Abstract
The study of the use of ion exchangers at high temperature has been carried out mainly with a view to purifying water in reactor circuits. The advantages of keeping high resistivity (from many hundreds to a few million ohm-cm) water within a reactor circuit are known; the decreased corrosion reduction in the amount of radiolysis, decreased radioactivity in the circuits and piping, the elements other than those forming water which are carried with the water usually becoming radioactive as they pass through the reactor. If the water circulation takes place at temperatures less than 75 deg. C continuous purification can be easily carried out by using organic ion exchange resins in agitated beds. However at higher temperatures particularly those above 100 deg. C it is not possible to use these media because of the rapid degradation of the high polymers used. Also the action of the radiation, for example that emanating from the products fixed on the ion exchange media permanently destroys the organic chains making up the skeleton of the resins. We have therefore sought after other compounds which are efficient demineralizer, but which have a structure such that high temperature and radiation do not bring about deterioration. We
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Hure, J;
Platzer, R;
Bittel, R;
[1]
Fourre, J;
[2]
Wey, R
[3]
- Commissariat a l'Energie Atomique, Saclay (France). Centre d'Etudes Nucleaires
- Societe le Carbone Lorraine, 75 - Paris (France)
- Faculte des Sciences de Strasbourg, Lab. de Mineralogie, 67 (France)
Citation Formats
Hure, J, Platzer, R, Bittel, R, Fourre, J, and Wey, R.
Study of some ion exchange minerals which can be used in water at high temperature; Etude de quelques echangeurs mineraux utilisables dans l'eau a haute temperature.
France: N. p.,
1958.
Web.
Hure, J, Platzer, R, Bittel, R, Fourre, J, & Wey, R.
Study of some ion exchange minerals which can be used in water at high temperature; Etude de quelques echangeurs mineraux utilisables dans l'eau a haute temperature.
France.
Hure, J, Platzer, R, Bittel, R, Fourre, J, and Wey, R.
1958.
"Study of some ion exchange minerals which can be used in water at high temperature; Etude de quelques echangeurs mineraux utilisables dans l'eau a haute temperature."
France.
@misc{etde_20900971,
title = {Study of some ion exchange minerals which can be used in water at high temperature; Etude de quelques echangeurs mineraux utilisables dans l'eau a haute temperature}
author = {Hure, J, Platzer, R, Bittel, R, Fourre, J, and Wey, R}
abstractNote = {The study of the use of ion exchangers at high temperature has been carried out mainly with a view to purifying water in reactor circuits. The advantages of keeping high resistivity (from many hundreds to a few million ohm-cm) water within a reactor circuit are known; the decreased corrosion reduction in the amount of radiolysis, decreased radioactivity in the circuits and piping, the elements other than those forming water which are carried with the water usually becoming radioactive as they pass through the reactor. If the water circulation takes place at temperatures less than 75 deg. C continuous purification can be easily carried out by using organic ion exchange resins in agitated beds. However at higher temperatures particularly those above 100 deg. C it is not possible to use these media because of the rapid degradation of the high polymers used. Also the action of the radiation, for example that emanating from the products fixed on the ion exchange media permanently destroys the organic chains making up the skeleton of the resins. We have therefore sought after other compounds which are efficient demineralizer, but which have a structure such that high temperature and radiation do not bring about deterioration. We have especially investigated t main types: - natural ion exchangers having an inorganic structure (montmorillonite type clays); - natural inorganic compounds which have been treated to give them ion exchange properties (activated carbons); - synthetic inorganic compounds (salts having a low solubility such as zirconium and thorium phosphates and hydroxides). In this research we have endeavoured to obtain products which are stable in the presence of water at high temperatures, insoluble and not broken down into fine particles (that is to say not polluting the high resistivity water) and which are capable of giving up H{sup +} or OH{sup -} ions in exchange for the ions contained in the water or at least capable of forming insoluble compounds with these impurities (that is to say capable of de-mineralizing polluted water). This paper describes the preliminary results of the investigation. (author) [French] L'etude de l'utilisation des echangeurs d'ions a haute temperature a ete essentiellement faite en vue de l'epuration de l'eau des reacteurs. On connait l'interet qu'il y a a garder dans un circuit de reacteur de l'eau de tres haute resistivite (plusieurs centaines a quelques millions {omega}.cm): abaissement de la corrosion, abaissement du taux de radiolyse, abaissement de la radioactivite des circuits et canalisations, les elements autres que les constituants de l'eau transportes par celle-ci devenant generalement radioactifs par leur passage au coeur du reacteur. Si la circulation d'eau se fait a des temperatures inferieures a 45 deg. C, les resines echangeuses d'ions organiques utilisees en lit melange resolvent tres bien le probleme de l'epuration en continu. Par contre, pour des temperatures plus elevees surtout au-dessus de 100 deg. C, leur utilisation n'est pas possible, la degradation de ces hauts polymeres etant tres rapide. De meme, l'action des rayonnements, par exemple ceux des produits fixes par les echangeurs d'ions, detruit irremediablement les chaines organiques constituant le squelette de ces echangeurs. Nous avons donc cherche d'es composes pouvant assurer une bonne deionisation de l'eau, mais de structures telles qu'elles ne soient pas deteriorees par l'action de la temperature et des rayonnements. Nous nous sommes particulierement orientes dans trois voies: - echangeurs d'ions naturels a structure minerale (argile du type montmorillonite), - composes mineraux naturels traites pour leur conferer les proprietes d'echangeurs d'ions (charbons actives), - composes mineraux synthetiques (sels tres peu solubles, phosphate et hydroxyde de zirconium et de thorium). Dans ces etudes, nous nous sommes attaches a obtenir des produits stables en presence d'eau a haute temperature, tres insolubles et non disperses en fines particules (c'est-a-dire ne polluant pas une eau de haute resistivite) et capables d'echanger contre des ions H{sup +} ou OH{sup -} les ions contenus dans l'eau, ou tout au moins de former avec eux des composes insolubles (c'est-a-dire capables de deioniser une eau polluee). Ce sont les premiers resultats de ces etudes que nous allons decrire. (auteur)}
place = {France}
year = {1958}
month = {Jul}
}
title = {Study of some ion exchange minerals which can be used in water at high temperature; Etude de quelques echangeurs mineraux utilisables dans l'eau a haute temperature}
author = {Hure, J, Platzer, R, Bittel, R, Fourre, J, and Wey, R}
abstractNote = {The study of the use of ion exchangers at high temperature has been carried out mainly with a view to purifying water in reactor circuits. The advantages of keeping high resistivity (from many hundreds to a few million ohm-cm) water within a reactor circuit are known; the decreased corrosion reduction in the amount of radiolysis, decreased radioactivity in the circuits and piping, the elements other than those forming water which are carried with the water usually becoming radioactive as they pass through the reactor. If the water circulation takes place at temperatures less than 75 deg. C continuous purification can be easily carried out by using organic ion exchange resins in agitated beds. However at higher temperatures particularly those above 100 deg. C it is not possible to use these media because of the rapid degradation of the high polymers used. Also the action of the radiation, for example that emanating from the products fixed on the ion exchange media permanently destroys the organic chains making up the skeleton of the resins. We have therefore sought after other compounds which are efficient demineralizer, but which have a structure such that high temperature and radiation do not bring about deterioration. We have especially investigated t main types: - natural ion exchangers having an inorganic structure (montmorillonite type clays); - natural inorganic compounds which have been treated to give them ion exchange properties (activated carbons); - synthetic inorganic compounds (salts having a low solubility such as zirconium and thorium phosphates and hydroxides). In this research we have endeavoured to obtain products which are stable in the presence of water at high temperatures, insoluble and not broken down into fine particles (that is to say not polluting the high resistivity water) and which are capable of giving up H{sup +} or OH{sup -} ions in exchange for the ions contained in the water or at least capable of forming insoluble compounds with these impurities (that is to say capable of de-mineralizing polluted water). This paper describes the preliminary results of the investigation. (author) [French] L'etude de l'utilisation des echangeurs d'ions a haute temperature a ete essentiellement faite en vue de l'epuration de l'eau des reacteurs. On connait l'interet qu'il y a a garder dans un circuit de reacteur de l'eau de tres haute resistivite (plusieurs centaines a quelques millions {omega}.cm): abaissement de la corrosion, abaissement du taux de radiolyse, abaissement de la radioactivite des circuits et canalisations, les elements autres que les constituants de l'eau transportes par celle-ci devenant generalement radioactifs par leur passage au coeur du reacteur. Si la circulation d'eau se fait a des temperatures inferieures a 45 deg. C, les resines echangeuses d'ions organiques utilisees en lit melange resolvent tres bien le probleme de l'epuration en continu. Par contre, pour des temperatures plus elevees surtout au-dessus de 100 deg. C, leur utilisation n'est pas possible, la degradation de ces hauts polymeres etant tres rapide. De meme, l'action des rayonnements, par exemple ceux des produits fixes par les echangeurs d'ions, detruit irremediablement les chaines organiques constituant le squelette de ces echangeurs. Nous avons donc cherche d'es composes pouvant assurer une bonne deionisation de l'eau, mais de structures telles qu'elles ne soient pas deteriorees par l'action de la temperature et des rayonnements. Nous nous sommes particulierement orientes dans trois voies: - echangeurs d'ions naturels a structure minerale (argile du type montmorillonite), - composes mineraux naturels traites pour leur conferer les proprietes d'echangeurs d'ions (charbons actives), - composes mineraux synthetiques (sels tres peu solubles, phosphate et hydroxyde de zirconium et de thorium). Dans ces etudes, nous nous sommes attaches a obtenir des produits stables en presence d'eau a haute temperature, tres insolubles et non disperses en fines particules (c'est-a-dire ne polluant pas une eau de haute resistivite) et capables d'echanger contre des ions H{sup +} ou OH{sup -} les ions contenus dans l'eau, ou tout au moins de former avec eux des composes insolubles (c'est-a-dire capables de deioniser une eau polluee). Ce sont les premiers resultats de ces etudes que nous allons decrire. (auteur)}
place = {France}
year = {1958}
month = {Jul}
}