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Mechanical alloying of Fe and Zn: phase analysis and Moessbauer studies

Abstract

Crystalline Fe{sub 25}Zn{sub 75} powder alloys ({Gamma}{sub 1} phase) have been prepared by mechanical alloying of pure elemental powders. A crystalline Fe{sub 27.9}Zn{sub 72.1} alloy ({Gamma} phase) was obtained after adequate annealing. The Moessbauer spectra at room temperature displayed three doublets before annealing, corresponding to iron atoms located at the outer tetrahedral, inner tetrahedral and octahedral sites in the unit cell of Fe{sub 25}Zn{sub 75}. For the annealed sample, two doublets associated with iron atoms located at two tetrahedral inequivalent sites in the unit cell of Fe{sub 27.9}Zn{sub 72.1} were observed. This {Gamma}{sub 1}-to-{Gamma}-phase transition was confirmed by X-ray diffraction and Moessbauer spectroscopy measurements. (orig.)
Authors:
De Lima, J C; [1]  Borba, E C; [1]  Paduani, C; [1]  Dos Santos, V H.F.; [1]  Grandi, T A; [1]  Rechenberg, H R; [2]  Denicolo, I; [3]  Elmassalami, M; [4]  Barbosa, A F [4] 
  1. Universidade Federal de Santa Catarina (Brazil). Departamento de Fisica
  2. Sao Paulo Univ. (Brazil). Inst. de Fisica
  3. Parana Univ., Curitiba (Brazil). Dept. de Fisica
  4. Centro Brasileiro de Pesquisas Fisicas (CBPF), Rio de Janeiro, RJ (Brazil)
Publication Date:
Feb 01, 1996
Product Type:
Journal Article
Reference Number:
SCA: 360102; 360101; 360104; 665100; PA: CHF-96:0G5917; EDB-96:059682; SN: 96001567300
Resource Relation:
Journal Name: Journal of Alloys and Compounds; Journal Volume: 234; Journal Issue: 1; Other Information: PBD: 1 Feb 1996
Subject:
36 MATERIALS SCIENCE; 66 PHYSICS; IRON ALLOYS; MOESSBAUER EFFECT; X-RAY DIFFRACTION; ZINC ALLOYS; ANNEALING; CRYSTAL STRUCTURE; ISOMER SHIFT; MILLING; PHASE TRANSFORMATIONS; THERMAL ANALYSIS; LATTICE PARAMETERS
OSTI ID:
206172
Country of Origin:
Switzerland
Language:
English
Other Identifying Numbers:
Journal ID: JALCEU; ISSN 0925-8388; TRN: CH96G5917
Submitting Site:
CHF
Size:
pp. 43-47
Announcement Date:
Apr 15, 1996

Citation Formats

De Lima, J C, Borba, E C, Paduani, C, Dos Santos, V H.F., Grandi, T A, Rechenberg, H R, Denicolo, I, Elmassalami, M, and Barbosa, A F. Mechanical alloying of Fe and Zn: phase analysis and Moessbauer studies. Switzerland: N. p., 1996. Web. doi:10.1016/0925-8388(95)02084-5.
De Lima, J C, Borba, E C, Paduani, C, Dos Santos, V H.F., Grandi, T A, Rechenberg, H R, Denicolo, I, Elmassalami, M, & Barbosa, A F. Mechanical alloying of Fe and Zn: phase analysis and Moessbauer studies. Switzerland. https://doi.org/10.1016/0925-8388(95)02084-5
De Lima, J C, Borba, E C, Paduani, C, Dos Santos, V H.F., Grandi, T A, Rechenberg, H R, Denicolo, I, Elmassalami, M, and Barbosa, A F. 1996. "Mechanical alloying of Fe and Zn: phase analysis and Moessbauer studies." Switzerland. https://doi.org/10.1016/0925-8388(95)02084-5.
@misc{etde_206172,
title = {Mechanical alloying of Fe and Zn: phase analysis and Moessbauer studies}
author = {De Lima, J C, Borba, E C, Paduani, C, Dos Santos, V H.F., Grandi, T A, Rechenberg, H R, Denicolo, I, Elmassalami, M, and Barbosa, A F}
abstractNote = {Crystalline Fe{sub 25}Zn{sub 75} powder alloys ({Gamma}{sub 1} phase) have been prepared by mechanical alloying of pure elemental powders. A crystalline Fe{sub 27.9}Zn{sub 72.1} alloy ({Gamma} phase) was obtained after adequate annealing. The Moessbauer spectra at room temperature displayed three doublets before annealing, corresponding to iron atoms located at the outer tetrahedral, inner tetrahedral and octahedral sites in the unit cell of Fe{sub 25}Zn{sub 75}. For the annealed sample, two doublets associated with iron atoms located at two tetrahedral inequivalent sites in the unit cell of Fe{sub 27.9}Zn{sub 72.1} were observed. This {Gamma}{sub 1}-to-{Gamma}-phase transition was confirmed by X-ray diffraction and Moessbauer spectroscopy measurements. (orig.)}
doi = {10.1016/0925-8388(95)02084-5}
journal = []
issue = {1}
volume = {234}
journal type = {AC}
place = {Switzerland}
year = {1996}
month = {Feb}
}