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Amorphous infinite coordination polymer microparticles: a new class of selective hydrogen storage materials

Abstract

A new class of micrometer-sized amorphous infinite coordination particles is selectively prepared from the coordination chemistry of a metallo-salen building block and Zn{sup 2+} ions. The particles show moderately high H{sub 2} uptake and almost no N{sub 2} adsorption, even though they are amorphous and do not have the well-defined channels typically used to explain such selectivity in metal-organic framework systems. (Abstract Copyright [2008], Wiley Periodicals, Inc.)
Authors:
Jeon, You-Moon; Heo, Jungseok; Mirkin, Chad A; [1]  Armatas, Gerasimos S; [2]  Kanatzidis, Mercouri G [3] 
  1. Department of Chemistry, International Institute for Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, IL (United States)
  2. Department of Chemistry, Northwestern University, Evanston, IL (United States)
  3. Materials Science Division, Argonne National Laboratory, Argonne, IL (United States)
Publication Date:
Jun 04, 2008
Product Type:
Journal Article
Resource Relation:
Journal Name: Advanced Materials (Weinheim); Journal Volume: 20; Journal Issue: 11; Other Information: With 3 figs., 0 tabs., 25 refs.. SICI: 0935-9648(20080604)20:11<2105::AID-ADMA200702605>3.0.TX;2-O
Subject:
08 HYDROGEN; POLYMERS; HYDROGEN STORAGE
OSTI ID:
21058849
Country of Origin:
Germany
Language:
English
Other Identifying Numbers:
Journal ID: ISSN 0935-9648; ADVMEW; TRN: DE08G7585
Availability:
Available from: http://dx.doi.org/10.1002/adma.200702605
Submitting Site:
DE
Size:
page(s) 2105-2110
Announcement Date:
Jul 24, 2008

Citation Formats

Jeon, You-Moon, Heo, Jungseok, Mirkin, Chad A, Armatas, Gerasimos S, and Kanatzidis, Mercouri G. Amorphous infinite coordination polymer microparticles: a new class of selective hydrogen storage materials. Germany: N. p., 2008. Web. doi:10.1002/ADMA.200702605.
Jeon, You-Moon, Heo, Jungseok, Mirkin, Chad A, Armatas, Gerasimos S, & Kanatzidis, Mercouri G. Amorphous infinite coordination polymer microparticles: a new class of selective hydrogen storage materials. Germany. doi:10.1002/ADMA.200702605.
Jeon, You-Moon, Heo, Jungseok, Mirkin, Chad A, Armatas, Gerasimos S, and Kanatzidis, Mercouri G. 2008. "Amorphous infinite coordination polymer microparticles: a new class of selective hydrogen storage materials." Germany. doi:10.1002/ADMA.200702605. https://www.osti.gov/servlets/purl/10.1002/ADMA.200702605.
@misc{etde_21058849,
title = {Amorphous infinite coordination polymer microparticles: a new class of selective hydrogen storage materials}
author = {Jeon, You-Moon, Heo, Jungseok, Mirkin, Chad A, Armatas, Gerasimos S, and Kanatzidis, Mercouri G}
abstractNote = {A new class of micrometer-sized amorphous infinite coordination particles is selectively prepared from the coordination chemistry of a metallo-salen building block and Zn{sup 2+} ions. The particles show moderately high H{sub 2} uptake and almost no N{sub 2} adsorption, even though they are amorphous and do not have the well-defined channels typically used to explain such selectivity in metal-organic framework systems. (Abstract Copyright [2008], Wiley Periodicals, Inc.)}
doi = {10.1002/ADMA.200702605}
journal = {Advanced Materials (Weinheim)}
issue = {11}
volume = {20}
place = {Germany}
year = {2008}
month = {Jun}
}