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Contamination profiles of short-chain polychlorinated n-alkanes in foodstuff samples from Japan

Abstract

Polychlorinated n-alkanes (PCAs) are group of chemicals manufactured by chlorination of liquid n-paraffin or paraffin wax that contain 30 to 70% chlorine by weight. Large amounts of PCAs are widely used as plasticizers for vinyl chloride, lubricants, paints, and flame retardants and number of other industrial applications. Annual global production of PCAs is approximately 300 kilo tones, with a majority having medium-carbon-chain (C14-C19) length. According to the investigation made by Kagaku Kogyo Nippon-Sha, the annual consumption of PCAs in Japan was about 83,000 tons in between 1986-2001. Short-carbon-chain (C10-C13) has been placed on the Priority Substance List under Canadian Environmental Protection Act and on the Environmental Protection Agency Toxic Release Inventory in the USA due to its potential to act as tumor promoters in mammals. Data on environment levels of PCAs is meager, nevertheless, PCAs have been measured at relatively high concentrations in biota from Sweden, biota, sediment from Canada and marine biota and human milk from the Canadian Arctic. In our earlier study, we reported concentrations of short-chain PCAs from sewage treatment plant (STP) collected from Tama River, Tokyo and river water and sediment from Tokyo and Osaka. STP influent water contained greater shortchain PCAs concentrations than STP effluent.  More>>
Authors:
Matsukami, Hidenori; Kurunthachalam, S; Ohi, Etsumasa; Takasuga, Takumi; [1]  Iino, Fukuya; Nakanishi, Junko [2] 
  1. Shimadzu Techno Research, Inc., Kyoto (Japan)
  2. National Inst. of Advanced Industrial Science and Technology, Tsukuba (Japan)
Publication Date:
Sep 15, 2004
Product Type:
Conference
Report Number:
ETDE-DE-1546
Resource Relation:
Conference: Dioxin 2004: 24. international symposium on halogenated environmental organic pollutants and POPs, Berlin (Germany), 6-10 Sep 2004; Related Information: In: Dioxin 2004: 24. international symposium on halogenated environmental organic pollutants and POPs. Proceedings, Organohalogen Compounds v. 66, 4035 pages.
Subject:
54 ENVIRONMENTAL SCIENCES; CHLORINATED ALIPHATIC HYDROCARBONS; FOOD; INTAKE; RISK ASSESSMENT; FRUITS; BREAD; VEGETABLE OILS; GRAMINEAE; MILK PRODUCTS; FISHES; MEAT; QUANTITATIVE CHEMICAL ANALYSIS
Sponsoring Organizations:
Bundesmin. fuer Umwelt, Naturschutz und Reaktorsicherheit, Bonn (Germany)
OSTI ID:
20828115
Research Organizations:
Technische Univ. Berlin (Germany). Inst. fuer Technischen Umweltschutz
Country of Origin:
Germany
Language:
English
Other Identifying Numbers:
Other: ISBN 3-928379-30-5; TRN: DE07G1404
Availability:
Available as CD-ROM; www.osti.gov/servlets/purl/20828115-aIlKxc/; Commercial reproduction prohibited; OSTI as DE20828115
Submitting Site:
DE
Size:
page(s) 2008-2014
Announcement Date:
Jan 29, 2007

Citation Formats

Matsukami, Hidenori, Kurunthachalam, S, Ohi, Etsumasa, Takasuga, Takumi, Iino, Fukuya, and Nakanishi, Junko. Contamination profiles of short-chain polychlorinated n-alkanes in foodstuff samples from Japan. Germany: N. p., 2004. Web.
Matsukami, Hidenori, Kurunthachalam, S, Ohi, Etsumasa, Takasuga, Takumi, Iino, Fukuya, & Nakanishi, Junko. Contamination profiles of short-chain polychlorinated n-alkanes in foodstuff samples from Japan. Germany.
Matsukami, Hidenori, Kurunthachalam, S, Ohi, Etsumasa, Takasuga, Takumi, Iino, Fukuya, and Nakanishi, Junko. 2004. "Contamination profiles of short-chain polychlorinated n-alkanes in foodstuff samples from Japan." Germany.
@misc{etde_20828115,
title = {Contamination profiles of short-chain polychlorinated n-alkanes in foodstuff samples from Japan}
author = {Matsukami, Hidenori, Kurunthachalam, S, Ohi, Etsumasa, Takasuga, Takumi, Iino, Fukuya, and Nakanishi, Junko}
abstractNote = {Polychlorinated n-alkanes (PCAs) are group of chemicals manufactured by chlorination of liquid n-paraffin or paraffin wax that contain 30 to 70% chlorine by weight. Large amounts of PCAs are widely used as plasticizers for vinyl chloride, lubricants, paints, and flame retardants and number of other industrial applications. Annual global production of PCAs is approximately 300 kilo tones, with a majority having medium-carbon-chain (C14-C19) length. According to the investigation made by Kagaku Kogyo Nippon-Sha, the annual consumption of PCAs in Japan was about 83,000 tons in between 1986-2001. Short-carbon-chain (C10-C13) has been placed on the Priority Substance List under Canadian Environmental Protection Act and on the Environmental Protection Agency Toxic Release Inventory in the USA due to its potential to act as tumor promoters in mammals. Data on environment levels of PCAs is meager, nevertheless, PCAs have been measured at relatively high concentrations in biota from Sweden, biota, sediment from Canada and marine biota and human milk from the Canadian Arctic. In our earlier study, we reported concentrations of short-chain PCAs from sewage treatment plant (STP) collected from Tama River, Tokyo and river water and sediment from Tokyo and Osaka. STP influent water contained greater shortchain PCAs concentrations than STP effluent. In addition, some river water and sediment samples contained detectable concentrations of short-chain PCAs, which was similar to other industrial countries. However, there is no study conducted to explore the contamination profiles of short-chain PCAs in human foodstuff samples. In the present study, we analyzed eleven foodstuff samples that were purchased from various supermarkets in order to know the short-chain PCAs concentrations in the foodstuff and possible human total daily intake (TDI) amounts.}
place = {Germany}
year = {2004}
month = {Sep}
}