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ETDEWEB   /       /    Chemisorption of M(2) (M = Co, Ni, Zn, Cd) by gelatin-immobilized copper(2) hexacyanoferrate(2); Khemosorbtsiya ionov M(2) ionov (M = Co, Ni, Zn, Cd) zhelatin-immobilizovannym geksatsianoferratom(2) medi(2)

Chemisorption of M(2) (M = Co, Ni, Zn, Cd) by gelatin-immobilized copper(2) hexacyanoferrate(2); Khemosorbtsiya ionov M(2) ionov (M = Co, Ni, Zn, Cd) zhelatin-immobilizovannym geksatsianoferratom(2) medi(2)

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Abstract

The chemisorption processes proceeding in the gelatin-immobilized copper(2) hexacyanoferrate(2) by its contact with the aqueous solutions of the metal chlorides MCl{sub 2} (M = Co, Ni, Zn, Cd) at 20 Deg C are studied through the X-ray analysis. It is shown that in this process there takes place partial replacement of the copper(2) ions by the ions of the above mentioned metals with formation of the heterobinuclear hexacyanoferrates. The threshold replacement degree depends on the M nature and it varies with the range of 19% (M = Cd) up to 31% (M = Co)
Authors:
Mikajlov, O V; [1]  Tatarintseva, T B; Kolgina, V A [2] 
  1. Kazanskij Gosudarstvennyj Tekhnologicheskij Univ., (Russian Federation)
  2. Kazanskij Gosudarstvennyj Ehnergeticheskij Univ., (Russian Federation)
Publication Date:
May 01, 2003
Product Type:
Journal Article
Resource Relation:
Journal Name: Zhurnal Fizicheskoj Khimii; Journal Volume: 77; Journal Issue: 5; Other Information: 10 refs., 1 fig; PBD: May 2003
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; AQUEOUS SOLUTIONS; CADMIUM CHLORIDES; CHEMISORPTION; COPPER COMPOUNDS; DISTRIBUTION FUNCTIONS; FERROCYANIDES; GELATIN; ION EXCHANGE; TEMPERATURE RANGE 0273-0400 K
OSTI ID:
20617369
Country of Origin:
Russian Federation
Language:
Russian
Other Identifying Numbers:
Journal ID: ISSN 0044-4537; ZFKHA9; TRN: RU0501683060598
Submitting Site:
INIS
Size:
page(s) 917-920
Announcement Date:
Aug 21, 2005

Journal Article:

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Citation Formats

Mikajlov, O V, Tatarintseva, T B, and Kolgina, V A. Chemisorption of M(2) (M = Co, Ni, Zn, Cd) by gelatin-immobilized copper(2) hexacyanoferrate(2); Khemosorbtsiya ionov M(2) ionov (M = Co, Ni, Zn, Cd) zhelatin-immobilizovannym geksatsianoferratom(2) medi(2). Russian Federation: N. p., 2003. Web.
Mikajlov, O V, Tatarintseva, T B, & Kolgina, V A. Chemisorption of M(2) (M = Co, Ni, Zn, Cd) by gelatin-immobilized copper(2) hexacyanoferrate(2); Khemosorbtsiya ionov M(2) ionov (M = Co, Ni, Zn, Cd) zhelatin-immobilizovannym geksatsianoferratom(2) medi(2). Russian Federation.
Mikajlov, O V, Tatarintseva, T B, and Kolgina, V A. 2003. "Chemisorption of M(2) (M = Co, Ni, Zn, Cd) by gelatin-immobilized copper(2) hexacyanoferrate(2); Khemosorbtsiya ionov M(2) ionov (M = Co, Ni, Zn, Cd) zhelatin-immobilizovannym geksatsianoferratom(2) medi(2)." Russian Federation.
@misc{etde_20617369,
title = {Chemisorption of M(2) (M = Co, Ni, Zn, Cd) by gelatin-immobilized copper(2) hexacyanoferrate(2); Khemosorbtsiya ionov M(2) ionov (M = Co, Ni, Zn, Cd) zhelatin-immobilizovannym geksatsianoferratom(2) medi(2)}
 author = {Mikajlov, O V, Tatarintseva, T B, and Kolgina, V A}
 abstractNote = {The chemisorption processes proceeding in the gelatin-immobilized copper(2) hexacyanoferrate(2) by its contact with the aqueous solutions of the metal chlorides MCl{sub 2} (M = Co, Ni, Zn, Cd) at 20 Deg C are studied through the X-ray analysis. It is shown that in this process there takes place partial replacement of the copper(2) ions by the ions of the above mentioned metals with formation of the heterobinuclear hexacyanoferrates. The threshold replacement degree depends on the M nature and it varies with the range of 19% (M = Cd) up to 31% (M = Co)}
 journal = []
 issue = {5}
 volume = {77}
 journal type = {AC}
 place = {Russian Federation}
 year = {2003}
 month = {May}
 }