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Synthesis and characterization of tetraphenylporphyrinate of dysprosium route dysprosium acetylacetonate.; Sintesis y caracterizacion de un porfirinato de disprosio via acetilacetonato de disprosio.

Abstract

Dysprosium bis (tetraphenylporphyrinate) and bis (dysprosium) Tris (tetraphenylporphyrinate) were synthesized from dysprosium tetraphenylporphyrinate prepared in situ, and characterized by IR, UV-vis, TGA, DTA, EPR and magnetic susceptibility measurements. The double decker compound was obtained by direct oxidation of the HDy(TPP){sub 2} intermediate. The existence of the radical anion, (TPP){sup -} , in the double decker product was conformed by EPR spectrometry. Dysprosium monoporphyrinate was isolated and characterized by the same techniques. (Author).
Authors:
Publication Date:
Dec 31, 1992
Product Type:
Thesis/Dissertation
Report Number:
INIS-mf-14590
Reference Number:
SCA: 400201; 400100; PA: AIX-26:069197; EDB-95:136828; ERA-20:030234; NTS-96:007106; SN: 95001471371
Resource Relation:
Other Information: TH: Thesis (Chemist).; PBD: 1992
Subject:
40 CHEMISTRY; PORPHYRINS; DYSPROSIUM; NEUTRON ACTIVATION ANALYSIS; STRUCTURAL CHEMICAL ANALYSIS; CHEMICAL PREPARATION; INFRARED SPECTRA; LIQUID COLUMN CHROMATOGRAPHY; MAGNETIC SUSCEPTIBILITY; THERMAL GRAVIMETRIC ANALYSIS; VISIBLE SPECTRA
OSTI ID:
110359
Research Organizations:
Universidad Autonoma del Estado de Mexico, Toluca (Mexico). Facultad de Quimica
Country of Origin:
Mexico
Language:
Spanish
Other Identifying Numbers:
Other: ON: DE96602472; TRN: MX9500008069197
Availability:
INIS; OSTI as DE96602472
Submitting Site:
INIS
Size:
108 p.
Announcement Date:

Citation Formats

Martinez M, V. Synthesis and characterization of tetraphenylporphyrinate of dysprosium route dysprosium acetylacetonate.; Sintesis y caracterizacion de un porfirinato de disprosio via acetilacetonato de disprosio.. Mexico: N. p., 1992. Web.
Martinez M, V. Synthesis and characterization of tetraphenylporphyrinate of dysprosium route dysprosium acetylacetonate.; Sintesis y caracterizacion de un porfirinato de disprosio via acetilacetonato de disprosio.. Mexico.
Martinez M, V. 1992. "Synthesis and characterization of tetraphenylporphyrinate of dysprosium route dysprosium acetylacetonate.; Sintesis y caracterizacion de un porfirinato de disprosio via acetilacetonato de disprosio." Mexico.
@misc{etde_110359,
title = {Synthesis and characterization of tetraphenylporphyrinate of dysprosium route dysprosium acetylacetonate.; Sintesis y caracterizacion de un porfirinato de disprosio via acetilacetonato de disprosio.}
author = {Martinez M, V}
abstractNote = {Dysprosium bis (tetraphenylporphyrinate) and bis (dysprosium) Tris (tetraphenylporphyrinate) were synthesized from dysprosium tetraphenylporphyrinate prepared in situ, and characterized by IR, UV-vis, TGA, DTA, EPR and magnetic susceptibility measurements. The double decker compound was obtained by direct oxidation of the HDy(TPP){sub 2} intermediate. The existence of the radical anion, (TPP){sup -} , in the double decker product was conformed by EPR spectrometry. Dysprosium monoporphyrinate was isolated and characterized by the same techniques. (Author).}
place = {Mexico}
year = {1992}
month = {Dec}
}