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Removal of heavy metals from water by zeolite mineral chemically modified. Mercury as a particular case; Remocion de metales pesados del agua por mineral zeolitico quimicamente modificado. Mercurio como un caso particular

Abstract

Research works on the removal of mercury from water by zeolite minerals show that a small quantity of this element is sorbed. In this work the mercury sorption from aqueous solutions in the presence and absence of Cu(l l), Ni(l l) and/or Zn(l l) by a Mexican zeolite mineral, natural and modified by cisteaminium chloride or cistaminium dichloride, was investigated in acidic p H. The zeolite minerals were characterized by X- Ray diffraction Ftir, scanning electron microscopy and semiquantitative elemental analysis (EDS), surface area analysis (BET) and thermogravimetric analysis (TGA). Mercury from aqueous solutions was quantified by Atomic absorption spectroscopy. The amount of sulphur on the zeolite samples treated with Na CI and modified with cisteaminium chloride (0.375 mmol/g) or cistaminium dichloride(0.475 mmol/g) was found to be higher than that of the zeolite minerals modified with cisteaminium chloride and cistaminium dichloride without treating them with Na CI. The amount of sulphur on the zeolite minerals modified with thiourea was the lowest. The diffusion coefficients and sorption isotherms for mercury were determined in the natural, treated with Na CI and, treated with Na CI and then modified with the cisteaminium chloride or cistaminium dichloride zeolite samples. The retention of mercury was  More>>
Authors:
Publication Date:
Jul 01, 2002
Product Type:
Thesis/Dissertation
Report Number:
INIS-MX-1006
Resource Relation:
Other Information: TH: Thesis (M. in Env. Sci.); PBD: [2002]
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ADSORPTION; AQUEOUS SOLUTIONS; CLINOPTILOLITE; COPPER; DIAGRAMS; INFRARED SPECTRA; MERCURY; NICKEL; REMOVAL; SODIUM CHLORIDES; THIOUREA; X-RAY DIFFRACTION; ZEOLITES; ZINC
OSTI ID:
20273613
Research Organizations:
Universidad Autonoma del Estado de Mexico, Toluca, Estado de Mexico (Mexico)
Country of Origin:
Mexico
Language:
Spanish
Other Identifying Numbers:
TRN: MX0200127037947
Availability:
Available from INIS in electronic form
Submitting Site:
MXN
Size:
131 pages
Announcement Date:

Citation Formats

Gebremedhin H, T. Removal of heavy metals from water by zeolite mineral chemically modified. Mercury as a particular case; Remocion de metales pesados del agua por mineral zeolitico quimicamente modificado. Mercurio como un caso particular. Mexico: N. p., 2002. Web.
Gebremedhin H, T. Removal of heavy metals from water by zeolite mineral chemically modified. Mercury as a particular case; Remocion de metales pesados del agua por mineral zeolitico quimicamente modificado. Mercurio como un caso particular. Mexico.
Gebremedhin H, T. 2002. "Removal of heavy metals from water by zeolite mineral chemically modified. Mercury as a particular case; Remocion de metales pesados del agua por mineral zeolitico quimicamente modificado. Mercurio como un caso particular." Mexico.
@misc{etde_20273613,
title = {Removal of heavy metals from water by zeolite mineral chemically modified. Mercury as a particular case; Remocion de metales pesados del agua por mineral zeolitico quimicamente modificado. Mercurio como un caso particular}
author = {Gebremedhin H, T}
abstractNote = {Research works on the removal of mercury from water by zeolite minerals show that a small quantity of this element is sorbed. In this work the mercury sorption from aqueous solutions in the presence and absence of Cu(l l), Ni(l l) and/or Zn(l l) by a Mexican zeolite mineral, natural and modified by cisteaminium chloride or cistaminium dichloride, was investigated in acidic p H. The zeolite minerals were characterized by X- Ray diffraction Ftir, scanning electron microscopy and semiquantitative elemental analysis (EDS), surface area analysis (BET) and thermogravimetric analysis (TGA). Mercury from aqueous solutions was quantified by Atomic absorption spectroscopy. The amount of sulphur on the zeolite samples treated with Na CI and modified with cisteaminium chloride (0.375 mmol/g) or cistaminium dichloride(0.475 mmol/g) was found to be higher than that of the zeolite minerals modified with cisteaminium chloride and cistaminium dichloride without treating them with Na CI. The amount of sulphur on the zeolite minerals modified with thiourea was the lowest. The diffusion coefficients and sorption isotherms for mercury were determined in the natural, treated with Na CI and, treated with Na CI and then modified with the cisteaminium chloride or cistaminium dichloride zeolite samples. The retention of mercury was the highest for the zeolite minerals treated Na CI and then modified with cisteaminium chloride or cistaminium dichloride, with adsorption capacity of 0.0511 and 0.0525 mmol Hg/g, respectively. In this research work, it was found that the retention of mercury by the modified minerals was not affected by the presence of Cu (Il), Zn(l l) y Ni (I l) under the experimental conditions. (Author)}
place = {Mexico}
year = {2002}
month = {Jul}
}