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Nanoscale SiO2 particles at high temperatures: Size dependent properties

Abstract

The properties of silica clusters at temperatures of 1500 to 2800 K have been investigated using classical molecular dynamics simulations for particles containing up to 1152 atoms. We found that the atoms in the cluster were arranged in a shell like structure at low temperatures and that the radial density profile peaked near the outer-edge of the particle. Our computed surface tension did not show any significant size dependent behavior. Finally our computed diffusion coefficients in the liquid state are larger than bulk computed diffusivities. Smaller clusters have much higher pressures and lower the temperature of melting.
Authors:
Schweigert, I V; [1]  Lehtinen, K E.J.; [2]  Carrier, M J; [3]  Zachariah, M R; [4]  Minnesota Supercomputer Institute, Minneapolis (United States)]
  1. Institute of Theoretical and Applied Mechanics, Novosibirsk 630090 (Russian Federation)
  2. University of Helsinki (Finland)
  3. National Institute of Standards and Technology, Gaithersburg (United States)
  4. Department of Mechanical Engineering and Chemistry, University of Minnesota, Minneapolis (United States)
Publication Date:
Dec 13, 2002
Product Type:
Journal Article
Resource Relation:
Journal Name: AIP Conference Proceedings; Journal Volume: 649; Journal Issue: 1; Conference: 3. international conference on the physics of dusty plasmas, Durban (South Africa), 20-24 May 2002; Other Information: DOI: 10.1063/1.1527812; (c) 2002 American Institute of Physics; Country of input: International Atomic Energy Agency (IAEA); PBD: 13 Dec 2002
Subject:
70 PLASMA PHYSICS AND FUSION TECHNOLOGY; ATOMS; DENSITY; DIFFUSION; GRAIN SIZE; LIQUIDS; MELTING; MOLECULAR DYNAMICS METHOD; NANOSTRUCTURES; PARTICLES; PLASMA; SILICA; SIMULATION; SURFACE TENSION; TEMPERATURE DEPENDENCE
OSTI ID:
20621178
Country of Origin:
United States
Language:
English
Other Identifying Numbers:
Journal ID: ISSN 0094-243X; APCPCS; TRN: US03C6083064828
Submitting Site:
INIS
Size:
page(s) 414-417
Announcement Date:
Aug 28, 2005

Citation Formats

Schweigert, I V, Lehtinen, K E.J., Carrier, M J, Zachariah, M R, and Minnesota Supercomputer Institute, Minneapolis (United States)]. Nanoscale SiO2 particles at high temperatures: Size dependent properties. United States: N. p., 2002. Web. doi:10.1063/1.1527812.
Schweigert, I V, Lehtinen, K E.J., Carrier, M J, Zachariah, M R, & Minnesota Supercomputer Institute, Minneapolis (United States)]. Nanoscale SiO2 particles at high temperatures: Size dependent properties. United States. https://doi.org/10.1063/1.1527812
Schweigert, I V, Lehtinen, K E.J., Carrier, M J, Zachariah, M R, and Minnesota Supercomputer Institute, Minneapolis (United States)]. 2002. "Nanoscale SiO2 particles at high temperatures: Size dependent properties." United States. https://doi.org/10.1063/1.1527812.
@misc{etde_20621178,
title = {Nanoscale SiO2 particles at high temperatures: Size dependent properties}
author = {Schweigert, I V, Lehtinen, K E.J., Carrier, M J, Zachariah, M R, and Minnesota Supercomputer Institute, Minneapolis (United States)]}
abstractNote = {The properties of silica clusters at temperatures of 1500 to 2800 K have been investigated using classical molecular dynamics simulations for particles containing up to 1152 atoms. We found that the atoms in the cluster were arranged in a shell like structure at low temperatures and that the radial density profile peaked near the outer-edge of the particle. Our computed surface tension did not show any significant size dependent behavior. Finally our computed diffusion coefficients in the liquid state are larger than bulk computed diffusivities. Smaller clusters have much higher pressures and lower the temperature of melting.}
doi = {10.1063/1.1527812}
journal = []
issue = {1}
volume = {649}
journal type = {AC}
place = {United States}
year = {2002}
month = {Dec}
}