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Fabrication and characterization of ZnO nano wires/Cd Se/CuSCN eta-solar cell

Abstract

ZnO/CdSe/CuSCN extremely thin absorber (eta)-solar cells based on ZnO nano-wires have been successfully realized using easily accessible electrochemical and solution deposition techniques. An n-type ZnO film consisting of free-standing single crystal nano-wires several microns high and 100-200 nm in diameter was-deposited on a conducting glass (SnO{sub 2}:F) substrate covered by a thin spray pyrolysis ZnO electronic blocking layer. A 30-40-nm-thin layer of CdSe absorber was electrodeposited, coating the ZnO nano-wires. The voids between the ZnO/CdSe nano-wires were filled with p-type CuSCN; the entire assembly formed a p-i-n junction. The ZnO/CdSe nano-wire layer exhibited a high light-trapping effect, with an effective absorbance of {approx}89% and effective reflectance of {approx}8% in the 400-800 nm region of the solar spectrum (AM1.5). The effects of an annealing process on the CdSe grain size and on the energy conversion efficiency of the eta-solar cell have been analyzed. The obtained efficiencies, for cells with annealed CdSe (1.5-2.3%) show that the ZnO/CdSe/CuSCN nano-heterostructure is an interesting option for developing new solar cell devices. (authors)
Authors:
Tena-Zaera, R; Ryan, M A; Abou, Katty; Hodes, G; Bastide, St; Levy-Clement, C; [1]  Tena-Zaera, R; [2]  Ryan, M A; [3]  Hodes, G [4] 
  1. LCMTR, Institut des sciences chimiques Seine-Amont, CNRS, 94 - Thiais (France)
  2. Valancia Univ., Dept. Fisica Aplicada i Electromagnetisme (Spain)
  3. Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA (United States)
  4. Weizmann Institute of Science, Dept. of Materials and Interfaces, Rehovot (Israel)
Publication Date:
May 15, 2006
Product Type:
Journal Article
Resource Relation:
Journal Name: Comptes Rendus. Chimie; Journal Issue: 5-6t.9; Conference: 15. international conference on photochemical conversion and storage of solar energy, 15. conference international sur la conversion photochimique et le stockage de l'energie solaire, Paris (France), 4-7 Jul 2004; Other Information: 37 refs
Subject:
14 SOLAR ENERGY; ANNEALING; CADMIUM SELENIDES; EFFICIENCY; ELECTRODEPOSITION; GRAIN SIZE; NANOSTRUCTURES; SOLAR CELLS; SOLAR ENERGY CONVERSION; ZINC OXIDES
OSTI ID:
20783983
Country of Origin:
France
Language:
English
Other Identifying Numbers:
Journal ID: ISSN 1631-0748; TRN: FR0602577087384
Availability:
Available from doi: <http://dx.doi.org/10.1016/j.crci.2005.03.034>;INIS
Submitting Site:
FRN
Size:
page(s) 717-729
Announcement Date:
Dec 04, 2006

Citation Formats

Tena-Zaera, R, Ryan, M A, Abou, Katty, Hodes, G, Bastide, St, Levy-Clement, C, Tena-Zaera, R, Ryan, M A, and Hodes, G. Fabrication and characterization of ZnO nano wires/Cd Se/CuSCN eta-solar cell. France: N. p., 2006. Web. doi:10.1016/J.CRCI.2005.03.034>.
Tena-Zaera, R, Ryan, M A, Abou, Katty, Hodes, G, Bastide, St, Levy-Clement, C, Tena-Zaera, R, Ryan, M A, & Hodes, G. Fabrication and characterization of ZnO nano wires/Cd Se/CuSCN eta-solar cell. France. https://doi.org/10.1016/J.CRCI.2005.03.034>
Tena-Zaera, R, Ryan, M A, Abou, Katty, Hodes, G, Bastide, St, Levy-Clement, C, Tena-Zaera, R, Ryan, M A, and Hodes, G. 2006. "Fabrication and characterization of ZnO nano wires/Cd Se/CuSCN eta-solar cell." France. https://doi.org/10.1016/J.CRCI.2005.03.034>.
@misc{etde_20783983,
title = {Fabrication and characterization of ZnO nano wires/Cd Se/CuSCN eta-solar cell}
author = {Tena-Zaera, R, Ryan, M A, Abou, Katty, Hodes, G, Bastide, St, Levy-Clement, C, Tena-Zaera, R, Ryan, M A, and Hodes, G}
abstractNote = {ZnO/CdSe/CuSCN extremely thin absorber (eta)-solar cells based on ZnO nano-wires have been successfully realized using easily accessible electrochemical and solution deposition techniques. An n-type ZnO film consisting of free-standing single crystal nano-wires several microns high and 100-200 nm in diameter was-deposited on a conducting glass (SnO{sub 2}:F) substrate covered by a thin spray pyrolysis ZnO electronic blocking layer. A 30-40-nm-thin layer of CdSe absorber was electrodeposited, coating the ZnO nano-wires. The voids between the ZnO/CdSe nano-wires were filled with p-type CuSCN; the entire assembly formed a p-i-n junction. The ZnO/CdSe nano-wire layer exhibited a high light-trapping effect, with an effective absorbance of {approx}89% and effective reflectance of {approx}8% in the 400-800 nm region of the solar spectrum (AM1.5). The effects of an annealing process on the CdSe grain size and on the energy conversion efficiency of the eta-solar cell have been analyzed. The obtained efficiencies, for cells with annealed CdSe (1.5-2.3%) show that the ZnO/CdSe/CuSCN nano-heterostructure is an interesting option for developing new solar cell devices. (authors)}
doi = {10.1016/J.CRCI.2005.03.034>}
journal = []
issue = {5-6t.9}
place = {France}
year = {2006}
month = {May}
}