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Crystal-face growth rate: role of the neighbouring concentration; Vitesse de croissance d'une face cristalline: role de la concentration qui regne a son voisinage

Abstract

A study has been made of the phenomena occurring in the neighbourhood of a growing crystal-face, with the help of several methods based on interferometric observation. If the system is considered at a given moment, it is possible to express the growth rate of the crystal in two ways: 1) using the origin of the solute contributing to the growth, by application of Fick's law modified in certain cases by a correction factor involving the absolute value of the concentration near the crystal face. 2) directly, using the supersaturation in the crystal-face neighbourhood. On the other hand, if an attempt is made to take into account the changes in growth rate with time, it is seen that this rate is not dependent on diffusion phenomena, but that the convection currents in the solution play an important role. (author) [French] Les phenomenes qui ont lieu dans la solution au voisinage d'un cristal en voie de croissance ont ete etudies grace a plusieurs methodes d'observation interferometriques. Si l'on considere la preparation a un instant donne, il est possible d'exprimer la vitesse de croissance du cristal de deux manieres: 1) a partir de la provenance du solute necessaire a la croissance, par application  More>>
Authors:
Publication Date:
Jul 01, 1967
Product Type:
Thesis/Dissertation
Report Number:
CEA-R-3085
Resource Relation:
Other Information: TH: These docteur es-sciences physiques; 51 refs; PBD: 1967
Subject:
36 MATERIALS SCIENCE; AMMONIUM SULFATES; CHLORATES; CONCENTRATION RATIO; CONVECTION; CRYSTAL GROWTH; CRYSTALLIZATION; DENDRITES; DENSITY; DIFFUSION; FICK LAWS; INTERFEROMETRY; KINETICS; POTASSIUM PHOSPHATES; POTASSIUM SULFATES; SATURATION; SODIUM SULFATES; SOLUTES; TEMPERATURE DEPENDENCE; TEMPERATURE MEASUREMENT; TIME DEPENDENCE
OSTI ID:
20622013
Research Organizations:
Commissariat a l'Energie Atomique, Saclay (France). Centre d'Etudes Nucleaires; Faculte des Sciences de l'Universite de Strasbourg - 67 (France)
Country of Origin:
France
Language:
French
Other Identifying Numbers:
TRN: FR05R3085065664
Availability:
Available from INIS in electronic form
Submitting Site:
FRN
Size:
62 pages
Announcement Date:
Aug 28, 2005

Citation Formats

Itti, R. Crystal-face growth rate: role of the neighbouring concentration; Vitesse de croissance d'une face cristalline: role de la concentration qui regne a son voisinage. France: N. p., 1967. Web.
Itti, R. Crystal-face growth rate: role of the neighbouring concentration; Vitesse de croissance d'une face cristalline: role de la concentration qui regne a son voisinage. France.
Itti, R. 1967. "Crystal-face growth rate: role of the neighbouring concentration; Vitesse de croissance d'une face cristalline: role de la concentration qui regne a son voisinage." France.
@misc{etde_20622013,
title = {Crystal-face growth rate: role of the neighbouring concentration; Vitesse de croissance d'une face cristalline: role de la concentration qui regne a son voisinage}
author = {Itti, R}
abstractNote = {A study has been made of the phenomena occurring in the neighbourhood of a growing crystal-face, with the help of several methods based on interferometric observation. If the system is considered at a given moment, it is possible to express the growth rate of the crystal in two ways: 1) using the origin of the solute contributing to the growth, by application of Fick's law modified in certain cases by a correction factor involving the absolute value of the concentration near the crystal face. 2) directly, using the supersaturation in the crystal-face neighbourhood. On the other hand, if an attempt is made to take into account the changes in growth rate with time, it is seen that this rate is not dependent on diffusion phenomena, but that the convection currents in the solution play an important role. (author) [French] Les phenomenes qui ont lieu dans la solution au voisinage d'un cristal en voie de croissance ont ete etudies grace a plusieurs methodes d'observation interferometriques. Si l'on considere la preparation a un instant donne, il est possible d'exprimer la vitesse de croissance du cristal de deux manieres: 1) a partir de la provenance du solute necessaire a la croissance, par application de l'equation de Fick moyennant, dans certains cas, un facteur correctif faisant intervenir la valeur absolue de la concentration au voisinage de la face, 2) directement a partir de la sursaturation qui regne pres de la face. Par contre, si l'on essaie de rendre compte de l'evolution de la vitesse de croissance au cours du temps, on voit que celle-ci n'est pas commandee par les phenomenes de diffusion, mais que les courants de convection qui existent dons la solution jouent un role important. (auteur)}
place = {France}
year = {1967}
month = {Jul}
}