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Greenhouse gases regional fluxes estimated from atmospheric measurements; Estimation des flux de gaz a effet de serre a l'echelle regionale a partir de mesures atmospheriques

Abstract

build up a new system to measure continuously CO{sub 2} (or CO), CH{sub 4}, N{sub 2}O and SF{sub 6} mixing ratios. It is based on a commercial gas chromatograph (Agilent 6890N) which have been modified to reach better precision. Reproducibility computed with a target gas on a 24 hours time step gives: 0.06 ppm for CO{sub 2}, 1.4 ppb for CO, 0.7 ppb for CH{sub 4}, 0.2 ppb for N{sub 2}O and 0.05 ppt for SF{sub 6}. The instrument's run is fully automated, an air sample analysis takes about 5 minutes. In July 2006, I install instrumentation on a telecommunication tall tower (200 m) situated near Orleans forest in Trainou, to monitor continuously greenhouse gases (CO{sub 2}, CH{sub 4}, N{sub 2}O, SF{sub 6}), atmospheric tracers (CO, Radon-222) and meteorological parameters. Intake lines were installed at 3 levels (50, 100 and 180 m) and allow us to sample air masses along the vertical. Continuous measurement started in January 2007. I used Mace Head (Ireland) and Gif-sur-Yvette continuous measurements to estimate major greenhouse gases emission fluxes at regional scale. To make the link between atmospheric measurements and surface fluxes, we need to quantify dilution due to atmospheric transport. I used Radon-222 as  More>>
Authors:
Publication Date:
Jul 15, 2007
Product Type:
Thesis/Dissertation
Report Number:
FRNC-TH-7217
Resource Relation:
Other Information: TH: These Chimie de la pollution atmospherique et physique de l'environnement; [120 refs.]; Also available from Bibliotheque de l'Universite Paris Diderot-Paris 7, 5, rue Thomas Mann Case 7051 Batiment Les Grands Moulins 75013 - Paris, 75205 Paris Cedex 13 (France)
Subject:
54 ENVIRONMENTAL SCIENCES; AIR POLLUTION MONITORING; BOUNDARY LAYERS; CALIBRATION; CARBON OXIDES; DAILY VARIATIONS; DILUTION; GAS CHROMATOGRAPHY; METEOROLOGY; METHANE; NITROUS OXIDE; POLLUTION SOURCES; RADON 222; SEASONAL VARIATIONS; SULFUR FLUORIDES; TRACER TECHNIQUES
OSTI ID:
20992641
Research Organizations:
Paris-7 Univ. Denis Diderot, 75 (France)
Country of Origin:
France
Language:
French
Other Identifying Numbers:
TRN: FR0704436016571
Availability:
Available from INIS in electronic form
Submitting Site:
FRN
Size:
176 pages
Announcement Date:
Mar 27, 2008

Citation Formats

Messager, C. Greenhouse gases regional fluxes estimated from atmospheric measurements; Estimation des flux de gaz a effet de serre a l'echelle regionale a partir de mesures atmospheriques. France: N. p., 2007. Web.
Messager, C. Greenhouse gases regional fluxes estimated from atmospheric measurements; Estimation des flux de gaz a effet de serre a l'echelle regionale a partir de mesures atmospheriques. France.
Messager, C. 2007. "Greenhouse gases regional fluxes estimated from atmospheric measurements; Estimation des flux de gaz a effet de serre a l'echelle regionale a partir de mesures atmospheriques." France.
@misc{etde_20992641,
title = {Greenhouse gases regional fluxes estimated from atmospheric measurements; Estimation des flux de gaz a effet de serre a l'echelle regionale a partir de mesures atmospheriques}
author = {Messager, C}
abstractNote = {build up a new system to measure continuously CO{sub 2} (or CO), CH{sub 4}, N{sub 2}O and SF{sub 6} mixing ratios. It is based on a commercial gas chromatograph (Agilent 6890N) which have been modified to reach better precision. Reproducibility computed with a target gas on a 24 hours time step gives: 0.06 ppm for CO{sub 2}, 1.4 ppb for CO, 0.7 ppb for CH{sub 4}, 0.2 ppb for N{sub 2}O and 0.05 ppt for SF{sub 6}. The instrument's run is fully automated, an air sample analysis takes about 5 minutes. In July 2006, I install instrumentation on a telecommunication tall tower (200 m) situated near Orleans forest in Trainou, to monitor continuously greenhouse gases (CO{sub 2}, CH{sub 4}, N{sub 2}O, SF{sub 6}), atmospheric tracers (CO, Radon-222) and meteorological parameters. Intake lines were installed at 3 levels (50, 100 and 180 m) and allow us to sample air masses along the vertical. Continuous measurement started in January 2007. I used Mace Head (Ireland) and Gif-sur-Yvette continuous measurements to estimate major greenhouse gases emission fluxes at regional scale. To make the link between atmospheric measurements and surface fluxes, we need to quantify dilution due to atmospheric transport. I used Radon-222 as tracer (radon tracer method) and planetary boundary layer heights estimates from ECMWF model (boundary layer budget method) to parameterize atmospheric transport. In both cases I compared results to available emission inventories. (author)}
place = {France}
year = {2007}
month = {Jul}
}