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The design, construction, commissioning and operation of a plant at Dounreay to dispose of sodium from KNKII

Abstract

In a competitive bidding exercise, AEA Technology at Dounreay won a contract to dispose of 88 tonnes of fast reactor sodium from the KNKII reactor at KarIsruhe, Germany. This sodium comprises of 36 tonnes of 'primary' sodium containing traces of caesium-137 and sodium-22 and 52 tonnes of lightly tritiated 'secondary' sodium. The sodium has been transported solid to Dounreay in 200 litre drums. To fulfil this contract a sodium disposal plant has been designed, constructed, commissioned and put into operation. Following an option study, an aqueous reaction plant design was selected. In this process, sodium is reacted with aqueous caustic soda, producing hydrogen gas and more caustic soda. The hydrogen is diluted with air and vented to atmosphere, and the caustic is neutralised with hydrochloric acid before discharge to the site low-active drain. All effluents - gaseous or liquid - are filtered and treated to remove as much radioactivity as possible before discharge. The main reasons for choosing this design option were that the process was well proven, the reaction is easily controlled by controlling the supply of sodium into the reaction vessel, reaction temperatures are relatively low and the effluent can be easily prepared for discharge. It was also  More>>
Authors:
Bowser, R; [1]  Farquhar, J; [2]  Currie, R [3] 
  1. AEA Technology, Dounreay (United Kingdom)
  2. AEA Technology, Harwell (United Kingdom)
  3. AEA Technology, Windscale (United Kingdom)
Publication Date:
Nov 01, 1997
Product Type:
Conference
Report Number:
IWGFR-98
Reference Number:
EDB-00:114395
Resource Relation:
Conference: Technical committee meeting on sodium removal and disposal from LMFRs in normal operation and in the framework of decommissioning, Aix-en-Provence (France), 3-7 Nov 1997; Other Information: 1 ref., 2 figs, 1 tab; PBD: Nov 1997; Related Information: In: Proceedings of the technical committee meeting on sodium removal and disposal from LMFRs in normal operation and in the framework of decommissioning, by Latge, C. [ed.] [CEA, Direction des Reacteurs Nucleaires, Departement d'Etudes des Reacteurs, CEA-Cadarache, Saint-Paul-lez-Durance (France)], 316 pages.
Subject:
12 MANAGEMENT OF RADIOACTIVE WASTES, AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES; CESIUM 137; DESIGN; KNK REACTOR; RADIOACTIVE EFFLUENTS; RADIOACTIVE WASTE DISPOSAL; SODIUM; SODIUM HYDROXIDES; UNITED KINGDOM ORGANIZATIONS; WASTE DISPOSAL; WASTE PROCESSING; WASTE PROCESSING PLANTS
OSTI ID:
20089139
Research Organizations:
International Atomic Energy Agency, International Working Group on Fast Reactors, Vienna (Austria)
Country of Origin:
IAEA
Language:
English
Other Identifying Numbers:
TRN: XA0055294040834
Availability:
Available from INIS in electronic form
Submitting Site:
INIS
Size:
page(s) 167-181
Announcement Date:
Dec 19, 2000

Citation Formats

Bowser, R, Farquhar, J, and Currie, R. The design, construction, commissioning and operation of a plant at Dounreay to dispose of sodium from KNKII. IAEA: N. p., 1997. Web.
Bowser, R, Farquhar, J, & Currie, R. The design, construction, commissioning and operation of a plant at Dounreay to dispose of sodium from KNKII. IAEA.
Bowser, R, Farquhar, J, and Currie, R. 1997. "The design, construction, commissioning and operation of a plant at Dounreay to dispose of sodium from KNKII." IAEA.
@misc{etde_20089139,
title = {The design, construction, commissioning and operation of a plant at Dounreay to dispose of sodium from KNKII}
author = {Bowser, R, Farquhar, J, and Currie, R}
abstractNote = {In a competitive bidding exercise, AEA Technology at Dounreay won a contract to dispose of 88 tonnes of fast reactor sodium from the KNKII reactor at KarIsruhe, Germany. This sodium comprises of 36 tonnes of 'primary' sodium containing traces of caesium-137 and sodium-22 and 52 tonnes of lightly tritiated 'secondary' sodium. The sodium has been transported solid to Dounreay in 200 litre drums. To fulfil this contract a sodium disposal plant has been designed, constructed, commissioned and put into operation. Following an option study, an aqueous reaction plant design was selected. In this process, sodium is reacted with aqueous caustic soda, producing hydrogen gas and more caustic soda. The hydrogen is diluted with air and vented to atmosphere, and the caustic is neutralised with hydrochloric acid before discharge to the site low-active drain. All effluents - gaseous or liquid - are filtered and treated to remove as much radioactivity as possible before discharge. The main reasons for choosing this design option were that the process was well proven, the reaction is easily controlled by controlling the supply of sodium into the reaction vessel, reaction temperatures are relatively low and the effluent can be easily prepared for discharge. It was also felt that an aqueous reaction plant could be designed to be operated remotely by one operator. The sodium in the drums is melted in a sodium melting station and then drained to a sodium buffer tank, prior to being injected into the reaction vessel. By collecting sodium in the buffer tank, sodium melting can proceed in parallel with sodium disposal allowing a high throughput to be achieved. This plant has been designed to dispose of 100 kg of sodium per hour, requiring a small operating team, suitably shielded from the radiological hazard. The design also ensures that the rate of reaction is controlled and that the effluent discharged to the low-active drain has been properly neutralised. The construction was performed within budget and in the agreed timescale. During inactive commissioning, problems were experienced with the sodium injection nozzle. This resulted in development of an improved nozzle of novel design which has been patented by AEA Technology. This modification enabled the plant to achieve its target throughput of 100 kg per hour and the plant has been put into service to dispose of sodium. (author)}
place = {IAEA}
year = {1997}
month = {Nov}
}