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Separation and recovery of dioxins using a heavy ion irradiation film

Abstract

It is demonstrated that halogenated dioxin and its derivatives can be separated from polluted aqueous solutions using pervaporation technique with a nanopore membrane fabricated by heavy-ion beam irradiation. The concentration of dioxin in the sample solution was set below 1 ppm. Polyethyleneterphthalate membrane was used. The membrane was first irradiated with high energy Xe-ions of 450 MeV with a fluence of 3 x 10{sup 3} to 3 x 10{sup 9} ions/cm{sup 2} using TIARA facility of JAERI Takasaki, etched with 6 mol/l NaOH solution resulting in formation of pores with diameter ranging from several to 40 nm, followed by grafting with monomers having affinity to dioxin. Dibenzo-p-dioxin was used to obtain permeability data. Separation factor obtained were within the range from 10 to 50. (S. Ohno)
Authors:
Takahashi, S; Iida, S; Ohbayashi, Y [1] 
  1. Meiji Univ., Kawasaki, Kanagawa (Japan). Faculty of Engineering
Publication Date:
Feb 01, 2004
Product Type:
Conference
Report Number:
JAERI-Conf-2003-021
Resource Relation:
Conference: 7. Symposium on JAERI's Reimei Research Program, Tokai, Ibaraki (Japan), 1-2 Jul 2003; Other Information: 8 refs., 8 figs., 4 tabs; PBD: Feb 2004; Related Information: In: Proceedings of the 7th symposium on JAERI's Reimei Research Program, by Shibata, Takemasa (ed.) [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment], 566 pages.
Subject:
07 ISOTOPES AND RADIATION SOURCES; CHEMICAL RADIATION EFFECTS; DIOXIN; ETCHING; FILTRATION; ION BEAMS; IRRADIATION; MEMBRANES; MOLECULAR WEIGHT; PARTICLE TRACKS; PERMEABILITY; PHYSICAL RADIATION EFFECTS; POLYESTERS; PORE STRUCTURE; XENON IONS
OSTI ID:
20510739
Research Organizations:
Japan Atomic Energy Research Inst., Kashiwa, Chiba (Japan)
Country of Origin:
Japan
Language:
Japanese
Other Identifying Numbers:
TRN: JP0450303080401
Availability:
Available from INIS in electronic form; Also available from JAERI; URL: http://jolisf.tokai.jaeri.go.jp/pdf/conf/JAERI-Conf-2003-021.pdf
Submitting Site:
INIS
Size:
page(s) 89-102
Announcement Date:
Oct 01, 2004

Citation Formats

Takahashi, S, Iida, S, and Ohbayashi, Y. Separation and recovery of dioxins using a heavy ion irradiation film. Japan: N. p., 2004. Web.
Takahashi, S, Iida, S, & Ohbayashi, Y. Separation and recovery of dioxins using a heavy ion irradiation film. Japan.
Takahashi, S, Iida, S, and Ohbayashi, Y. 2004. "Separation and recovery of dioxins using a heavy ion irradiation film." Japan.
@misc{etde_20510739,
title = {Separation and recovery of dioxins using a heavy ion irradiation film}
author = {Takahashi, S, Iida, S, and Ohbayashi, Y}
abstractNote = {It is demonstrated that halogenated dioxin and its derivatives can be separated from polluted aqueous solutions using pervaporation technique with a nanopore membrane fabricated by heavy-ion beam irradiation. The concentration of dioxin in the sample solution was set below 1 ppm. Polyethyleneterphthalate membrane was used. The membrane was first irradiated with high energy Xe-ions of 450 MeV with a fluence of 3 x 10{sup 3} to 3 x 10{sup 9} ions/cm{sup 2} using TIARA facility of JAERI Takasaki, etched with 6 mol/l NaOH solution resulting in formation of pores with diameter ranging from several to 40 nm, followed by grafting with monomers having affinity to dioxin. Dibenzo-p-dioxin was used to obtain permeability data. Separation factor obtained were within the range from 10 to 50. (S. Ohno)}
place = {Japan}
year = {2004}
month = {Feb}
}