts of the corresponding binary systems at high concentrations of ZrCl{sub 4} or HfCl{sub 4}.
Salyulev, A B;
Vovkotrub, Eh G;
Strekalovskij, V N
[1]
- UrO RAN, Inst. Vysokotemperaturnoj Ehlektrokhimii, Ekaterinburg (Russian Federation)
Citation Formats
Salyulev, A B, Vovkotrub, Eh G, and Strekalovskij, V N.
Interaction of zirconium and hafnium tetrachlorides with cesium, rubidium and potassium chlorides and Raman spectra of reaction products; Vzaimodejstvie tetrakhloridov tsirkoniya i gafniya s khloridami tseziya, rubidiya i kaliya i spektry KRS produktov reaktsij.
Russian Federation: N. p.,
2008.
Web.
Salyulev, A B, Vovkotrub, Eh G, & Strekalovskij, V N.
Interaction of zirconium and hafnium tetrachlorides with cesium, rubidium and potassium chlorides and Raman spectra of reaction products; Vzaimodejstvie tetrakhloridov tsirkoniya i gafniya s khloridami tseziya, rubidiya i kaliya i spektry KRS produktov reaktsij.
Russian Federation.
Salyulev, A B, Vovkotrub, Eh G, and Strekalovskij, V N.
2008.
"Interaction of zirconium and hafnium tetrachlorides with cesium, rubidium and potassium chlorides and Raman spectra of reaction products; Vzaimodejstvie tetrakhloridov tsirkoniya i gafniya s khloridami tseziya, rubidiya i kaliya i spektry KRS produktov reaktsij."
Russian Federation.
@misc{etde_21114635,
title = {Interaction of zirconium and hafnium tetrachlorides with cesium, rubidium and potassium chlorides and Raman spectra of reaction products; Vzaimodejstvie tetrakhloridov tsirkoniya i gafniya s khloridami tseziya, rubidiya i kaliya i spektry KRS produktov reaktsij}
author = {Salyulev, A B, Vovkotrub, Eh G, and Strekalovskij, V N}
abstractNote = {Raman spectroscopy was used to reveal the formation of novel complexes involving [Zr{sub 2}Cl{sub 9}]{sup -} and [Hf{sub 2}Cl{sub 9}]{sup -} anions in molten mixtures of ZrCl{sub 4} and HfCl{sub 4} with CsCl, RbCl, and KCl. A prediction is made about the presence of the above-mentioned complex anions in poorly investigated melts of the corresponding binary systems at high concentrations of ZrCl{sub 4} or HfCl{sub 4}.}
journal = []
issue = {3}
place = {Russian Federation}
year = {2008}
month = {May}
}
title = {Interaction of zirconium and hafnium tetrachlorides with cesium, rubidium and potassium chlorides and Raman spectra of reaction products; Vzaimodejstvie tetrakhloridov tsirkoniya i gafniya s khloridami tseziya, rubidiya i kaliya i spektry KRS produktov reaktsij}
author = {Salyulev, A B, Vovkotrub, Eh G, and Strekalovskij, V N}
abstractNote = {Raman spectroscopy was used to reveal the formation of novel complexes involving [Zr{sub 2}Cl{sub 9}]{sup -} and [Hf{sub 2}Cl{sub 9}]{sup -} anions in molten mixtures of ZrCl{sub 4} and HfCl{sub 4} with CsCl, RbCl, and KCl. A prediction is made about the presence of the above-mentioned complex anions in poorly investigated melts of the corresponding binary systems at high concentrations of ZrCl{sub 4} or HfCl{sub 4}.}
journal = []
issue = {3}
place = {Russian Federation}
year = {2008}
month = {May}
}