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Research and development of basic technologies for next generation industries, 'electrically conductive polymeric material'. Evaluation on second term research and development; Jisedai sangyo kiban gijutsu kenkyu kaihatsu. Dodensei kobunshi zairyo (dainiki kenkyu kaihatsu hyoka)

Abstract

The research and development in the second term included development of raw materials, elucidation of electricity conduction mechanism, and development of methods to improve stability and a new processing method. Crystals of a large number of charge migrating complexes were grown to elucidate their electron properties and structures. A theoretical model was structured for the superconduction mechanism in the charge migrating complexes. Poly-p-phenylene vinylene-based polymers achieved {sigma}=1.1 times 10{sup 4}s/cm as a result of extension of soluble reaction intermediates. Poly-2, 5-phenylene vinylene doped with FeCl{sub 3} retained 10{sup 3}s/m for 165 days in nitrogen. Polypyrrole achieved 3.0 times 10{sup 3}s/cm in constant potential electrolytically oxidizing polymerization and extension at low temperatures. Polypyrrole doped with ClO{sub 4}{sup -} retained electric conductivity of 85% for 400 days in nitrogen. Electric conductivity of higher than 10{sup 5}s/cm was obtained by applying different kinds of doping into thin film and fiber formed graphite. The world's highest conductivity of 9 times 10{sup 5}s/cm was achieved particularly with discharge laminated and polymerized graphite doped with AsF{sub 5}. (NEDO)
Authors:
"NONE"
Publication Date:
Mar 01, 1988
Product Type:
Technical Report
Report Number:
JP-NEDO-010018021
Resource Relation:
Other Information: PBD: Mar 1988
Subject:
36 MATERIALS SCIENCE; SUPERCONDUCTIVITY; ELECTRON TRANSFER; COMPLEXES; CRYSTAL GROWTH; DOPED MATERIALS; POLYMERIZATION; PYRROLES; ELECTRIC CONDUCTIVITY; GRAPHITE; POLYMERS
OSTI ID:
20090312
Research Organizations:
New Energy and Industrial Technology Development Organization, Tokyo (Japan)
Country of Origin:
Japan
Language:
Japanese
Other Identifying Numbers:
TRN: JN0040042
Availability:
Available to ETDE participating countries only(see www.etde.org); commercial reproduction prohibited; OSTI as DE20090312
Submitting Site:
NEDO
Size:
[200] pages
Announcement Date:

Citation Formats

Research and development of basic technologies for next generation industries, 'electrically conductive polymeric material'. Evaluation on second term research and development; Jisedai sangyo kiban gijutsu kenkyu kaihatsu. Dodensei kobunshi zairyo (dainiki kenkyu kaihatsu hyoka). Japan: N. p., 1988. Web.
Research and development of basic technologies for next generation industries, 'electrically conductive polymeric material'. Evaluation on second term research and development; Jisedai sangyo kiban gijutsu kenkyu kaihatsu. Dodensei kobunshi zairyo (dainiki kenkyu kaihatsu hyoka). Japan.
1988. "Research and development of basic technologies for next generation industries, 'electrically conductive polymeric material'. Evaluation on second term research and development; Jisedai sangyo kiban gijutsu kenkyu kaihatsu. Dodensei kobunshi zairyo (dainiki kenkyu kaihatsu hyoka)." Japan.
@misc{etde_20090312,
title = {Research and development of basic technologies for next generation industries, 'electrically conductive polymeric material'. Evaluation on second term research and development; Jisedai sangyo kiban gijutsu kenkyu kaihatsu. Dodensei kobunshi zairyo (dainiki kenkyu kaihatsu hyoka)}
abstractNote = {The research and development in the second term included development of raw materials, elucidation of electricity conduction mechanism, and development of methods to improve stability and a new processing method. Crystals of a large number of charge migrating complexes were grown to elucidate their electron properties and structures. A theoretical model was structured for the superconduction mechanism in the charge migrating complexes. Poly-p-phenylene vinylene-based polymers achieved {sigma}=1.1 times 10{sup 4}s/cm as a result of extension of soluble reaction intermediates. Poly-2, 5-phenylene vinylene doped with FeCl{sub 3} retained 10{sup 3}s/m for 165 days in nitrogen. Polypyrrole achieved 3.0 times 10{sup 3}s/cm in constant potential electrolytically oxidizing polymerization and extension at low temperatures. Polypyrrole doped with ClO{sub 4}{sup -} retained electric conductivity of 85% for 400 days in nitrogen. Electric conductivity of higher than 10{sup 5}s/cm was obtained by applying different kinds of doping into thin film and fiber formed graphite. The world's highest conductivity of 9 times 10{sup 5}s/cm was achieved particularly with discharge laminated and polymerized graphite doped with AsF{sub 5}. (NEDO)}
place = {Japan}
year = {1988}
month = {Mar}
}