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Preparatory of X zeolite (faujasite) with surfactant hexa decyl trimethyl ammonium bromide (HMDTA) for adsorption of organic compounds; Acondicionamiento de zeolita X (faujasita) con surfactante bromuro de hexa decil trimetil amonio (HDTMA) para adsorcion de compuestos organicos

Abstract

The water represents one of the most valuable natural resources for the alive beings, since it is the essential component of the alive matter. Also, it is fundamental part of our planet, since is an indispensable element for the integral development of the same one. The demographic growth, the human being's activities and the industrial growth, he/she brings as consequence an increase in the use of the water and the generation of residual waters that successively contaminate the hydrological basins, becoming an environmental problem urgent. The contamination of the water with compound such as phenol and benzene, it is a problem that it requires the search of solutions, since it is of compound not very biodegradable, able to accumulate through the food chains and very toxic to the alive beings that they enter in contact with them (Tolgyessy, 1993). In the human beings it can take place damages in liver and kidney, the Agency of Protection to the Atmosphere of the United States (EPA) it considers that the exhibition for benzene is related with the leukemia, it is also considered as a carcinogen substance. Of the methods that are used for the treatment of polluted waters, it highlights the use  More>>
Authors:
Publication Date:
Jul 01, 2003
Product Type:
Thesis/Dissertation
Report Number:
INIS-MX-1401
Resource Relation:
Other Information: TH: Thesis (Pharmaceutical Biologist Chemist); PBD: [2003]
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ABSORPTION SPECTROSCOPY; ADSORPTION; AMMONIUM HALIDES; BENZENE; BROMIDES; CONCENTRATION RATIO; DIAGRAMS; EXPERIMENTAL DATA; IMAGES; NEUTRON ACTIVATION ANALYSIS; ORGANIC COMPOUNDS; PHENOLS; SCANNING ELECTRON MICROSCOPY; SURFACTANTS; TESTING; WATER POLLUTION; WATER TREATMENT; X-RAY DIFFRACTION; ZEOLITES
OSTI ID:
20485160
Research Organizations:
Universidad Autonoma del Estado de Mexico, Facultad de Quimica, Toluca, Estado de Mexico (Mexico)
Country of Origin:
Mexico
Language:
Spanish
Other Identifying Numbers:
TRN: MX0400113057948
Availability:
Available from INIS in electronic form
Submitting Site:
MXN
Size:
62 pages
Announcement Date:
Jul 23, 2004

Citation Formats

Gonzalez R, V. Preparatory of X zeolite (faujasite) with surfactant hexa decyl trimethyl ammonium bromide (HMDTA) for adsorption of organic compounds; Acondicionamiento de zeolita X (faujasita) con surfactante bromuro de hexa decil trimetil amonio (HDTMA) para adsorcion de compuestos organicos. Mexico: N. p., 2003. Web.
Gonzalez R, V. Preparatory of X zeolite (faujasite) with surfactant hexa decyl trimethyl ammonium bromide (HMDTA) for adsorption of organic compounds; Acondicionamiento de zeolita X (faujasita) con surfactante bromuro de hexa decil trimetil amonio (HDTMA) para adsorcion de compuestos organicos. Mexico.
Gonzalez R, V. 2003. "Preparatory of X zeolite (faujasite) with surfactant hexa decyl trimethyl ammonium bromide (HMDTA) for adsorption of organic compounds; Acondicionamiento de zeolita X (faujasita) con surfactante bromuro de hexa decil trimetil amonio (HDTMA) para adsorcion de compuestos organicos." Mexico.
@misc{etde_20485160,
title = {Preparatory of X zeolite (faujasite) with surfactant hexa decyl trimethyl ammonium bromide (HMDTA) for adsorption of organic compounds; Acondicionamiento de zeolita X (faujasita) con surfactante bromuro de hexa decil trimetil amonio (HDTMA) para adsorcion de compuestos organicos}
author = {Gonzalez R, V}
abstractNote = {The water represents one of the most valuable natural resources for the alive beings, since it is the essential component of the alive matter. Also, it is fundamental part of our planet, since is an indispensable element for the integral development of the same one. The demographic growth, the human being's activities and the industrial growth, he/she brings as consequence an increase in the use of the water and the generation of residual waters that successively contaminate the hydrological basins, becoming an environmental problem urgent. The contamination of the water with compound such as phenol and benzene, it is a problem that it requires the search of solutions, since it is of compound not very biodegradable, able to accumulate through the food chains and very toxic to the alive beings that they enter in contact with them (Tolgyessy, 1993). In the human beings it can take place damages in liver and kidney, the Agency of Protection to the Atmosphere of the United States (EPA) it considers that the exhibition for benzene is related with the leukemia, it is also considered as a carcinogen substance. Of the methods that are used for the treatment of polluted waters, it highlights the use of adsorber and one of them is the zeolites, since they are broadly used in those separation processes. The zeolites is crystalline aluminosilicates, they are characterized for to have a big superficial area and for their great capacity of exchange cationic, due to it the process of adsorption depends on these two characteristics, since to the modified being superficially for surfactants cationic it originates an enriched layer of carbon organic, which has the capacity to remove pollutants of the water. The present work outlines as objective to carry out the superficial modification of zeolite X using hexa decyl trimethyl ammonium bromide (HMDTA-Br) to different concentrations, with the purpose of making it useful in the removal of pollutants organic, present in watery solution. The results of this investigation work indicate that the superficial modification of the zeolite X with HMDTA-Br to the four used concentrations 29, 58, 116 and 174 mmol L was possible, and it is demonstrated by the results of electronic microscopy of sweeping and for the decrease of the content of sodium carried out by Neutron activation analysis. In relation to the removal tests, it was found that the zeolite modified X with the biggest surfactant concentration it presents the highest phenol percentage removed, being this of 38% for a time of contact of 3 hours. In accordance with the results of removal of benzene is observed that the zeolite X removes 56%, but the modified zeolite removes a bigger quantity of until 90%, said percentage varies with regard to the time of contact. Therefore the modification of the zeolite X is favorable for the removal of the benzene. (Author)}
place = {Mexico}
year = {2003}
month = {Jul}
}