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Rapid quantification of polycyclic aromatic hydrocarbons in hydroxypropyl-{beta}-cyclodextrin (HPCD) soil extracts by synchronous fluorescence spectroscopy (SFS)

Journal Article:

Abstract

Synchronous fluorescence spectroscopy (SFS) was directly applied to rapidly quantify selected polycyclic aromatic hydrocarbons (PAHs: benzo[a]pyrene and pyrene) in aqueous hydroxypropyl-{beta}-cyclodextrin (HPCD) soil extract solutions from a variety of aged contaminated soils containing four different PAHs. The method was optimized and validated. The results show that SFS can be used to analyse benzo[a]pyrene and pyrene in HPCD based soil extracts with high sensitivity and selectivity. The linear calibration ranges were 4.0 x 10{sup -6}-1.0 x 10{sup -3} mM for benzo[a]pyrene and 6.0 x 10{sup -6}-1.2 x 10{sup -3} mM for pyrene in 10 mM HPCD aqueous solution alone. The detection limits according to the error propagation theory for benzo[a]pyrene and pyrene were 3.9 x 10{sup -6} and 5.4 x 10{sup -6} mM, respectively. A good agreement between SFS and HPLC was reached for both determinations of PAHs in HPCD alone and in soil HPCD extracts. Hence, SFS is a potential means to simplify the present non-exhaustive hydroxypropyl-{beta}-cyclodextrin (HPCD)-based extraction technique for the evaluation of PAH bioavailability in soil. - SFS can be used to rapidly quantify selected PAHs in soil extracts and to simplify the non-exhaustive HPCD-based extraction technique for the evaluation of PAH bioavailability.
Authors:
Guoxiong, Hua; [1]  Broderick, John; [1]  Semple, Kirk T; [2]  Killham, Ken; [3]  Singleton, Ian [1] 
  1. School of Biology and Psychology, Institute for Research on Environment and Sustainability, Newcastle University, Newcastle upon Tyne NE1 7RU (United Kingdom)
  2. Department of Environmental Science, Faculty of Science and Technology, University of Lancaster, Lancaster LA1 4YQ (United Kingdom)
  3. School of Biological Sciences, University of Aberdeen, Aberdeen AB24 3UU (United Kingdom)
Publication Date:
Jul 15, 2007
Product Type:
Journal Article
Resource Relation:
Journal Name: Environmental Pollution (1987); Journal Volume: 148; Journal Issue: 1; Other Information: DOI: 10.1016/j.envpol.2006.10.040; PII: S0269-7491(06)00595-1; Copyright (c) 2006 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA)
Subject:
60 APPLIED LIFE SCIENCES; AQUEOUS SOLUTIONS; BIOLOGICAL AVAILABILITY; BIOREMEDIATION; CALIBRATION; ELDERLY PEOPLE; ERRORS; EVALUATION; EXTRACTION; FLUORESCENCE SPECTROSCOPY; HIGH-PERFORMANCE LIQUID CHROMATOGRAPHY; POLYCYCLIC AROMATIC HYDROCARBONS; PYRENE; SENSITIVITY; SOILS
OSTI ID:
20973283
Country of Origin:
United Kingdom
Language:
English
Other Identifying Numbers:
Journal ID: ISSN 0269-7491; ENPOEK; TRN: GB07R5850002721
Submitting Site:
GBN
Size:
page(s) 176-181
Announcement Date:
Feb 07, 2008

Journal Article:

Citation Formats

Guoxiong, Hua, Broderick, John, Semple, Kirk T, Killham, Ken, and Singleton, Ian. Rapid quantification of polycyclic aromatic hydrocarbons in hydroxypropyl-{beta}-cyclodextrin (HPCD) soil extracts by synchronous fluorescence spectroscopy (SFS). United Kingdom: N. p., 2007. Web.
Guoxiong, Hua, Broderick, John, Semple, Kirk T, Killham, Ken, & Singleton, Ian. Rapid quantification of polycyclic aromatic hydrocarbons in hydroxypropyl-{beta}-cyclodextrin (HPCD) soil extracts by synchronous fluorescence spectroscopy (SFS). United Kingdom.
Guoxiong, Hua, Broderick, John, Semple, Kirk T, Killham, Ken, and Singleton, Ian. 2007. "Rapid quantification of polycyclic aromatic hydrocarbons in hydroxypropyl-{beta}-cyclodextrin (HPCD) soil extracts by synchronous fluorescence spectroscopy (SFS)." United Kingdom.
@misc{etde_20973283,
title = {Rapid quantification of polycyclic aromatic hydrocarbons in hydroxypropyl-{beta}-cyclodextrin (HPCD) soil extracts by synchronous fluorescence spectroscopy (SFS)}
author = {Guoxiong, Hua, Broderick, John, Semple, Kirk T, Killham, Ken, and Singleton, Ian}
abstractNote = {Synchronous fluorescence spectroscopy (SFS) was directly applied to rapidly quantify selected polycyclic aromatic hydrocarbons (PAHs: benzo[a]pyrene and pyrene) in aqueous hydroxypropyl-{beta}-cyclodextrin (HPCD) soil extract solutions from a variety of aged contaminated soils containing four different PAHs. The method was optimized and validated. The results show that SFS can be used to analyse benzo[a]pyrene and pyrene in HPCD based soil extracts with high sensitivity and selectivity. The linear calibration ranges were 4.0 x 10{sup -6}-1.0 x 10{sup -3} mM for benzo[a]pyrene and 6.0 x 10{sup -6}-1.2 x 10{sup -3} mM for pyrene in 10 mM HPCD aqueous solution alone. The detection limits according to the error propagation theory for benzo[a]pyrene and pyrene were 3.9 x 10{sup -6} and 5.4 x 10{sup -6} mM, respectively. A good agreement between SFS and HPLC was reached for both determinations of PAHs in HPCD alone and in soil HPCD extracts. Hence, SFS is a potential means to simplify the present non-exhaustive hydroxypropyl-{beta}-cyclodextrin (HPCD)-based extraction technique for the evaluation of PAH bioavailability in soil. - SFS can be used to rapidly quantify selected PAHs in soil extracts and to simplify the non-exhaustive HPCD-based extraction technique for the evaluation of PAH bioavailability.}
journal = {Environmental Pollution (1987)}
issue = {1}
volume = {148}
place = {United Kingdom}
year = {2007}
month = {Jul}
}