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Removing and recovering of uranium from the acid mine waters by using ion exchange resin; Remocao e recuperacao de uranio de aguas acidas de mina por resina de troca ionica

Abstract

Ion exchange using resins is one of the few processes capable of reducing ionic contaminants in effluents to very low levels. In this study the process was used to remove and recovery uranium from acid mine waters at Pocos de Caldas-MG Uranium Mining and Milling Plant. The local mineralogical features, allied to the biogeochemical phenomena, owing to presence of pyrite in the rock piles, moreover another factors, resulting acid drainage with several pollutants, including uranium ranging from 6 to 14 mg/l, as sulfate complex, that can be removed by anionic exchanger. The iron interference is eliminated by lime pretreatment of water, increasing pH from 2.6 to 3.3-3.8 to precipitate this cation, without changing the uranium amount. Eight anionic resins were tested, based on the uranium loading, in sorption studies. Retention time, and pH influence was verified for the exchanger chose. With breakthrough of 1 mg U/L and 10 mg U/l in the feed solution, the uranium decontamination level was 94%. Typical values of loading resin were 20-30 g U/l and 70-90 g SO{sub 4}/l. Uranium elution was done with Na Cl solution. Retention time, saline, and acid concentration were the parameters studied. The concentrate, obtained from the eluate by ammonia  More>>
Publication Date:
Jul 01, 1998
Product Type:
Thesis/Dissertation
Report Number:
INIS-BR-3804
Reference Number:
EDB-01:018886
Resource Relation:
Other Information: TH: Tese (M.Sc.); 53 refs., 15 figs., 18 tabs; PBD: 1998
Subject:
11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS; FUEL CYCLE; ION EXCHANGE MATERIALS; MINING; ORGANIC ION EXCHANGERS; RESINS; URANIUM
OSTI ID:
20136213
Research Organizations:
Sao Carlos Univ., SP (Brazil). Centro de Ciencias Exatas. Dept. de Quimica
Country of Origin:
Brazil
Language:
Portuguese
Other Identifying Numbers:
TRN: BR01B0867005644
Availability:
Available from INIS in electronic form
Submitting Site:
BRN
Size:
108 pages
Announcement Date:
Mar 02, 2001

Citation Formats

Nascimento, Marcos Roberto Lopes do. Removing and recovering of uranium from the acid mine waters by using ion exchange resin; Remocao e recuperacao de uranio de aguas acidas de mina por resina de troca ionica. Brazil: N. p., 1998. Web.
Nascimento, Marcos Roberto Lopes do. Removing and recovering of uranium from the acid mine waters by using ion exchange resin; Remocao e recuperacao de uranio de aguas acidas de mina por resina de troca ionica. Brazil.
Nascimento, Marcos Roberto Lopes do. 1998. "Removing and recovering of uranium from the acid mine waters by using ion exchange resin; Remocao e recuperacao de uranio de aguas acidas de mina por resina de troca ionica." Brazil.
@misc{etde_20136213,
title = {Removing and recovering of uranium from the acid mine waters by using ion exchange resin; Remocao e recuperacao de uranio de aguas acidas de mina por resina de troca ionica}
author = {Nascimento, Marcos Roberto Lopes do}
abstractNote = {Ion exchange using resins is one of the few processes capable of reducing ionic contaminants in effluents to very low levels. In this study the process was used to remove and recovery uranium from acid mine waters at Pocos de Caldas-MG Uranium Mining and Milling Plant. The local mineralogical features, allied to the biogeochemical phenomena, owing to presence of pyrite in the rock piles, moreover another factors, resulting acid drainage with several pollutants, including uranium ranging from 6 to 14 mg/l, as sulfate complex, that can be removed by anionic exchanger. The iron interference is eliminated by lime pretreatment of water, increasing pH from 2.6 to 3.3-3.8 to precipitate this cation, without changing the uranium amount. Eight anionic resins were tested, based on the uranium loading, in sorption studies. Retention time, and pH influence was verified for the exchanger chose. With breakthrough of 1 mg U/L and 10 mg U/l in the feed solution, the uranium decontamination level was 94%. Typical values of loading resin were 20-30 g U/l and 70-90 g SO{sub 4}/l. Uranium elution was done with Na Cl solution. Retention time, saline, and acid concentration were the parameters studied. The concentrate, obtained from the eluate by ammonia precipitation, presented uranium (86,8% as U{sub 3} O{sub 8}) and impurities within commercial specifications. (author)}
place = {Brazil}
year = {1998}
month = {Jul}
}