Abstract
Based on {sup 99}Tc NMR data, it is found that carboxylate anions in aqueous solutions coordinate with the Tc(CO){sub 3}{sup +} ion mainly in the monodentate fashion to form weak 1 : 1, 1 : 2, and 1 : 3 complexes. The stability of the complexes decreases with increasing size of the alkyl radical. In the series of halo-substituted acetates, all the stability constants decrease with a decrease in the basicity of the anion.
Suglobov, D N;
Miroslavov, A E;
Sidorenko, G V;
Gorshkov, N I;
Lumpov, A A
[1]
- NPO Radievyj Inst. im. V.G.Khlopina, Sankt-Peterburg (Russian Federation)
Citation Formats
Suglobov, D N, Miroslavov, A E, Sidorenko, G V, Gorshkov, N I, and Lumpov, A A.
Complexation of Tc(CO){sub 3}{sup +}{center_dot}aq with anions of monobasic carboxylic acids in aqueous solutions: a {sup 99}Tc NMR study; Kompleksoobrazovanie Tc(CO){sub 3}+ {center_dot}aq s anionami odnoosnovnykh karbonovykh kislot v vodnykh rastvorakh, po dannym spektroskopii YaMR {sup 99}Tc.
Russian Federation: N. p.,
2005.
Web.
Suglobov, D N, Miroslavov, A E, Sidorenko, G V, Gorshkov, N I, & Lumpov, A A.
Complexation of Tc(CO){sub 3}{sup +}{center_dot}aq with anions of monobasic carboxylic acids in aqueous solutions: a {sup 99}Tc NMR study; Kompleksoobrazovanie Tc(CO){sub 3}+ {center_dot}aq s anionami odnoosnovnykh karbonovykh kislot v vodnykh rastvorakh, po dannym spektroskopii YaMR {sup 99}Tc.
Russian Federation.
Suglobov, D N, Miroslavov, A E, Sidorenko, G V, Gorshkov, N I, and Lumpov, A A.
2005.
"Complexation of Tc(CO){sub 3}{sup +}{center_dot}aq with anions of monobasic carboxylic acids in aqueous solutions: a {sup 99}Tc NMR study; Kompleksoobrazovanie Tc(CO){sub 3}+ {center_dot}aq s anionami odnoosnovnykh karbonovykh kislot v vodnykh rastvorakh, po dannym spektroskopii YaMR {sup 99}Tc."
Russian Federation.
@misc{etde_20617467,
title = {Complexation of Tc(CO){sub 3}{sup +}{center_dot}aq with anions of monobasic carboxylic acids in aqueous solutions: a {sup 99}Tc NMR study; Kompleksoobrazovanie Tc(CO){sub 3}+ {center_dot}aq s anionami odnoosnovnykh karbonovykh kislot v vodnykh rastvorakh, po dannym spektroskopii YaMR {sup 99}Tc}
author = {Suglobov, D N, Miroslavov, A E, Sidorenko, G V, Gorshkov, N I, and Lumpov, A A}
abstractNote = {Based on {sup 99}Tc NMR data, it is found that carboxylate anions in aqueous solutions coordinate with the Tc(CO){sub 3}{sup +} ion mainly in the monodentate fashion to form weak 1 : 1, 1 : 2, and 1 : 3 complexes. The stability of the complexes decreases with increasing size of the alkyl radical. In the series of halo-substituted acetates, all the stability constants decrease with a decrease in the basicity of the anion.}
journal = []
issue = {1}
volume = {47}
journal type = {AC}
place = {Russian Federation}
year = {2005}
month = {Feb}
}
title = {Complexation of Tc(CO){sub 3}{sup +}{center_dot}aq with anions of monobasic carboxylic acids in aqueous solutions: a {sup 99}Tc NMR study; Kompleksoobrazovanie Tc(CO){sub 3}+ {center_dot}aq s anionami odnoosnovnykh karbonovykh kislot v vodnykh rastvorakh, po dannym spektroskopii YaMR {sup 99}Tc}
author = {Suglobov, D N, Miroslavov, A E, Sidorenko, G V, Gorshkov, N I, and Lumpov, A A}
abstractNote = {Based on {sup 99}Tc NMR data, it is found that carboxylate anions in aqueous solutions coordinate with the Tc(CO){sub 3}{sup +} ion mainly in the monodentate fashion to form weak 1 : 1, 1 : 2, and 1 : 3 complexes. The stability of the complexes decreases with increasing size of the alkyl radical. In the series of halo-substituted acetates, all the stability constants decrease with a decrease in the basicity of the anion.}
journal = []
issue = {1}
volume = {47}
journal type = {AC}
place = {Russian Federation}
year = {2005}
month = {Feb}
}