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Self cleaning photoactive TiO{sub 2} coatings on SLS glasses by sol-gel dip coating

Abstract

Self-cleaning and anti-fogging coatings can be realized utilizing TiO{sub 2} thin films on various substrates. Photoactive TiO{sub 2} films exhibit strong oxidation power to breakdown organic compounds when illuminated by UV. TiO{sub 2} thin films possess photo-induced hydrophilicity, which is required for self-cleaning properties. They give optical quality with high reflectivity when coated on glass. In the present study, commercial float glass samples were coated by using sol-gel dip-coating process. Coated glasses were heat treated at 400 C for obtaining the desired properties. In order to monitor the photoactivity of the films, the decrease in the absorption of the aqueous solution of rhodamine B was measured after light irradiation of film surfaces as a function of time. The photoactivity of the films was measured also through the decomposition of stearic acid applied onto TiO{sub 2} films. In this study, the effects of film thickness and mean crystallite size on the photoactivity were given and discussed. (orig.)
Authors:
Sam, E D; Urgen, M; [1]  Tepehan, F Z; [2]  Gunay, V [3] 
  1. Istanbul Technical Univ., Metallurgical and Materials Engineering Dept., Maslak, Istanbul (Turkey)
  2. Istanbul Technical Univ., Physics Dept., Maslak, Istanbul (Turkey)
  3. Tubitak - MRC, MCTRI, Gebze, Kocaeli (Turkey)
Publication Date:
Jul 01, 2004
Product Type:
Journal Article
Resource Relation:
Journal Name: Key Engineering Materials; Journal Volume: 264-268; Journal Issue: pt.1; Conference: 8. conference and exhibition of the European Ceramics Society (ECerS), Istanbul (Turkey), 29 Jun - 3 Jul 2003; Other Information: Euro ceramics VII; PBD: 2004
Subject:
36 MATERIALS SCIENCE; COATINGS; TITANIUM OXIDES; GLASS; SOL-GEL PROCESS; THIN FILMS; SUBSTRATES; HEAT TREATMENTS; TEMPERATURE RANGE 0400-1000 K; OCTADECANOIC ACID; DECOMPOSITION; THICKNESS; PARTICLE SIZE; X-RAY DIFFRACTION; RHODAMINES; ABSORPTION SPECTRA; VISIBLE SPECTRA
OSTI ID:
20524152
Country of Origin:
Switzerland
Language:
English
Other Identifying Numbers:
Journal ID: ISSN 1013-9826; KEMAEY; TRN: CH04GB000
Submitting Site:
CHF
Size:
page(s) 407-410
Announcement Date:
Nov 24, 2004

Citation Formats

Sam, E D, Urgen, M, Tepehan, F Z, and Gunay, V. Self cleaning photoactive TiO{sub 2} coatings on SLS glasses by sol-gel dip coating. Switzerland: N. p., 2004. Web.
Sam, E D, Urgen, M, Tepehan, F Z, & Gunay, V. Self cleaning photoactive TiO{sub 2} coatings on SLS glasses by sol-gel dip coating. Switzerland.
Sam, E D, Urgen, M, Tepehan, F Z, and Gunay, V. 2004. "Self cleaning photoactive TiO{sub 2} coatings on SLS glasses by sol-gel dip coating." Switzerland.
@misc{etde_20524152,
title = {Self cleaning photoactive TiO{sub 2} coatings on SLS glasses by sol-gel dip coating}
author = {Sam, E D, Urgen, M, Tepehan, F Z, and Gunay, V}
abstractNote = {Self-cleaning and anti-fogging coatings can be realized utilizing TiO{sub 2} thin films on various substrates. Photoactive TiO{sub 2} films exhibit strong oxidation power to breakdown organic compounds when illuminated by UV. TiO{sub 2} thin films possess photo-induced hydrophilicity, which is required for self-cleaning properties. They give optical quality with high reflectivity when coated on glass. In the present study, commercial float glass samples were coated by using sol-gel dip-coating process. Coated glasses were heat treated at 400 C for obtaining the desired properties. In order to monitor the photoactivity of the films, the decrease in the absorption of the aqueous solution of rhodamine B was measured after light irradiation of film surfaces as a function of time. The photoactivity of the films was measured also through the decomposition of stearic acid applied onto TiO{sub 2} films. In this study, the effects of film thickness and mean crystallite size on the photoactivity were given and discussed. (orig.)}
journal = []
issue = {pt.1}
volume = {264-268}
journal type = {AC}
place = {Switzerland}
year = {2004}
month = {Jul}
}