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Structural characterization and frictional properties of carbon nanotube/alumina composites prepared by precursor method

Abstract

Multi-walled carbon nanotube (MWCNT)/Al{sub 2}O{sub 3} composites with MWCNTs content up to 10 mass% were prepared by precursor method. XRD analysis revealed that MWCNT/Al{sub 2}O{sub 3} composites were successfully synthesized by the dehydration of aluminum hydroxide-MWCNTs mixture at 1500 deg. C in vacuum. The steady-state friction coefficient ({mu}) of the composites decreased with increasing up to 4 mass% MWCNT and stayed constant ({mu} = 0.33) with further addition of MWCNT, which value was substantially lower than that of MWCNT-free monolithic Al{sub 2}O{sub 3} ({mu} = 0.57). Microstructural observations showed that resultant friction behavior may be related to the smearing of transferred film over the contact area, which was expected to permit easy shear and then help to achieve a lubricating effect during sliding. However, fracture property tests have shown that no improvement of the fracture strength and fracture toughness of the composites was achieved by addition of MWCNTs. It may be mainly due to the agglomeration of MWCNTs and the weak interface between MWCNTs and the Al{sub 2}O{sub 3} matrix.
Authors:
Yamamoto, Go; [1]  Fracture and Reliability Research Institute, Tohoku University, 6-6-11-707 Aza-Aoba, Aramaki, Aobaku, Sendai 980-8579 (Japan)], E-mail: gyamamoto@rift.mech.tohoku.ac.jp; Omori, Mamoru; Yokomizo, Kenji; Hashida, Toshiyuki; [2]  Adachi, Koshi [3] 
  1. Institute of Fluid Science, Tohoku University, 2-1-1 Katahira, Aobaku, Sendai 980-8577 (Japan)
  2. Fracture and Reliability Research Institute, Tohoku University, 6-6-11-707 Aza-Aoba, Aramaki, Aobaku, Sendai 980-8579 (Japan)
  3. Graduate School of Engineering, Tohoku University, 6-6-01 Aza-Aoba, Aramaki, Aobaku, Sendai 980-8579 (Japan)
Publication Date:
Feb 25, 2008
Product Type:
Journal Article
Resource Relation:
Journal Name: Materials Science and Engineering. B, Solid-State Materials for Advanced Technology; Journal Volume: 148; Journal Issue: 1-3; Conference: STAC: 1. International conference on the science and technology for advanced ceramics; JTMC: 2. International conference on joining technology for new metallic glasses and inorganic materials, Kanagawa (Japan), 23-25 May 2007; Other Information: DOI: 10.1016/j.mseb.2007.09.013; PII: S0921-5107(07)00509-0; Copyright (c) 2007 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA)
Subject:
36 MATERIALS SCIENCE; AGGLOMERATION; ALUMINIUM HYDROXIDES; ALUMINIUM OXIDES; CARBON; DEHYDRATION; FILMS; FRACTURE PROPERTIES; FRICTION; FRICTION FACTOR; INTERFACES; MICROSTRUCTURE; MIXTURES; NANOTUBES; PRECURSOR; STEADY-STATE CONDITIONS; TEMPERATURE RANGE 1000-4000 K; X-RAY DIFFRACTION
OSTI ID:
21093956
Country of Origin:
Netherlands
Language:
English
Other Identifying Numbers:
Journal ID: ISSN 0921-5107; MSBTEK; TRN: NL08R3841104007
Availability:
Available from http://dx.doi.org/10.1016/j.mseb.2007.09.013;INIS
Submitting Site:
NLN
Size:
page(s) 265-269
Announcement Date:
Nov 13, 2008

Citation Formats

Yamamoto, Go, Fracture and Reliability Research Institute, Tohoku University, 6-6-11-707 Aza-Aoba, Aramaki, Aobaku, Sendai 980-8579 (Japan)], E-mail: gyamamoto@rift.mech.tohoku.ac.jp, Omori, Mamoru, Yokomizo, Kenji, Hashida, Toshiyuki, and Adachi, Koshi. Structural characterization and frictional properties of carbon nanotube/alumina composites prepared by precursor method. Netherlands: N. p., 2008. Web. doi:10.1016/j.mseb.2007.09.013.
Yamamoto, Go, Fracture and Reliability Research Institute, Tohoku University, 6-6-11-707 Aza-Aoba, Aramaki, Aobaku, Sendai 980-8579 (Japan)], E-mail: gyamamoto@rift.mech.tohoku.ac.jp, Omori, Mamoru, Yokomizo, Kenji, Hashida, Toshiyuki, & Adachi, Koshi. Structural characterization and frictional properties of carbon nanotube/alumina composites prepared by precursor method. Netherlands. https://doi.org/10.1016/j.mseb.2007.09.013
Yamamoto, Go, Fracture and Reliability Research Institute, Tohoku University, 6-6-11-707 Aza-Aoba, Aramaki, Aobaku, Sendai 980-8579 (Japan)], E-mail: gyamamoto@rift.mech.tohoku.ac.jp, Omori, Mamoru, Yokomizo, Kenji, Hashida, Toshiyuki, and Adachi, Koshi. 2008. "Structural characterization and frictional properties of carbon nanotube/alumina composites prepared by precursor method." Netherlands. https://doi.org/10.1016/j.mseb.2007.09.013.
@misc{etde_21093956,
title = {Structural characterization and frictional properties of carbon nanotube/alumina composites prepared by precursor method}
author = {Yamamoto, Go, Fracture and Reliability Research Institute, Tohoku University, 6-6-11-707 Aza-Aoba, Aramaki, Aobaku, Sendai 980-8579 (Japan)], E-mail: gyamamoto@rift.mech.tohoku.ac.jp, Omori, Mamoru, Yokomizo, Kenji, Hashida, Toshiyuki, and Adachi, Koshi}
abstractNote = {Multi-walled carbon nanotube (MWCNT)/Al{sub 2}O{sub 3} composites with MWCNTs content up to 10 mass% were prepared by precursor method. XRD analysis revealed that MWCNT/Al{sub 2}O{sub 3} composites were successfully synthesized by the dehydration of aluminum hydroxide-MWCNTs mixture at 1500 deg. C in vacuum. The steady-state friction coefficient ({mu}) of the composites decreased with increasing up to 4 mass% MWCNT and stayed constant ({mu} = 0.33) with further addition of MWCNT, which value was substantially lower than that of MWCNT-free monolithic Al{sub 2}O{sub 3} ({mu} = 0.57). Microstructural observations showed that resultant friction behavior may be related to the smearing of transferred film over the contact area, which was expected to permit easy shear and then help to achieve a lubricating effect during sliding. However, fracture property tests have shown that no improvement of the fracture strength and fracture toughness of the composites was achieved by addition of MWCNTs. It may be mainly due to the agglomeration of MWCNTs and the weak interface between MWCNTs and the Al{sub 2}O{sub 3} matrix.}
doi = {10.1016/j.mseb.2007.09.013}
journal = []
issue = {1-3}
volume = {148}
place = {Netherlands}
year = {2008}
month = {Feb}
}