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Do final state relaxation channel contribute to Extended X-ray Absorption Fine Structure (EXAFS)?

Abstract

Full text: First order EXAFS analysis calculates the interaction of the outgoing photo-electron with nearby atomic neighbours. Until now a second order solution has relied upon calculations of multiple scattering of this photo-electron. We propose an entirely new solution as the second order term in the EXAFS spectrum which investigates the role of the decay channels of the excited atom in modifying the local attenuation coefficient or EXAFS structure. We present absolute EXAFS data for the K-edge of copper and the L1-edge of gold. Using a simultaneous measurement of x-ray fluorescence and transmission EXAFS data, we explore a correlation between the EXAFS oscillations and the intermediate decay channels of the target atom as measured in fluorescence detector. We will discuss the multi-configuration Dirac Fock (MCDF) calculation and its implications. The results will also be considered in relation to the possibility of atomic EXAFS.
Authors:
Dhal, B B; De Jonge, M; Tran, C Q; Barnea, Z; Chantler, C T [1] 
  1. University of Melbourne, Parkville, VIC (Australia). School of Physics
Publication Date:
Jul 01, 2002
Product Type:
Conference
Resource Relation:
Conference: 15. Biennial Congress of the Australian Institute of Physics. Physics and industry working together, Sydney, NSW (Australia), 8-11 Jul 2002; Other Information: PBD: 2002; Related Information: In: 15th Biennial Congress of the Australian Institute of Physics incorporating Australian Conference of Optical Fibre Technology (ACOFT) and Australian Optical Society (AOS). Handbook and abstracts, 235 pages.
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; ABSORPTION; ABSORPTION SPECTROSCOPY; ATOMS; ATTENUATION; COPPER; DECAY; DIRAC EQUATION; ELECTRON-ATOM COLLISIONS; ELECTRONS; FINE STRUCTURE; FLUORESCENCE; GOLD; MATHEMATICAL SOLUTIONS; PHOTON-ATOM COLLISIONS; RELAXATION; X RADIATION; X-RAY SPECTROSCOPY
OSTI ID:
20619924
Research Organizations:
Australian Institute of Physics (Australia)
Country of Origin:
Australia
Language:
English
Other Identifying Numbers:
TRN: AU0524602063574
Availability:
Available in abstract form only, full text entered in this record
Submitting Site:
INIS
Size:
page(s) 211
Announcement Date:
Aug 28, 2005

Citation Formats

Dhal, B B, De Jonge, M, Tran, C Q, Barnea, Z, and Chantler, C T. Do final state relaxation channel contribute to Extended X-ray Absorption Fine Structure (EXAFS)?. Australia: N. p., 2002. Web.
Dhal, B B, De Jonge, M, Tran, C Q, Barnea, Z, & Chantler, C T. Do final state relaxation channel contribute to Extended X-ray Absorption Fine Structure (EXAFS)?. Australia.
Dhal, B B, De Jonge, M, Tran, C Q, Barnea, Z, and Chantler, C T. 2002. "Do final state relaxation channel contribute to Extended X-ray Absorption Fine Structure (EXAFS)?" Australia.
@misc{etde_20619924,
title = {Do final state relaxation channel contribute to Extended X-ray Absorption Fine Structure (EXAFS)?}
author = {Dhal, B B, De Jonge, M, Tran, C Q, Barnea, Z, and Chantler, C T}
abstractNote = {Full text: First order EXAFS analysis calculates the interaction of the outgoing photo-electron with nearby atomic neighbours. Until now a second order solution has relied upon calculations of multiple scattering of this photo-electron. We propose an entirely new solution as the second order term in the EXAFS spectrum which investigates the role of the decay channels of the excited atom in modifying the local attenuation coefficient or EXAFS structure. We present absolute EXAFS data for the K-edge of copper and the L1-edge of gold. Using a simultaneous measurement of x-ray fluorescence and transmission EXAFS data, we explore a correlation between the EXAFS oscillations and the intermediate decay channels of the target atom as measured in fluorescence detector. We will discuss the multi-configuration Dirac Fock (MCDF) calculation and its implications. The results will also be considered in relation to the possibility of atomic EXAFS.}
place = {Australia}
year = {2002}
month = {Jul}
}