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Microstructural changes causing a superconductor to insulator transition in YBa{sub 2}Cu{sub 3}O{sub 7} thin films

Abstract

Fully oxidized YBa{sub 2}Cu{sub 3}O{sub 7} thin films were prepared by pulsed laser deposition. By variation of the deposition temperature, in particular between 500 and 550 deg. C, the properties of the films range from insulating to superconducting. Since the stoichiometry of the films is identical the occurrence or non-occurrence of superconductivity can be attributed mainly to microstructural changes. To examine the structural differences, the films were characterized by transmission electron microscopy. HREM and ED measurements reveal that thin films consist of coherent connected small domains showing the original layered structure of Y and Ba-atoms. The c-axis of the domains is oriented perpendicular or parallel to the substrate surface, respectively. The domain size is reduced to a few nm by decrease of the deposition temperature. A correlation between the structural and superconducting properties becomes obvious: the film with the nm-sized ordering does not show any superconductivity while the film with a domain size variation from 10 to 200 nm shows a broad transition from 30 K down to 5 K.
Publication Date:
Aug 01, 2004
Product Type:
Journal Article
Resource Relation:
Journal Name: Physica. C, Superconductivity; Journal Volume: 408-410; Journal Issue: 3-4; Conference: 7. M2SRIO: International conference on materials and mechanisms of superconductivity and high temperature superconductors, Rio de Janeiro (Brazil), 25-30 May 2003; Other Information: DOI: 10.1016/j.physc.2004.03.215; PII: S0921453404004976; Copyright (c) 2004 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA); PBD: Aug 2004
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; ATOMS; BARIUM COMPOUNDS; CORRELATIONS; CUPRATES; ENERGY BEAM DEPOSITION; HIGH-TC SUPERCONDUCTORS; LASER RADIATION; MICROSTRUCTURE; PHASE TRANSFORMATIONS; PULSED IRRADIATION; STOICHIOMETRY; SUBSTRATES; SUPERCONDUCTING FILMS; SUPERCONDUCTIVITY; SURFACES; TEMPERATURE DEPENDENCE; THIN FILMS; TRANSMISSION ELECTRON MICROSCOPY; VARIATIONS; YTTRIUM COMPOUNDS
OSTI ID:
20618387
Country of Origin:
Netherlands
Language:
English
Other Identifying Numbers:
Journal ID: ISSN 0921-4534; PHYCE6; TRN: NL05S0584061885
Submitting Site:
NLN
Size:
page(s) 842-843
Announcement Date:
Aug 21, 2005

Citation Formats

Koehler, Anke, Zandbergen, Henny W, Linzen, Sven, and Seidel, Paul. Microstructural changes causing a superconductor to insulator transition in YBa{sub 2}Cu{sub 3}O{sub 7} thin films. Netherlands: N. p., 2004. Web. doi:10.1016/j.physc.2004.03.215.
Koehler, Anke, Zandbergen, Henny W, Linzen, Sven, & Seidel, Paul. Microstructural changes causing a superconductor to insulator transition in YBa{sub 2}Cu{sub 3}O{sub 7} thin films. Netherlands. https://doi.org/10.1016/j.physc.2004.03.215
Koehler, Anke, Zandbergen, Henny W, Linzen, Sven, and Seidel, Paul. 2004. "Microstructural changes causing a superconductor to insulator transition in YBa{sub 2}Cu{sub 3}O{sub 7} thin films." Netherlands. https://doi.org/10.1016/j.physc.2004.03.215.
@misc{etde_20618387,
title = {Microstructural changes causing a superconductor to insulator transition in YBa{sub 2}Cu{sub 3}O{sub 7} thin films}
author = {Koehler, Anke, Zandbergen, Henny W, Linzen, Sven, and Seidel, Paul}
abstractNote = {Fully oxidized YBa{sub 2}Cu{sub 3}O{sub 7} thin films were prepared by pulsed laser deposition. By variation of the deposition temperature, in particular between 500 and 550 deg. C, the properties of the films range from insulating to superconducting. Since the stoichiometry of the films is identical the occurrence or non-occurrence of superconductivity can be attributed mainly to microstructural changes. To examine the structural differences, the films were characterized by transmission electron microscopy. HREM and ED measurements reveal that thin films consist of coherent connected small domains showing the original layered structure of Y and Ba-atoms. The c-axis of the domains is oriented perpendicular or parallel to the substrate surface, respectively. The domain size is reduced to a few nm by decrease of the deposition temperature. A correlation between the structural and superconducting properties becomes obvious: the film with the nm-sized ordering does not show any superconductivity while the film with a domain size variation from 10 to 200 nm shows a broad transition from 30 K down to 5 K.}
doi = {10.1016/j.physc.2004.03.215}
journal = []
issue = {3-4}
volume = {408-410}
journal type = {AC}
place = {Netherlands}
year = {2004}
month = {Aug}
}