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Alloy composition, deformation temperature, pressure and post-deformation annealing effects in severely deformed Ti-Ni based shape memory alloys

Abstract

Structure formation in Ti-48.5, Ti-50.0, Ti-50.7 at.% Ni and Ti-47 at.% Ni-3 at.% Fe shape memory alloys depending on deformation temperature (-196 to 400 deg C) and pressure (4-8 GPa) under conditions of high-pressure torsion and post-deformation annealing (200-400 deg C) was studied using transmission electron microscopy and X-ray diffraction methods. The tendency to form an amorphous structure depends on the relative values of the deformation temperature and martensite start (M {sub s}) temperature as follows: it is strongest in initially martensitic alloy, intermediate in a premartensitic austenite, and the weakest in initially thermally stable austenitic alloy. Lowering of the deformation temperature in the range below the martensite finish (M {sub f}) temperature facilitates amorphization. Raising of the deformation temperature in the austenitic temperature range suppresses amorphization. The upper limiting deformation temperature for partial amorphization of the alloy having the highest M {sub s} is located about 300 deg C. The upper limiting deformation temperature for actually nanocrystalline structure formation is located about 350 deg C for non-aging Ti-Ni alloys and somewhat higher than 400 deg C for aged Ti-Ni alloy. The thermomechanical conditions of the equal-channel angular pressing for obtaining actually nanocrystalline structure are recommended. Isothermal martensitic transformation is  More>>
Authors:
Prokoshkin, S D; [1]  Khmelevskaya, I Yu; [1]  Dobatkin, S V; [1]  Baikov Institute of Metallurgy and Material Science, Russian Academy of Sciences, Leninsky prosp., 49, Moscow 119049 (Russian Federation)]; Trubitsyna, I B; [1]  Tatyanin, E V; [2]  Institute for High Pressure Physics, Russian Academy of Sciences, Troitsk (Russian Federation)]; Stolyarov, V V; [3]  Prokofiev, E A [3] 
  1. Moscow State Institute of Steel and Alloys, Leninsky prosp., 4, Moscow 119049 (Russian Federation)
  2. Baikov Institute of Metallurgy and Material Science, Russian Academy of Sciences, Leninsky prosp., 49, Moscow 119049 (Russian Federation)
  3. Institute of Physics of Advanced Materials, Ufa (Russian Federation)
Publication Date:
May 15, 2005
Product Type:
Journal Article
Resource Relation:
Journal Name: Acta Materialia; Journal Volume: 53; Journal Issue: 9; Other Information: DOI: 10.1016/j.actamat.2005.02.032; PII: S1359-6454(05)00131-X; Copyright (c) 2005 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA)
Subject:
36 MATERIALS SCIENCE; AGING; AMORPHOUS STATE; ANNEALING; AUSTENITE; AUSTENITIC STEELS; CRYSTALS; DEFORMATION; GRAIN SIZE; MARTENSITE; NANOSTRUCTURES; PHASE TRANSFORMATIONS; PLASTICITY; PRESSING; PRESSURE RANGE GIGA PA; SHAPE MEMORY EFFECT; TEMPERATURE RANGE 0273-0400 K; TEMPERATURE RANGE 0400-1000 K; TITANIUM ALLOYS; TRANSMISSION ELECTRON MICROSCOPY; X-RAY DIFFRACTION
OSTI ID:
20747403
Country of Origin:
United Kingdom
Language:
English
Other Identifying Numbers:
Journal ID: ISSN 1359-6454; ACMAFD; TRN: GB05X4144055987
Submitting Site:
GBN
Size:
page(s) 2703-2714
Announcement Date:
Aug 14, 2006

Citation Formats

Prokoshkin, S D, Khmelevskaya, I Yu, Dobatkin, S V, Baikov Institute of Metallurgy and Material Science, Russian Academy of Sciences, Leninsky prosp., 49, Moscow 119049 (Russian Federation)], Trubitsyna, I B, Tatyanin, E V, Institute for High Pressure Physics, Russian Academy of Sciences, Troitsk (Russian Federation)], Stolyarov, V V, and Prokofiev, E A. Alloy composition, deformation temperature, pressure and post-deformation annealing effects in severely deformed Ti-Ni based shape memory alloys. United Kingdom: N. p., 2005. Web. doi:10.1016/j.actamat.2005.02.032.
Prokoshkin, S D, Khmelevskaya, I Yu, Dobatkin, S V, Baikov Institute of Metallurgy and Material Science, Russian Academy of Sciences, Leninsky prosp., 49, Moscow 119049 (Russian Federation)], Trubitsyna, I B, Tatyanin, E V, Institute for High Pressure Physics, Russian Academy of Sciences, Troitsk (Russian Federation)], Stolyarov, V V, & Prokofiev, E A. Alloy composition, deformation temperature, pressure and post-deformation annealing effects in severely deformed Ti-Ni based shape memory alloys. United Kingdom. https://doi.org/10.1016/j.actamat.2005.02.032
Prokoshkin, S D, Khmelevskaya, I Yu, Dobatkin, S V, Baikov Institute of Metallurgy and Material Science, Russian Academy of Sciences, Leninsky prosp., 49, Moscow 119049 (Russian Federation)], Trubitsyna, I B, Tatyanin, E V, Institute for High Pressure Physics, Russian Academy of Sciences, Troitsk (Russian Federation)], Stolyarov, V V, and Prokofiev, E A. 2005. "Alloy composition, deformation temperature, pressure and post-deformation annealing effects in severely deformed Ti-Ni based shape memory alloys." United Kingdom. https://doi.org/10.1016/j.actamat.2005.02.032.
@misc{etde_20747403,
title = {Alloy composition, deformation temperature, pressure and post-deformation annealing effects in severely deformed Ti-Ni based shape memory alloys}
author = {Prokoshkin, S D, Khmelevskaya, I Yu, Dobatkin, S V, Baikov Institute of Metallurgy and Material Science, Russian Academy of Sciences, Leninsky prosp., 49, Moscow 119049 (Russian Federation)], Trubitsyna, I B, Tatyanin, E V, Institute for High Pressure Physics, Russian Academy of Sciences, Troitsk (Russian Federation)], Stolyarov, V V, and Prokofiev, E A}
abstractNote = {Structure formation in Ti-48.5, Ti-50.0, Ti-50.7 at.% Ni and Ti-47 at.% Ni-3 at.% Fe shape memory alloys depending on deformation temperature (-196 to 400 deg C) and pressure (4-8 GPa) under conditions of high-pressure torsion and post-deformation annealing (200-400 deg C) was studied using transmission electron microscopy and X-ray diffraction methods. The tendency to form an amorphous structure depends on the relative values of the deformation temperature and martensite start (M {sub s}) temperature as follows: it is strongest in initially martensitic alloy, intermediate in a premartensitic austenite, and the weakest in initially thermally stable austenitic alloy. Lowering of the deformation temperature in the range below the martensite finish (M {sub f}) temperature facilitates amorphization. Raising of the deformation temperature in the austenitic temperature range suppresses amorphization. The upper limiting deformation temperature for partial amorphization of the alloy having the highest M {sub s} is located about 300 deg C. The upper limiting deformation temperature for actually nanocrystalline structure formation is located about 350 deg C for non-aging Ti-Ni alloys and somewhat higher than 400 deg C for aged Ti-Ni alloy. The thermomechanical conditions of the equal-channel angular pressing for obtaining actually nanocrystalline structure are recommended. Isothermal martensitic transformation is observed in the Ti-48.5 at.% Ni alloy as a result of keeping for 10 year at room temperature after high-temperature severe plastic deformation. Increasing the pressure suppresses the tendency to form an amorphous structure. The nanocrystalline structure formed under post-deformation annealing from the amorphous structure remains finer than the nanostructure formed as a result of severe plastic deformation through the annealing temperature range covering a nano-grain size scale.}
doi = {10.1016/j.actamat.2005.02.032}
journal = []
issue = {9}
volume = {53}
place = {United Kingdom}
year = {2005}
month = {May}
}