You need JavaScript to view this

NaPdPS{sub 4} and RbPdPS{sub 4}: systems with infinite straight ((1)/({infinity}))[PdPS{sub 4}]{sup -} chains soluble in polar solvents and the structure of cubic RbPdPS{sub 4}{l_brace}Rb{sub 0.33}P{sub 0.4}S{sub 2.23}O{sub x}{r_brace}

Abstract

The synthesis, crystal structures, chemical and spectroscopic properties of NaPdPS{sub 4}, RbPdPS{sub 4}, and RbPdPS{sub 4}{l_brace}Rb{sub 0.33}P{sub 0.4}S{sub 2.23}O{sub x}{r_brace} are described. NaPdPS{sub 4}, RbPdPS{sub 4}, are isostructural and crystallize in the tetragonal system I4/mcm with cell parameters a=7.3074(8) A, c=12.2308(14) A and a=8.2954(3) A, c=12.2284(4) A respectively. RbPdPS{sub 4}{l_brace}Rb{sub 0.33}P{sub 0.4}S{sub 2.23}O{sub x}{r_brace} is cubic, space group Pm-3n and a=12.0042(2) A. All compounds contain the same ((1)/({infinity}))[PdPS{sub 4}]{sup -} chains made of alternating square planar Pd{sup 2+} cations and tetrahedral [PS{sub 4}]{sup 3-} anions. RbPdPS{sub 4}{l_brace}Rb{sub 0.33}P{sub 0.4}S{sub 2.23}O{sub x}{r_brace} contains co-crystallized highly disordered molecular species encapsulated within [Rb{sub 8}] cubic cavities. Spectroscopic solid state {sup 31}P NMR, infrared and Raman data as well as elemental analysis suggest that these species could be S{sub n}{sup 2-} (n=3 or 4) anions and possibly cationic [P{sub 4}S{sub 6}O]{sup 6+} fragments. NaPdPS{sub 4} and RbPdPS{sub 4} exhibit exfoliative dissolution in polar solvents giving rise to solutions that show signs of complex fluid behavior.
Publication Date:
Nov 01, 2003
Product Type:
Journal Article
Resource Relation:
Journal Name: Journal of Solid State Chemistry; Journal Volume: 175; Journal Issue: 2; Other Information: DOI: 10.1016/S0022-4596(03)00138-5; PII: S0022459603001385; Copyright (c) 2003 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA); PBD: Nov 2003
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CHEMICAL PREPARATION; INFRARED SPECTRA; LATTICE PARAMETERS; NMR SPECTRA; PALLADIUM COMPOUNDS; PHOSPHIDES; POLAR COMPOUNDS; RAMAN SPECTRA; RUBIDIUM COMPOUNDS; SODIUM COMPOUNDS; SOLVENTS; SULFIDES; TETRAGONAL LATTICES; X-RAY DIFFRACTION
OSTI ID:
20461074
Country of Origin:
United States
Language:
English
Other Identifying Numbers:
Journal ID: ISSN 0022-4596; JSSCBI; TRN: US04R1555037947
Submitting Site:
INIS
Size:
page(s) 133-145
Announcement Date:

Citation Formats

Coste, Servane, Hanko, Jason, Bujoli-Doeuff, Martine, Louarn, Guy, Evain, Michel, Brec, Raymond, Alonso, Bruno, Jobic, S, and Kanatzidis, Mercouri G. NaPdPS{sub 4} and RbPdPS{sub 4}: systems with infinite straight ((1)/({infinity}))[PdPS{sub 4}]{sup -} chains soluble in polar solvents and the structure of cubic RbPdPS{sub 4}{l_brace}Rb{sub 0.33}P{sub 0.4}S{sub 2.23}O{sub x}{r_brace}. United States: N. p., 2003. Web. doi:10.1016/S0022-4596(03)00138-5.
Coste, Servane, Hanko, Jason, Bujoli-Doeuff, Martine, Louarn, Guy, Evain, Michel, Brec, Raymond, Alonso, Bruno, Jobic, S, & Kanatzidis, Mercouri G. NaPdPS{sub 4} and RbPdPS{sub 4}: systems with infinite straight ((1)/({infinity}))[PdPS{sub 4}]{sup -} chains soluble in polar solvents and the structure of cubic RbPdPS{sub 4}{l_brace}Rb{sub 0.33}P{sub 0.4}S{sub 2.23}O{sub x}{r_brace}. United States. doi:10.1016/S0022-4596(03)00138-5.
Coste, Servane, Hanko, Jason, Bujoli-Doeuff, Martine, Louarn, Guy, Evain, Michel, Brec, Raymond, Alonso, Bruno, Jobic, S, and Kanatzidis, Mercouri G. 2003. "NaPdPS{sub 4} and RbPdPS{sub 4}: systems with infinite straight ((1)/({infinity}))[PdPS{sub 4}]{sup -} chains soluble in polar solvents and the structure of cubic RbPdPS{sub 4}{l_brace}Rb{sub 0.33}P{sub 0.4}S{sub 2.23}O{sub x}{r_brace}." United States. doi:10.1016/S0022-4596(03)00138-5. https://www.osti.gov/servlets/purl/10.1016/S0022-4596(03)00138-5.
@misc{etde_20461074,
title = {NaPdPS{sub 4} and RbPdPS{sub 4}: systems with infinite straight ((1)/({infinity}))[PdPS{sub 4}]{sup -} chains soluble in polar solvents and the structure of cubic RbPdPS{sub 4}{l_brace}Rb{sub 0.33}P{sub 0.4}S{sub 2.23}O{sub x}{r_brace}}
author = {Coste, Servane, Hanko, Jason, Bujoli-Doeuff, Martine, Louarn, Guy, Evain, Michel, Brec, Raymond, Alonso, Bruno, Jobic, S, and Kanatzidis, Mercouri G}
abstractNote = {The synthesis, crystal structures, chemical and spectroscopic properties of NaPdPS{sub 4}, RbPdPS{sub 4}, and RbPdPS{sub 4}{l_brace}Rb{sub 0.33}P{sub 0.4}S{sub 2.23}O{sub x}{r_brace} are described. NaPdPS{sub 4}, RbPdPS{sub 4}, are isostructural and crystallize in the tetragonal system I4/mcm with cell parameters a=7.3074(8) A, c=12.2308(14) A and a=8.2954(3) A, c=12.2284(4) A respectively. RbPdPS{sub 4}{l_brace}Rb{sub 0.33}P{sub 0.4}S{sub 2.23}O{sub x}{r_brace} is cubic, space group Pm-3n and a=12.0042(2) A. All compounds contain the same ((1)/({infinity}))[PdPS{sub 4}]{sup -} chains made of alternating square planar Pd{sup 2+} cations and tetrahedral [PS{sub 4}]{sup 3-} anions. RbPdPS{sub 4}{l_brace}Rb{sub 0.33}P{sub 0.4}S{sub 2.23}O{sub x}{r_brace} contains co-crystallized highly disordered molecular species encapsulated within [Rb{sub 8}] cubic cavities. Spectroscopic solid state {sup 31}P NMR, infrared and Raman data as well as elemental analysis suggest that these species could be S{sub n}{sup 2-} (n=3 or 4) anions and possibly cationic [P{sub 4}S{sub 6}O]{sup 6+} fragments. NaPdPS{sub 4} and RbPdPS{sub 4} exhibit exfoliative dissolution in polar solvents giving rise to solutions that show signs of complex fluid behavior.}
doi = {10.1016/S0022-4596(03)00138-5}
journal = {Journal of Solid State Chemistry}
issue = {2}
volume = {175}
journal type = {AC}
place = {United States}
year = {2003}
month = {Nov}
}