You need JavaScript to view this

Crystallization kinetics of polysilane derived SiC

Abstract

By means of {sup 29}Si MAS NMR, ESR, XRD, SAXS as well as DTA/TG the crystallization process of polymer-derived amorphous silicon carbide was studied. The temperatures of optimum nucleation and crystal growth, respectively, were determined and the corresponding activation energies were estimated. The nucleation mechanism proposed for the nearly stoichiometric Si-C system investigated here differs from mechanisms reported hitherto in the literature for C rich systems. (orig.)
Authors:
Mueller, E; Kurtenbach, D; Roewer, G; Brendler, E; [1]  Mitchell, B S [2] 
  1. Freiberg Univ. of Mining and Technology, Freiberg (Germany)
  2. Tulane Univ., New Orleans, LA (United States)
Publication Date:
Jul 01, 2002
Product Type:
Journal Article
Resource Relation:
Journal Name: Key Engineering Materials; Journal Volume: 206-213; Journal Issue: pt.1; Conference: 7. conference and exhibition of the European Ceramic Society (ECerS), Brugge (Belgium), 9-13 Sep 2001; Other Information: PBD: 2002
Subject:
36 MATERIALS SCIENCE; 42 ENGINEERING; CERAMICS; SYNTHESIS; SILICON CARBIDES; PRECURSOR; SILANES; POLYMERS; AMORPHOUS STATE; CRYSTALLIZATION; NMR SPECTRA; ELECTRON SPIN RESONANCE; X-RAY DIFFRACTION; SMALL ANGLE SCATTERING; DIFFERENTIAL THERMAL ANALYSIS; THERMAL GRAVIMETRIC ANALYSIS; NUCLEATION; CRYSTAL GROWTH; ACTIVATION ENERGY; STOICHIOMETRY
OSTI ID:
20210669
Country of Origin:
Switzerland
Language:
English
Other Identifying Numbers:
Journal ID: ISSN 1013-9826; KEMAEY; TRN: CH01GF173
Submitting Site:
CHF
Size:
page(s) 55-58
Announcement Date:
Jan 02, 2002

Citation Formats

Mueller, E, Kurtenbach, D, Roewer, G, Brendler, E, and Mitchell, B S. Crystallization kinetics of polysilane derived SiC. Switzerland: N. p., 2002. Web.
Mueller, E, Kurtenbach, D, Roewer, G, Brendler, E, & Mitchell, B S. Crystallization kinetics of polysilane derived SiC. Switzerland.
Mueller, E, Kurtenbach, D, Roewer, G, Brendler, E, and Mitchell, B S. 2002. "Crystallization kinetics of polysilane derived SiC." Switzerland.
@misc{etde_20210669,
title = {Crystallization kinetics of polysilane derived SiC}
author = {Mueller, E, Kurtenbach, D, Roewer, G, Brendler, E, and Mitchell, B S}
abstractNote = {By means of {sup 29}Si MAS NMR, ESR, XRD, SAXS as well as DTA/TG the crystallization process of polymer-derived amorphous silicon carbide was studied. The temperatures of optimum nucleation and crystal growth, respectively, were determined and the corresponding activation energies were estimated. The nucleation mechanism proposed for the nearly stoichiometric Si-C system investigated here differs from mechanisms reported hitherto in the literature for C rich systems. (orig.)}
journal = []
issue = {pt.1}
volume = {206-213}
journal type = {AC}
place = {Switzerland}
year = {2002}
month = {Jul}
}