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Characterization of the potential mobilization of inorganic pollutants in polluted soils; Caracterisation de la mobilisation potentielle des polluants inorganiques dans les sols pollues

Abstract

This work is made of 5 parts. The first chapter presents the regulatory aspects relative to the polluted sites and soils in France and in Europe in order to allow a better understanding of the stakes of this study. Chapter 2 proposes, first, a bibliographic synthesis of the hydro-mechanical and physico-chemical mechanisms controlling the transfer of pollutants in soils, and then, and exhaustive review of the laboratory tests that allow to evaluate the mobility of pollutants in soils. Chapter 3 is devoted to the experimental study of the interaction between a natural soil and 4 metals (As, Cr, Pb, Zn). It comprises the study of the adsorption-desorption kinetics and the implementation of adsorption-desorption isotherms. This chapter also introduces the notion of speciation (sequential extractions) and shows off the role played by the various constituents of the soil. An experiment of lead-humic acid equilibrium setting-up is proposed to evaluate the phenomenon of complexation on organic matter. Chapter 4 proposes to apply the selected laboratory tests to the previous natural soil artificially polluted in order to characterize the parameters necessary to obtain a mobility scale. The procedures are performed first, on a recently polluted soil and on the same soil after several  More>>
Authors:
Publication Date:
Mar 01, 2000
Product Type:
Thesis/Dissertation
Report Number:
FRNC-TH-4843
Resource Relation:
Other Information: TH: These formation doctorale: sciences et techniques du dechet. Ecole doctorale de chimie de Lyon; [205 refs.]; PBD: Mar 2000
Subject:
54 ENVIRONMENTAL SCIENCES; LAND POLLUTION; POLLUTANTS; METALS; SOIL CHEMISTRY; MOBILITY; CHEMICAL REACTION KINETICS; ADSORPTION ISOTHERMS; DESORPTION; CHEMICAL STATE; ORGANIC MATTER; POLLUTION REGULATIONS; DIFFUSION; LEACHING; HUMIC ACIDS; PH VALUE
OSTI ID:
20255283
Research Organizations:
Institut National des Sciences Appliquees (INSA), Lab. d'Analyse Environnementale des Procedes et des Systemes Industriels, 69 - Villeurbanne (France)
Country of Origin:
France
Language:
French
Other Identifying Numbers:
TRN: FR0202504
Availability:
Available to ETDE participating countries only(see www.etde.org); commercial reproduction prohibited; OSTI as DE20255283
Submitting Site:
FR
Size:
301 pages
Announcement Date:
Sep 18, 2002

Citation Formats

Blanchard, C. Characterization of the potential mobilization of inorganic pollutants in polluted soils; Caracterisation de la mobilisation potentielle des polluants inorganiques dans les sols pollues. France: N. p., 2000. Web.
Blanchard, C. Characterization of the potential mobilization of inorganic pollutants in polluted soils; Caracterisation de la mobilisation potentielle des polluants inorganiques dans les sols pollues. France.
Blanchard, C. 2000. "Characterization of the potential mobilization of inorganic pollutants in polluted soils; Caracterisation de la mobilisation potentielle des polluants inorganiques dans les sols pollues." France.
@misc{etde_20255283,
title = {Characterization of the potential mobilization of inorganic pollutants in polluted soils; Caracterisation de la mobilisation potentielle des polluants inorganiques dans les sols pollues}
author = {Blanchard, C}
abstractNote = {This work is made of 5 parts. The first chapter presents the regulatory aspects relative to the polluted sites and soils in France and in Europe in order to allow a better understanding of the stakes of this study. Chapter 2 proposes, first, a bibliographic synthesis of the hydro-mechanical and physico-chemical mechanisms controlling the transfer of pollutants in soils, and then, and exhaustive review of the laboratory tests that allow to evaluate the mobility of pollutants in soils. Chapter 3 is devoted to the experimental study of the interaction between a natural soil and 4 metals (As, Cr, Pb, Zn). It comprises the study of the adsorption-desorption kinetics and the implementation of adsorption-desorption isotherms. This chapter also introduces the notion of speciation (sequential extractions) and shows off the role played by the various constituents of the soil. An experiment of lead-humic acid equilibrium setting-up is proposed to evaluate the phenomenon of complexation on organic matter. Chapter 4 proposes to apply the selected laboratory tests to the previous natural soil artificially polluted in order to characterize the parameters necessary to obtain a mobility scale. The procedures are performed first, on a recently polluted soil and on the same soil after several months of aging. Chapter 5 applies the previously tested procedures to an industrial polluted soil (arsenic, chromium, lead, zinc) in order to propose an elaborated methodology for the evaluation of the mobility of inorganic pollutants. (J.S.)}
place = {France}
year = {2000}
month = {Mar}
}