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Cationization and gamma irradiation effects on the dyeability of polyester fabric towards disperse dyes

Abstract

The effect of hydrazine hydrate (HZH) treatment and/or gamma irradiation on the dyeing, mechanical and thermal properties of polyester fabrics (PET) was studied. The different factors that may affect the dyeing performance, such as concentrations of HZH, benzyl alcohol and pH values, were investigated. In this regard, the colour strength of untreated polyester fabrics dyed with the dyestuffs Dispersol blue BR, Dispersol orange B2R and Dispersol red B2B was found to be 10.34, 10.76 and 10.12 compared to 24.61, 24.90 and 23.00 in the case of irradiated and HZH-treated polyester fabrics, respectively. These colour strength values were achieved by preirradiation at a dose of 75kGy followed by treatment with 15mll-1 of HZH. Thermogravimetric analysis (TGA) showed that the thermal decomposition stability was improved by using gamma irradiation and the treatment with HZH as indicated by the calculated activation energies. FT-IR spectroscopy showed that the treatment with HZH acts as cationizer prior to dyeing with disperse dyes.
Authors:
Zohdy, Maged H [1] 
  1. Department of Radiation Chemistry, National Center for Radiation Research and Technology, P.O. Box 29, Nasr City, Cairo (Egypt)
Publication Date:
Jun 01, 2005
Product Type:
Journal Article
Resource Relation:
Journal Name: Radiation Physics and Chemistry (1993); Journal Volume: 73; Journal Issue: 2; Other Information: DOI: 10.1016/j.radphyschem.2004.07.002; PII: S0969-806X(04)00454-2; Copyright (c) 2004 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA); PBD: Jun 2005
Subject:
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; ACTIVATION ENERGY; BENZYL ALCOHOL; COLOR; DYES; FOURIER TRANSFORMATION; GAMMA RADIATION; HYDRATES; HYDRAZINE; INFRARED SPECTRA; IRRADIATION; PH VALUE; POLYESTERS; RADIATION DOSES; THERMAL GRAVIMETRIC ANALYSIS; THERMODYNAMIC PROPERTIES
OSTI ID:
20620281
Country of Origin:
United Kingdom
Language:
English
Other Identifying Numbers:
Journal ID: ISSN 0969-806X; RPCHDM; TRN: GB05R3103063931
Submitting Site:
GBN
Size:
page(s) 101-110
Announcement Date:
Aug 28, 2005

Citation Formats

Zohdy, Maged H. Cationization and gamma irradiation effects on the dyeability of polyester fabric towards disperse dyes. United Kingdom: N. p., 2005. Web. doi:10.1016/j.radphyschem.2004.07.002.
Zohdy, Maged H. Cationization and gamma irradiation effects on the dyeability of polyester fabric towards disperse dyes. United Kingdom. https://doi.org/10.1016/j.radphyschem.2004.07.002
Zohdy, Maged H. 2005. "Cationization and gamma irradiation effects on the dyeability of polyester fabric towards disperse dyes." United Kingdom. https://doi.org/10.1016/j.radphyschem.2004.07.002.
@misc{etde_20620281,
title = {Cationization and gamma irradiation effects on the dyeability of polyester fabric towards disperse dyes}
author = {Zohdy, Maged H}
abstractNote = {The effect of hydrazine hydrate (HZH) treatment and/or gamma irradiation on the dyeing, mechanical and thermal properties of polyester fabrics (PET) was studied. The different factors that may affect the dyeing performance, such as concentrations of HZH, benzyl alcohol and pH values, were investigated. In this regard, the colour strength of untreated polyester fabrics dyed with the dyestuffs Dispersol blue BR, Dispersol orange B2R and Dispersol red B2B was found to be 10.34, 10.76 and 10.12 compared to 24.61, 24.90 and 23.00 in the case of irradiated and HZH-treated polyester fabrics, respectively. These colour strength values were achieved by preirradiation at a dose of 75kGy followed by treatment with 15mll-1 of HZH. Thermogravimetric analysis (TGA) showed that the thermal decomposition stability was improved by using gamma irradiation and the treatment with HZH as indicated by the calculated activation energies. FT-IR spectroscopy showed that the treatment with HZH acts as cationizer prior to dyeing with disperse dyes.}
doi = {10.1016/j.radphyschem.2004.07.002}
journal = []
issue = {2}
volume = {73}
journal type = {AC}
place = {United Kingdom}
year = {2005}
month = {Jun}
}