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Influences of interlayer distance and cobalt oxidation state on superconductivity of Na{sub x}CoO{sub 2}

Abstract

Sodium cobalt oxide with bilayer-hydrate structure, Na{sub x}CoO{sub 2} {center_dot} yH{sub 2}O (x{approx}0.35, y{approx}1.3), is the first superconductor in cobalt oxide system. Several sodium cobalt oxide hydrates related to the superconducting one were synthesized in order to explore the influence of the structure and composition upon the superconductivity. Partial dehydration brought about shrinkage of the interlayer distance to yield a monolayer hydrate, in which the superconductivity vanished. Modification of the carrier density, or lowering the Co oxidation state, lowered the superconducting transition temperature from 5 to 2 K.
Publication Date:
Oct 01, 2004
Product Type:
Journal Article
Resource Relation:
Journal Name: Physica. C, Superconductivity; Journal Volume: 412-414; Journal Issue: 1-2; Conference: ISS 2003: 16. International symposium on superconductivity: Advances in superconductivity XVI. Part I, Tsukuba (Japan), 27-29 Oct 2003; Other Information: DOI: 10.1016/j.physc.2003.12.024; PII: S0921453404006148; Copyright (c) 2004 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA); PBD: Oct 2004
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; CARRIER DENSITY; COBALT OXIDES; DEHYDRATION; DISTANCE; HYDRATES; LAYERS; SODIUM COMPOUNDS; SUPERCONDUCTIVITY; SUPERCONDUCTORS; TRANSITION TEMPERATURE; VALENCE
OSTI ID:
20618614
Country of Origin:
Netherlands
Language:
English
Other Identifying Numbers:
Journal ID: ISSN 0921-4534; PHYCE6; TRN: NL05S0811062112
Submitting Site:
NLN
Size:
page(s) 14-20
Announcement Date:
Aug 21, 2005

Citation Formats

Takada, Kazunori, Sakurai, Hiroya, Takayama-Muromachi, Eiji, Izumi, Fujio, Dilanian, Ruben A, and Sasaki, Takayoshi. Influences of interlayer distance and cobalt oxidation state on superconductivity of Na{sub x}CoO{sub 2}. Netherlands: N. p., 2004. Web. doi:10.1016/j.physc.2003.12.024.
Takada, Kazunori, Sakurai, Hiroya, Takayama-Muromachi, Eiji, Izumi, Fujio, Dilanian, Ruben A, & Sasaki, Takayoshi. Influences of interlayer distance and cobalt oxidation state on superconductivity of Na{sub x}CoO{sub 2}. Netherlands. https://doi.org/10.1016/j.physc.2003.12.024
Takada, Kazunori, Sakurai, Hiroya, Takayama-Muromachi, Eiji, Izumi, Fujio, Dilanian, Ruben A, and Sasaki, Takayoshi. 2004. "Influences of interlayer distance and cobalt oxidation state on superconductivity of Na{sub x}CoO{sub 2}." Netherlands. https://doi.org/10.1016/j.physc.2003.12.024.
@misc{etde_20618614,
title = {Influences of interlayer distance and cobalt oxidation state on superconductivity of Na{sub x}CoO{sub 2}}
author = {Takada, Kazunori, Sakurai, Hiroya, Takayama-Muromachi, Eiji, Izumi, Fujio, Dilanian, Ruben A, and Sasaki, Takayoshi}
abstractNote = {Sodium cobalt oxide with bilayer-hydrate structure, Na{sub x}CoO{sub 2} {center_dot} yH{sub 2}O (x{approx}0.35, y{approx}1.3), is the first superconductor in cobalt oxide system. Several sodium cobalt oxide hydrates related to the superconducting one were synthesized in order to explore the influence of the structure and composition upon the superconductivity. Partial dehydration brought about shrinkage of the interlayer distance to yield a monolayer hydrate, in which the superconductivity vanished. Modification of the carrier density, or lowering the Co oxidation state, lowered the superconducting transition temperature from 5 to 2 K.}
doi = {10.1016/j.physc.2003.12.024}
journal = []
issue = {1-2}
volume = {412-414}
journal type = {AC}
place = {Netherlands}
year = {2004}
month = {Oct}
}