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Assessment of metal concentrations in sediment samples from Billings Reservoir, Rio Grande tributary, Sao Paulo, Brazil; Avaliacao da concentracao de metais em amostras de sedimento do Reservatorio Billings, Braco Rio Grande, Sao Paulo, Brasil

Abstract

The present study chemically characterized sediment samples from the Billings reservoir, Rio Grande tributary, in the Metropolitan region of Sao Paulo, by determining metal concentration and other elements of interest. The chosen chemical parameters for this characterization were Aluminum, Arsenic, Barium, Cadmium, Copper, Chromium, Iron, Lead, Manganese, Mercury, Nickel, Selenium and Zinco. These parameters are also used in the water quality index, with the exception of Selenium. The concentrations were determined through different analytical techniques such as atomic absorption spectrometry (FAAS, GFAAS and CVAAS), optical emission spectrometry (ICP OES) and neutron activation analysis. These analytical methodologies were assessed for precision, accuracy and detection and/or quantification limits for the sediment elements in question. Advantages and disadvantages of each technique for each element and its concentration were also discussed. From these assessments the most adequate technique was selected for the routine analysis of sediment samples for each element concentration determination. This assessment verified also that digestion in a closed microwave system with nitric acid is efficient for the evaluation of extracted metals of environmental interest. The analytical techniques chosen were equally efficient for metals determination. In the case of Cd and Pb, the FAAS technique was selected due to better results than  More>>
Publication Date:
Jul 01, 2006
Product Type:
Thesis/Dissertation
Report Number:
INIS-BR-4154
Resource Relation:
Other Information: TH: Dissertacao (M.Sc.); refs., 48 figs., 32 tabs
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ABSORPTION SPECTROSCOPY; CALIBRATION STANDARDS; CONCENTRATION RATIO; ELEMENT ABUNDANCE; EXPERIMENTAL DATA; METALS; NEUTRON ACTIVATION ANALYSIS; SEDIMENTS; TRACE AMOUNTS; WATER POLLUTION; WATER RESERVOIRS
OSTI ID:
20899055
Research Organizations:
Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil)
Country of Origin:
Brazil
Language:
Portuguese
Other Identifying Numbers:
TRN: BR0746411061243
Availability:
Available from INIS in electronic form; Also available from the Library of the Brazilian Nuclear and Energy Research Institute (CNEN/IPEN-SP), Sao Paulo, SP
Submitting Site:
BRN
Size:
130 pages
Announcement Date:
Aug 28, 2007

Citation Formats

Bostelmann, Eleine. Assessment of metal concentrations in sediment samples from Billings Reservoir, Rio Grande tributary, Sao Paulo, Brazil; Avaliacao da concentracao de metais em amostras de sedimento do Reservatorio Billings, Braco Rio Grande, Sao Paulo, Brasil. Brazil: N. p., 2006. Web.
Bostelmann, Eleine. Assessment of metal concentrations in sediment samples from Billings Reservoir, Rio Grande tributary, Sao Paulo, Brazil; Avaliacao da concentracao de metais em amostras de sedimento do Reservatorio Billings, Braco Rio Grande, Sao Paulo, Brasil. Brazil.
Bostelmann, Eleine. 2006. "Assessment of metal concentrations in sediment samples from Billings Reservoir, Rio Grande tributary, Sao Paulo, Brazil; Avaliacao da concentracao de metais em amostras de sedimento do Reservatorio Billings, Braco Rio Grande, Sao Paulo, Brasil." Brazil.
@misc{etde_20899055,
title = {Assessment of metal concentrations in sediment samples from Billings Reservoir, Rio Grande tributary, Sao Paulo, Brazil; Avaliacao da concentracao de metais em amostras de sedimento do Reservatorio Billings, Braco Rio Grande, Sao Paulo, Brasil}
author = {Bostelmann, Eleine}
abstractNote = {The present study chemically characterized sediment samples from the Billings reservoir, Rio Grande tributary, in the Metropolitan region of Sao Paulo, by determining metal concentration and other elements of interest. The chosen chemical parameters for this characterization were Aluminum, Arsenic, Barium, Cadmium, Copper, Chromium, Iron, Lead, Manganese, Mercury, Nickel, Selenium and Zinco. These parameters are also used in the water quality index, with the exception of Selenium. The concentrations were determined through different analytical techniques such as atomic absorption spectrometry (FAAS, GFAAS and CVAAS), optical emission spectrometry (ICP OES) and neutron activation analysis. These analytical methodologies were assessed for precision, accuracy and detection and/or quantification limits for the sediment elements in question. Advantages and disadvantages of each technique for each element and its concentration were also discussed. From these assessments the most adequate technique was selected for the routine analysis of sediment samples for each element concentration determination. This assessment verified also that digestion in a closed microwave system with nitric acid is efficient for the evaluation of extracted metals of environmental interest. The analytical techniques chosen were equally efficient for metals determination. In the case of Cd and Pb, the FAAS technique was selected due to better results than ICP OES, as it does not present matrix interference. The concentration values obtained for metals As, Cd, Cu, Cr, Hg, Ni, Pb and Zn in the sediment samples were compared to Canadian Council of Minister of the Environment (CCME) TEL and PEL values. (author)}
place = {Brazil}
year = {2006}
month = {Jul}
}