Abstract
The behaviour of the different degrees of oxidation of plutonium have been studied using a falling drop mercury electrode in a non-complexing medium: dilute perchloric acid. In this medium it is possible to carry out the polarographic determination of plutonium using the reduction step situated at - 0.54 V/ECS which corresponds to the passage from the degree of oxidation(V) to the degree(III). The modifications brought about by a complexing ion, acetate, are then observed and interpreted. The existence of two plutonium(IV) acetic complexes has been shown; one is a polymerized substance. (author) [French] Le comportement des differents degres d'oxydation du plutonium est etudie a l'electrode a gouttes de mercure dans un milieu non complexant: l'acide perchlorique dilue. Il est possible dans ce milieu d'effectuer le dosage polarographique du plutonium en utilisant la vague de reduction situee a - 0.54 V/ECS qui correspond au passage du degre d'oxydation(V) au degre(III). Les modifications apportees par un ion complexant, l'acetate, sont ensuite observees et interpretees. Deux complexes acetiques du plutonium(IV) ont ete mis en evidence, dont l'un est un compose polymerise. (auteur)
Guichard, C
[1]
- Commissariat a l'Energie Atomique, Fontenay-aux-Roses (France). Centre d'Etudes Nucleaires
Citation Formats
Guichard, C.
Polarographic study of the electrochemical properties of plutonium; Etude polarographique des proprietes electrochimiques du plutonium.
France: N. p.,
1968.
Web.
Guichard, C.
Polarographic study of the electrochemical properties of plutonium; Etude polarographique des proprietes electrochimiques du plutonium.
France.
Guichard, C.
1968.
"Polarographic study of the electrochemical properties of plutonium; Etude polarographique des proprietes electrochimiques du plutonium."
France.
@misc{etde_20523423,
title = {Polarographic study of the electrochemical properties of plutonium; Etude polarographique des proprietes electrochimiques du plutonium}
author = {Guichard, C}
abstractNote = {The behaviour of the different degrees of oxidation of plutonium have been studied using a falling drop mercury electrode in a non-complexing medium: dilute perchloric acid. In this medium it is possible to carry out the polarographic determination of plutonium using the reduction step situated at - 0.54 V/ECS which corresponds to the passage from the degree of oxidation(V) to the degree(III). The modifications brought about by a complexing ion, acetate, are then observed and interpreted. The existence of two plutonium(IV) acetic complexes has been shown; one is a polymerized substance. (author) [French] Le comportement des differents degres d'oxydation du plutonium est etudie a l'electrode a gouttes de mercure dans un milieu non complexant: l'acide perchlorique dilue. Il est possible dans ce milieu d'effectuer le dosage polarographique du plutonium en utilisant la vague de reduction situee a - 0.54 V/ECS qui correspond au passage du degre d'oxydation(V) au degre(III). Les modifications apportees par un ion complexant, l'acetate, sont ensuite observees et interpretees. Deux complexes acetiques du plutonium(IV) ont ete mis en evidence, dont l'un est un compose polymerise. (auteur)}
place = {France}
year = {1968}
month = {Jul}
}
title = {Polarographic study of the electrochemical properties of plutonium; Etude polarographique des proprietes electrochimiques du plutonium}
author = {Guichard, C}
abstractNote = {The behaviour of the different degrees of oxidation of plutonium have been studied using a falling drop mercury electrode in a non-complexing medium: dilute perchloric acid. In this medium it is possible to carry out the polarographic determination of plutonium using the reduction step situated at - 0.54 V/ECS which corresponds to the passage from the degree of oxidation(V) to the degree(III). The modifications brought about by a complexing ion, acetate, are then observed and interpreted. The existence of two plutonium(IV) acetic complexes has been shown; one is a polymerized substance. (author) [French] Le comportement des differents degres d'oxydation du plutonium est etudie a l'electrode a gouttes de mercure dans un milieu non complexant: l'acide perchlorique dilue. Il est possible dans ce milieu d'effectuer le dosage polarographique du plutonium en utilisant la vague de reduction situee a - 0.54 V/ECS qui correspond au passage du degre d'oxydation(V) au degre(III). Les modifications apportees par un ion complexant, l'acetate, sont ensuite observees et interpretees. Deux complexes acetiques du plutonium(IV) ont ete mis en evidence, dont l'un est un compose polymerise. (auteur)}
place = {France}
year = {1968}
month = {Jul}
}