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Operation related on-line measurements of low temperature fire side corrosion during co-combustion of biomass and oil; Driftrelaterad direktmaetning av laagtemperaturkorrosion i en braensleeldad kraftvaermeanlaeggning

Abstract

A number of combustion plants have experienced corrosion attack on air preheaters and economisers when fired with biomass fuels. In certain plants the problems are great and reconstruction has been performed so that exposed components can be exchanged during operation. The electrochemical techniques offer on-line measurements of the changes in corrosion rate in the low temperature region in a waste incinerator. The purpose with this study was to evaluate the technique in a biomass fired boiler where the corrosion rate is considerable lower compared to a waste incinerator. Experiments were performed at the Haesselby plant, boiler 3, which was fired with pure biomass as well as a mixture of biomass and oil during the test period. It was found that the electrochemical technique is a useful tool for on-line measurements of the changes in corrosion rate in biomass fired utilities. Since the corrosion rate in the low temperature region is dependent on the boiler construction, electrochemical measurements give valuable information on the corrosion rate during optimisation of the fuel mixture, SNCR and temperature or the low temperature components. This is of special importance when introducing new fuels or fuel mixtures. Soot blowing is of prime importance for the total corrosion.  More>>
Authors:
Eriksson, Thomas [1] 
  1. Studsvik Nuclear AB, Nykoeping (Sweden)
Publication Date:
May 01, 2000
Product Type:
Technical Report
Report Number:
SVF-691
Reference Number:
EDB-01:012982
Resource Relation:
Other Information: Figures and tables with text in English. 1 ref, 8 figs, 3 tabs; PBD: May 2000
Subject:
09 BIOMASS FUELS; CORROSION; BOILERS; BIOMASS; ELECTROCHEMISTRY; ON-LINE MEASUREMENT SYSTEMS; COCOMBUSTION; EXPERIMENTAL DATA
OSTI ID:
20086731
Research Organizations:
Vaermeforsk, Stockholm (Sweden)
Country of Origin:
Sweden
Language:
Swedish
Other Identifying Numbers:
Other: Project Vaermeforsk-M6-817; ISSN 0282-3772; TRN: SE0007333
Availability:
Also available from: Vaermeforsk Service AB, SE-101 53 Stockholm, Sweden; Available to ETDE participating countries only(see www.etde.org); commercial reproduction prohibited; OSTI as DE20086731
Submitting Site:
SWD
Size:
29 pages
Announcement Date:
Feb 17, 2001

Citation Formats

Eriksson, Thomas. Operation related on-line measurements of low temperature fire side corrosion during co-combustion of biomass and oil; Driftrelaterad direktmaetning av laagtemperaturkorrosion i en braensleeldad kraftvaermeanlaeggning. Sweden: N. p., 2000. Web.
Eriksson, Thomas. Operation related on-line measurements of low temperature fire side corrosion during co-combustion of biomass and oil; Driftrelaterad direktmaetning av laagtemperaturkorrosion i en braensleeldad kraftvaermeanlaeggning. Sweden.
Eriksson, Thomas. 2000. "Operation related on-line measurements of low temperature fire side corrosion during co-combustion of biomass and oil; Driftrelaterad direktmaetning av laagtemperaturkorrosion i en braensleeldad kraftvaermeanlaeggning." Sweden.
@misc{etde_20086731,
title = {Operation related on-line measurements of low temperature fire side corrosion during co-combustion of biomass and oil; Driftrelaterad direktmaetning av laagtemperaturkorrosion i en braensleeldad kraftvaermeanlaeggning}
author = {Eriksson, Thomas}
abstractNote = {A number of combustion plants have experienced corrosion attack on air preheaters and economisers when fired with biomass fuels. In certain plants the problems are great and reconstruction has been performed so that exposed components can be exchanged during operation. The electrochemical techniques offer on-line measurements of the changes in corrosion rate in the low temperature region in a waste incinerator. The purpose with this study was to evaluate the technique in a biomass fired boiler where the corrosion rate is considerable lower compared to a waste incinerator. Experiments were performed at the Haesselby plant, boiler 3, which was fired with pure biomass as well as a mixture of biomass and oil during the test period. It was found that the electrochemical technique is a useful tool for on-line measurements of the changes in corrosion rate in biomass fired utilities. Since the corrosion rate in the low temperature region is dependent on the boiler construction, electrochemical measurements give valuable information on the corrosion rate during optimisation of the fuel mixture, SNCR and temperature or the low temperature components. This is of special importance when introducing new fuels or fuel mixtures. Soot blowing is of prime importance for the total corrosion. During a few minutes an individual soot blower can initiate such a high corrosion rate that it represents the total corrosion. The material temperature is another important parameter. Above a certain temperature the corrosion rate is negligible. During co-combustion this temperature was found to be in the region 65-85 deg C. The influence of the SNCR with ammonia, with respect to corrosion, is dependent on the fuel mixture used. In utilities where acidic combustion products are formed, ammonia has a neutralising effect e.g. in Hoegdalen. At the Haesselby plant this neutralising effect was not found. During cocombustion with oil the ammonia forms ammoniahydrosulphate which increases the corrosion rate. Simultaneously the use of oil leads to better combustion which is of importance for a low corrosion rate. Hence the fuel mixture is important.}
place = {Sweden}
year = {2000}
month = {May}
}