Abstract
The general properties of the NaHSO{sub 4} - KHSO{sub 4} molten eutectic resemble those of neutral sulphates and those of concentrated H{sub 2}SO{sub 4}. We have been able to show the existence in solution of the ions HSO{sup -}{sub 4} SO{sup 2-}{sub 4}, and H{sub 3}O{sup +}, these last being formed by the action of the HSO{sup -}{sub 4} ions on dissolved H{sub 2}O. The electro-active zone with a polished platinum electrode is limited in oxidation by the ions H{sub 3}O{sup +} and SO{sup 2-}{sub 4}, and in reduction by the protons of HSO{sup -}{sub 4}. We have compared the electro-active zones obtained with different electrodes (Ag-Au-graphite-mercury). We have considered the dissolution of a few metallic oxides and halides. This work shows the role as O{sup 2-} ion acceptors of HSO{sup -}{sub 4} ions. We have undertaken an electro-chemical study of a few oxido-reduction Systems: H{sup +} / H{sub 2}, Ag{down_arrow} / Ag (1), the vanadium and uranium Systems, those of mercury Hg{down_arrow} / Hg{sup 2-}{sub 2} and of gold Au/Au{sup 3+}, then of the attack by the solvent of a few common metals such as aluminium, iron, copper and nickel. The study of silver Systems has made it possible
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Le Ber, F
[1]
- Commissariat a l'Energie Atomique, Saclay (France). Centre d'Etudes Nucleaires
Citation Formats
Le Ber, F.
Electrochemical study in the molten sodium acid sulphate - potassium acid sulphate eutectic; Etude electrochimique dans l'eutectique fondu sulfate acide de sodium - sulfate acide de potassium.
France: N. p.,
1964.
Web.
Le Ber, F.
Electrochemical study in the molten sodium acid sulphate - potassium acid sulphate eutectic; Etude electrochimique dans l'eutectique fondu sulfate acide de sodium - sulfate acide de potassium.
France.
Le Ber, F.
1964.
"Electrochemical study in the molten sodium acid sulphate - potassium acid sulphate eutectic; Etude electrochimique dans l'eutectique fondu sulfate acide de sodium - sulfate acide de potassium."
France.
@misc{etde_20795926,
title = {Electrochemical study in the molten sodium acid sulphate - potassium acid sulphate eutectic; Etude electrochimique dans l'eutectique fondu sulfate acide de sodium - sulfate acide de potassium}
author = {Le Ber, F}
abstractNote = {The general properties of the NaHSO{sub 4} - KHSO{sub 4} molten eutectic resemble those of neutral sulphates and those of concentrated H{sub 2}SO{sub 4}. We have been able to show the existence in solution of the ions HSO{sup -}{sub 4} SO{sup 2-}{sub 4}, and H{sub 3}O{sup +}, these last being formed by the action of the HSO{sup -}{sub 4} ions on dissolved H{sub 2}O. The electro-active zone with a polished platinum electrode is limited in oxidation by the ions H{sub 3}O{sup +} and SO{sup 2-}{sub 4}, and in reduction by the protons of HSO{sup -}{sub 4}. We have compared the electro-active zones obtained with different electrodes (Ag-Au-graphite-mercury). We have considered the dissolution of a few metallic oxides and halides. This work shows the role as O{sup 2-} ion acceptors of HSO{sup -}{sub 4} ions. We have undertaken an electro-chemical study of a few oxido-reduction Systems: H{sup +} / H{sub 2}, Ag{down_arrow} / Ag (1), the vanadium and uranium Systems, those of mercury Hg{down_arrow} / Hg{sup 2-}{sub 2} and of gold Au/Au{sup 3+}, then of the attack by the solvent of a few common metals such as aluminium, iron, copper and nickel. The study of silver Systems has made it possible to obtain the solubility products of AgCl and AgBr and to consider the possibility of coulometric titration Cl{sup -} ions with Ag{sup +} ions. We have shown the existence of various chemical species of vanadium which may exist in the molten eutectic. (author) [French] Les proprietes generales de l'eutectique NaHSO{sub 4} - KHSO{sub 4} fondu s'apparentent a celles des sulfates neutres et a celles de H{sub 2}SO{sub 4} concentre. Nous avons pu mettre en evidence l'existence en solution d'ions HSO{sup -}{sub 4}, SO{sup 2-}{sub 4},et H{sub 3}O{sup +}, ces derniers resultats de l'action des ions HSO{sup -}{sub 4} sur H{sup 2}O dissoute. Le domaine d'electroactivite a une electrode de platine poli est limite en oxydation par les ions H{sub 3}O{sup +} + SO{sup 2-}{sub 4} et en reduction par les protons de HSO{sup -}{sub 4}. Nous avons compare les domaines d'electroactivite obtenus a differentes electrodes (Ag-Au-Graphite-Hg). Nous avons envisage la dissolution de quelques oxydes et halogenures metalliques. Cette etude montre le role des ions HSO{sup -}{sub 4} en tant qu'accepteurs d'ions O{sup 2-}. Nous avons entrepris l'etude electrochimique de quelques systemes oxydo-reducteurs: H{sup +} / H{sub 2}, Ag{down_arrow} / Ag (I), les systemes du vanadium et de l'uranium, du mercure Hg{down_arrow} / Hg{sup 2-}{sub 2} et de l'or Au/Au{sup 3+}; puis l'attaque par le solvant de quelques metaux usuels comme l'aluminium, le fer, le cuivre et le nickel. L'etude des systemes de l'argent nous a permis d'atteindre les produits de solubilite de AgCl et AgBr et d'envisager le titrage coulometrique des ions Cl{sup -} par des ions Ag{sup +}. Nous avons mis en evidence differentes especes chimiques du vanadium pouvant exister dans l'eutectique fondu. (auteur)}
place = {France}
year = {1964}
month = {Jul}
}
title = {Electrochemical study in the molten sodium acid sulphate - potassium acid sulphate eutectic; Etude electrochimique dans l'eutectique fondu sulfate acide de sodium - sulfate acide de potassium}
author = {Le Ber, F}
abstractNote = {The general properties of the NaHSO{sub 4} - KHSO{sub 4} molten eutectic resemble those of neutral sulphates and those of concentrated H{sub 2}SO{sub 4}. We have been able to show the existence in solution of the ions HSO{sup -}{sub 4} SO{sup 2-}{sub 4}, and H{sub 3}O{sup +}, these last being formed by the action of the HSO{sup -}{sub 4} ions on dissolved H{sub 2}O. The electro-active zone with a polished platinum electrode is limited in oxidation by the ions H{sub 3}O{sup +} and SO{sup 2-}{sub 4}, and in reduction by the protons of HSO{sup -}{sub 4}. We have compared the electro-active zones obtained with different electrodes (Ag-Au-graphite-mercury). We have considered the dissolution of a few metallic oxides and halides. This work shows the role as O{sup 2-} ion acceptors of HSO{sup -}{sub 4} ions. We have undertaken an electro-chemical study of a few oxido-reduction Systems: H{sup +} / H{sub 2}, Ag{down_arrow} / Ag (1), the vanadium and uranium Systems, those of mercury Hg{down_arrow} / Hg{sup 2-}{sub 2} and of gold Au/Au{sup 3+}, then of the attack by the solvent of a few common metals such as aluminium, iron, copper and nickel. The study of silver Systems has made it possible to obtain the solubility products of AgCl and AgBr and to consider the possibility of coulometric titration Cl{sup -} ions with Ag{sup +} ions. We have shown the existence of various chemical species of vanadium which may exist in the molten eutectic. (author) [French] Les proprietes generales de l'eutectique NaHSO{sub 4} - KHSO{sub 4} fondu s'apparentent a celles des sulfates neutres et a celles de H{sub 2}SO{sub 4} concentre. Nous avons pu mettre en evidence l'existence en solution d'ions HSO{sup -}{sub 4}, SO{sup 2-}{sub 4},et H{sub 3}O{sup +}, ces derniers resultats de l'action des ions HSO{sup -}{sub 4} sur H{sup 2}O dissoute. Le domaine d'electroactivite a une electrode de platine poli est limite en oxydation par les ions H{sub 3}O{sup +} + SO{sup 2-}{sub 4} et en reduction par les protons de HSO{sup -}{sub 4}. Nous avons compare les domaines d'electroactivite obtenus a differentes electrodes (Ag-Au-Graphite-Hg). Nous avons envisage la dissolution de quelques oxydes et halogenures metalliques. Cette etude montre le role des ions HSO{sup -}{sub 4} en tant qu'accepteurs d'ions O{sup 2-}. Nous avons entrepris l'etude electrochimique de quelques systemes oxydo-reducteurs: H{sup +} / H{sub 2}, Ag{down_arrow} / Ag (I), les systemes du vanadium et de l'uranium, du mercure Hg{down_arrow} / Hg{sup 2-}{sub 2} et de l'or Au/Au{sup 3+}; puis l'attaque par le solvant de quelques metaux usuels comme l'aluminium, le fer, le cuivre et le nickel. L'etude des systemes de l'argent nous a permis d'atteindre les produits de solubilite de AgCl et AgBr et d'envisager le titrage coulometrique des ions Cl{sup -} par des ions Ag{sup +}. Nous avons mis en evidence differentes especes chimiques du vanadium pouvant exister dans l'eutectique fondu. (auteur)}
place = {France}
year = {1964}
month = {Jul}
}