Abstract
Research and development has been performed on a technology to manufacture hydrogen effectively from water utilizing solar beam and using an organics oxidizing and reducing system as the intermediary, and its achievements in fiscal 1984 was reported. With regard to the process in hydrogen generation stage as the first step, water dissolvable rhodium complex was synthesized to improve the process having been developed in the previous fiscal year. Its photo-hydrogen generation capability was discussed. In the rhodium complex of ligand having sulfonic acid group for water solution, a system using only water as a solvent was discovered to show the photo-hydrogen generation capability equivalent to or greater than the system of organic solvent and water using non-water dissolvable rhodium complex. In the stage of reduction of oxidized type organics by water as the second step, discussions were given on photo-electrochemical behavior of iron oxide sintered electrodes. Photo-hydrogen generation was investigated by retaining the electrode potential to a potential generated by beam irradiation onto the iron oxide sintered electrodes, and using a system of water dissolvable rhodium complex and rhuthenium complex. As a result, a possibility of recycling the materials was discovered. (NEDO)
Citation Formats
None.
Report on achievements in fiscal 1984 on research and development commissioned from Sunshine Project. Studies on hydrogen manufacturing utilizing solar beam; 1984 nendo taiyoko riyo ni yoru suiso seizo no kenkyu seika hokokusho.
Japan: N. p.,
1985.
Web.
None.
Report on achievements in fiscal 1984 on research and development commissioned from Sunshine Project. Studies on hydrogen manufacturing utilizing solar beam; 1984 nendo taiyoko riyo ni yoru suiso seizo no kenkyu seika hokokusho.
Japan.
None.
1985.
"Report on achievements in fiscal 1984 on research and development commissioned from Sunshine Project. Studies on hydrogen manufacturing utilizing solar beam; 1984 nendo taiyoko riyo ni yoru suiso seizo no kenkyu seika hokokusho."
Japan.
@misc{etde_20102579,
title = {Report on achievements in fiscal 1984 on research and development commissioned from Sunshine Project. Studies on hydrogen manufacturing utilizing solar beam; 1984 nendo taiyoko riyo ni yoru suiso seizo no kenkyu seika hokokusho}
author = {None}
abstractNote = {Research and development has been performed on a technology to manufacture hydrogen effectively from water utilizing solar beam and using an organics oxidizing and reducing system as the intermediary, and its achievements in fiscal 1984 was reported. With regard to the process in hydrogen generation stage as the first step, water dissolvable rhodium complex was synthesized to improve the process having been developed in the previous fiscal year. Its photo-hydrogen generation capability was discussed. In the rhodium complex of ligand having sulfonic acid group for water solution, a system using only water as a solvent was discovered to show the photo-hydrogen generation capability equivalent to or greater than the system of organic solvent and water using non-water dissolvable rhodium complex. In the stage of reduction of oxidized type organics by water as the second step, discussions were given on photo-electrochemical behavior of iron oxide sintered electrodes. Photo-hydrogen generation was investigated by retaining the electrode potential to a potential generated by beam irradiation onto the iron oxide sintered electrodes, and using a system of water dissolvable rhodium complex and rhuthenium complex. As a result, a possibility of recycling the materials was discovered. (NEDO)}
place = {Japan}
year = {1985}
month = {Mar}
}
title = {Report on achievements in fiscal 1984 on research and development commissioned from Sunshine Project. Studies on hydrogen manufacturing utilizing solar beam; 1984 nendo taiyoko riyo ni yoru suiso seizo no kenkyu seika hokokusho}
author = {None}
abstractNote = {Research and development has been performed on a technology to manufacture hydrogen effectively from water utilizing solar beam and using an organics oxidizing and reducing system as the intermediary, and its achievements in fiscal 1984 was reported. With regard to the process in hydrogen generation stage as the first step, water dissolvable rhodium complex was synthesized to improve the process having been developed in the previous fiscal year. Its photo-hydrogen generation capability was discussed. In the rhodium complex of ligand having sulfonic acid group for water solution, a system using only water as a solvent was discovered to show the photo-hydrogen generation capability equivalent to or greater than the system of organic solvent and water using non-water dissolvable rhodium complex. In the stage of reduction of oxidized type organics by water as the second step, discussions were given on photo-electrochemical behavior of iron oxide sintered electrodes. Photo-hydrogen generation was investigated by retaining the electrode potential to a potential generated by beam irradiation onto the iron oxide sintered electrodes, and using a system of water dissolvable rhodium complex and rhuthenium complex. As a result, a possibility of recycling the materials was discovered. (NEDO)}
place = {Japan}
year = {1985}
month = {Mar}
}