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Correlation between the structure and infra-red absorption characteristics of mono-deuterated compounds: contribution to the study of organo-magnesium compounds; Correlations entre structure et absorption infrarouge de composes monodeuteries; contribution a l'etude des composes organomagnesiens

Abstract

The high sensitivity of the {nu} (C-D) vibration to the variations brought about by the substitution of the carbon attached to the deuterium is shown in the case of organic or organo-metallic mono-deuterated molecules. In particular, syntheses of various mono-deuterated organo-magnesium compounds have been carried out; results are given concerning an infra-red spectrometric examination of these compounds in the range 2100 - 2250 cm{sup -1}. The results show the existence of only one type of deuterated carbon, which suggests that the same carbanion is involved in various ionic associations for the different magnesium-containing compounds. (authors) [French] La grande sensibilite de la vibration {nu} (C-D) aux variations apportees dans la substitution du carbone porteur du deuterium est mise en evidence pour des molecules organiques au organometalliques monodeuteriees. On a notamment realise la synthese de divers composes organomagnesiens monodeuteries; les observations auxquelles ils ont donne lieu en spectrometrie infrarouge, dons la zone 2100 - 2250 cm{sup -1}, sont rapportees; les resultats ne mettent en evidence qu'un seul type de carbone deuterie ce qui suggere I'intervention d'un meme carbanion dans des associations ioniques diverses pour les differents reactifs magnesiens. (auteur)
Authors:
Paillous, A [1] 
  1. Commissariat a l'Energie Atomique, Saclay (France). Centre d'Etudes Nucleaires
Publication Date:
Oct 01, 1965
Product Type:
Thesis/Dissertation
Report Number:
CEA-R-2934
Resource Relation:
Other Information: TH: These ES sciences physiques; 80 refs; PBD: Oct 1965
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ABSORPTION SPECTROSCOPY; ALCOHOLS; ANIONS; CHEMICAL PREPARATION; DEUTERIUM COMPOUNDS; GRIGNARD REAGENTS; HALOGEN COMPOUNDS; INFRARED SPECTRA; ISOMERS; LITHIUM DEUTERIDES; MAGNESIUM COMPOUNDS; MOLECULAR STRUCTURE; STRUCTURAL CHEMICAL ANALYSIS; VIBRATIONAL STATES
OSTI ID:
20598757
Research Organizations:
CEA Saclay, 91 - Gif-sur-Yvette (France); Faculte des Sciences de l'Universite de Paris, Centre d'Orsay, 91 (France)
Country of Origin:
France
Language:
French
Other Identifying Numbers:
TRN: FR05R2934045269
Availability:
Available from INIS in electronic form
Submitting Site:
FRN
Size:
[48] pages
Announcement Date:

Citation Formats

Paillous, A. Correlation between the structure and infra-red absorption characteristics of mono-deuterated compounds: contribution to the study of organo-magnesium compounds; Correlations entre structure et absorption infrarouge de composes monodeuteries; contribution a l'etude des composes organomagnesiens. France: N. p., 1965. Web.
Paillous, A. Correlation between the structure and infra-red absorption characteristics of mono-deuterated compounds: contribution to the study of organo-magnesium compounds; Correlations entre structure et absorption infrarouge de composes monodeuteries; contribution a l'etude des composes organomagnesiens. France.
Paillous, A. 1965. "Correlation between the structure and infra-red absorption characteristics of mono-deuterated compounds: contribution to the study of organo-magnesium compounds; Correlations entre structure et absorption infrarouge de composes monodeuteries; contribution a l'etude des composes organomagnesiens." France.
@misc{etde_20598757,
title = {Correlation between the structure and infra-red absorption characteristics of mono-deuterated compounds: contribution to the study of organo-magnesium compounds; Correlations entre structure et absorption infrarouge de composes monodeuteries; contribution a l'etude des composes organomagnesiens}
author = {Paillous, A}
abstractNote = {The high sensitivity of the {nu} (C-D) vibration to the variations brought about by the substitution of the carbon attached to the deuterium is shown in the case of organic or organo-metallic mono-deuterated molecules. In particular, syntheses of various mono-deuterated organo-magnesium compounds have been carried out; results are given concerning an infra-red spectrometric examination of these compounds in the range 2100 - 2250 cm{sup -1}. The results show the existence of only one type of deuterated carbon, which suggests that the same carbanion is involved in various ionic associations for the different magnesium-containing compounds. (authors) [French] La grande sensibilite de la vibration {nu} (C-D) aux variations apportees dans la substitution du carbone porteur du deuterium est mise en evidence pour des molecules organiques au organometalliques monodeuteriees. On a notamment realise la synthese de divers composes organomagnesiens monodeuteries; les observations auxquelles ils ont donne lieu en spectrometrie infrarouge, dons la zone 2100 - 2250 cm{sup -1}, sont rapportees; les resultats ne mettent en evidence qu'un seul type de carbone deuterie ce qui suggere I'intervention d'un meme carbanion dans des associations ioniques diverses pour les differents reactifs magnesiens. (auteur)}
place = {France}
year = {1965}
month = {Oct}
}