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Extraction and purification of plutonium by a tertiary amine; Extraction et purification du plutonium par une amine tertiaire

Abstract

Trilaurylamine diluted with a paraffinic solvent (dodecane) was studied as part of the research dealing with the separation and purification of plutonium. The physical properties (solubility of nitrates in the amine as a function of temperature) and the resistance to radiations of this substance were examined. The extraction characteristics of nitric solutions of plutonium, uranium and certain fission products are given as a function of the following factors: concentration of the various ions in solution, valency states. A method of plutonium purification based on these results is presented. (author) [French] La trilaurylamine diluee par un solvant paraffinique (dodecane) a ete etudiee dans le cadre des recherches concernant la separation et la purification du plutonium. Une etude des caracteres physiques (solubilite des nitrates dans l'amine en fonction de la temperature) s'ajoute a celle de la tenue aux radiations de ce corps. Les caracteristiques d'extraction de solutions nitriques de plutonium, uranium, et certains produits de fission, sont donnes en fonction des facteurs suivants: concentration des differents ions en solution, etats de valence. On presente une methode de purification du plutonium basee sur ces resultats. (auteur)
Authors:
Trentinian, M de; Chesne, A; [1]  Commissariat a l'Energie Atomique, Saclay (France).Centre d'Etudes Nucleaires]
  1. Commissariat a l'Energie Atomique, Fontenay aux Roses, Section de Chimie des Actimides (France).Centre d'Etudes Nucleaires
Publication Date:
Jul 01, 1960
Product Type:
Technical Report
Report Number:
CEA-R-1426
Resource Relation:
Other Information: 5 refs
Subject:
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; AQUEOUS SOLUTIONS; COMPARATIVE EVALUATIONS; DECONTAMINATION; DODECANE; EFFICIENCY; FISSION PRODUCTS; HOT ATOM CHEMISTRY; MULTI-ELEMENT SEPARATION; ORGANIC SOLVENTS; PARTITION; PLUTONIUM; PLUTONIUM IONS; PURIFICATION; SATURATION; SOLVENT EXTRACTION; TBP; TRIDODECYLAMINE; URANIUM; URANYL NITRATES; VALENCE
OSTI ID:
20943005
Research Organizations:
CEA Saclay, 91 - Gif-sur-Yvette (France); CEA Fontenay-aux-Roses, 92 (France)
Country of Origin:
France
Language:
French
Other Identifying Numbers:
TRN: FR07R1426096458
Availability:
Available from INIS in electronic form
Submitting Site:
FRN
Size:
16 pages
Announcement Date:
Dec 13, 2007

Citation Formats

Trentinian, M de, Chesne, A, and Commissariat a l'Energie Atomique, Saclay (France).Centre d'Etudes Nucleaires]. Extraction and purification of plutonium by a tertiary amine; Extraction et purification du plutonium par une amine tertiaire. France: N. p., 1960. Web.
Trentinian, M de, Chesne, A, & Commissariat a l'Energie Atomique, Saclay (France).Centre d'Etudes Nucleaires]. Extraction and purification of plutonium by a tertiary amine; Extraction et purification du plutonium par une amine tertiaire. France.
Trentinian, M de, Chesne, A, and Commissariat a l'Energie Atomique, Saclay (France).Centre d'Etudes Nucleaires]. 1960. "Extraction and purification of plutonium by a tertiary amine; Extraction et purification du plutonium par une amine tertiaire." France.
@misc{etde_20943005,
title = {Extraction and purification of plutonium by a tertiary amine; Extraction et purification du plutonium par une amine tertiaire}
author = {Trentinian, M de, Chesne, A, and Commissariat a l'Energie Atomique, Saclay (France).Centre d'Etudes Nucleaires]}
abstractNote = {Trilaurylamine diluted with a paraffinic solvent (dodecane) was studied as part of the research dealing with the separation and purification of plutonium. The physical properties (solubility of nitrates in the amine as a function of temperature) and the resistance to radiations of this substance were examined. The extraction characteristics of nitric solutions of plutonium, uranium and certain fission products are given as a function of the following factors: concentration of the various ions in solution, valency states. A method of plutonium purification based on these results is presented. (author) [French] La trilaurylamine diluee par un solvant paraffinique (dodecane) a ete etudiee dans le cadre des recherches concernant la separation et la purification du plutonium. Une etude des caracteres physiques (solubilite des nitrates dans l'amine en fonction de la temperature) s'ajoute a celle de la tenue aux radiations de ce corps. Les caracteristiques d'extraction de solutions nitriques de plutonium, uranium, et certains produits de fission, sont donnes en fonction des facteurs suivants: concentration des differents ions en solution, etats de valence. On presente une methode de purification du plutonium basee sur ces resultats. (auteur)}
place = {France}
year = {1960}
month = {Jul}
}